Organic 1: Introduction Flashcards

1
Q

What is an empirical formula?

A

The simplest ratio of each element in a compound

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2
Q

What is the molecular formula?

A

The actual number of atoms of each element present in a compound

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3
Q

What is a structural formula?

A

The arrangement of atoms in a molecule in a simplified form, without showing all the bonds

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4
Q

What is the displayed formula?

A

Every atom and every bond in a molecule

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5
Q

What is the skeletal formula?

A

Straight lines represent carbon-carbon bonds
No hydrogen atoms are shown

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6
Q

What is a homologous series?

A

A family of organic compounds with the same functional group, but different carbon chain length
E.g. alkanes

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7
Q

What are the characteristics of a homologous series?

A

1) Same general formula
2) Same functional group
3) Trends in physical properties
4) Similar chemical properties

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8
Q

How does melting and boiling point change as carbon chain length increases?

A

As carbon chain length increases, melting and boiling points increase
Because there are more intermolecular forces, so stronger intermolecular forces
Which require more energy to overcome

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9
Q

How does chain branching affect melting and boiling point?

A

Chain branching reduces melting points because molecules are less compact

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10
Q

What are isomers?

A

Molecules that have the same molecular formula but whose atoms are arranged differently

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11
Q

What are the two main types of isomer?

A

Structural isomer
Stereoisomer

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12
Q

What are structural isomers?

A

Molecules that have the same molecular formula but whose atoms are arranged differently

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13
Q

What are the three types of structural isomerism?

A

1) Chain isomerism
2) Position isomerism
3) Functional group isomerism

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14
Q

What is chain isomerism?

A

When isomers have a different arrangement of the hydrocarbon chain, such as branching

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15
Q

What is position isomerism?

A

When isomers have the same functional group attached to the main chain but at different points

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16
Q

What is functional group isomerism?

A

When isomers have the same molecular formula but different functional groups (like aldehydes and ketones)

17
Q

What are stereoisomers?

A

Isomers that have the same structural formula but different arrangement of bonds in space

18
Q

What are the two types of stereoisomer?

A

1) Geometric (E-Z isomer)
2) Optical

19
Q

What is E-Z isomerism?

A

Where the positions of substituents at either side of a carbon-carbon double bond are different
If they are on the same side, it is a Z-isomer
If they are on opposite sides, it is an E-isomer