ORGANIC 1: Chapter 1: Hybridization & Bonding Flashcards

1
Q

What is the hybridization of the indicated atom?

A

sp2

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2
Q

What is the hybridization of the indicated atom?

A

sp3

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3
Q

What is the hybridization of the indicated atom?

A

sp3

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4
Q

What is the hybridization of the indicated atom?

A

sp

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5
Q

What is the hybridization of the indicated atom?

A

sp

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6
Q

What is the hybridization of the indicated atom?

A

sp3

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7
Q

What is the hybridization of the indicated atom?

A

sp3

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8
Q

What is the hybridization of the indicated atom?

A

sp2

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9
Q

What is the hybridization of the indicated atom?

A

sp3

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10
Q

What is the hybridization of the indicated atom?

A

sp2

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11
Q

What is the hybridization of the indicated atom?

A

sp3

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12
Q

What is the relationship between bond length & bond strength?

A

The shorter the bond, the stronger it is and

the longer the bond, the weaker it is

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13
Q

Which of the indicated bonds in the molecule shown below is the longest?

A

A

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14
Q

Which of the indicated bonds in the molecule shown below is the shortest?

A

C

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15
Q

Which of the indicated bonds in the molecule shown below is the strongest?

A

C

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16
Q

Which of the indicated bonds in the molecule shown below is the weakest?

A

A

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17
Q

Sigma bonds are formed from the overlap of _______ orbitals.

A

Hybrid orbitals (sp, sp2, sp3, etc.) or atomic orbitals (hydrogen-hydrogen/carbon-hydrogen)

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18
Q

Pi bonds are formed from the overlap of _______ orbitals.

A

P orbitals

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19
Q

What type of bonding is depicted below?

A

Sigma bonding

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20
Q

What type of bonding is depectied below?

A

Sigma anti-bonding

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21
Q

What type of bonding is depectied below?

A

Pi bonding

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22
Q

What type of bonding is depectied below?

A

Pi anti-bonding

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23
Q

What is the formula to calculate formal charge?

A

Formal Charge = # valence electrons - # bonds - # electrons

or

Formal Charge = # valence electrons - # lines - # dots

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24
Q

What is the formal charge of the indicated atom?

A

0

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25
What is the formal charge of the indicated atom?
+1
26
What is the formal charge of the indicated atom?
+1
27
What is the formal charge of the indicated atom?
+1
28
What is the formal charge of the indicated atom?
-1
29
# Define Constitutional Isomers
Molecules that have the same molecular formula but different connectivity
30
How many valence electrons does oxygen have?
6
31
How many valence electrons does nitrogen have?
5
32
How many valence electrons does carbon have?
4
33
# Define Condensed Structure
Structural representation that omits some/all covalent bonds and displays all atoms bound to a carbon in the list next to it. (i.e. CH3CH3)
34
# Bond Angle & Geometry sp2
120°, trigonal planar
35
# Bond Angle & Geometry sp3
109.5°, tetrahedral
36
# Bond Angle & Geometry sp
180°, linear
37
What hybridization does an atom have if it has 3 regions of electron density?
sp2
38
What hybridization does an atom have if it has 4 regions of electron density?
sp3
39
What hybridization does an atom have if it has 2 regions of electron density?
sp
40
How many atoms in the molecule below display tetrahedral geometry?
6 atoms (all sp3 hybridized atoms)
41
What molecular geometry does the indicated atom display?
Trigonal planar (sp2 hybridized)
42
What type of bonding is depicted below?
Sigma bonding
43
What type of bonding is depicted below?
Sigma anti-bonding
44
What orbitals overlap to form the C-C bond in ethane (CH3CH3)?
sp3-sp3
45
What orbitals overlap to form the C-H bond in ethane (CH3CH3)?
sp3-s
46
What orbitals overlap to form the C-C bond in ethene (CH2=CH2)?
Sigma: sp2-sp2 Pi: p-p
47
What orbitals overlap to form the C-H bond in ethene (CH2=CH2)?
sp2-s
48
What orbitals overlap to form the C-C bond in ethyne (CH≡CH)?
Sigma: sp-sp Pi: p-p x2
49
What orbitals overlap to form the C-H bond in ethyne (CH≡CH)?
sp-s
50
What is the hybridization of the indicated atom?
sp
51
How many hydrogens are present on the indicated atom?
0 hydrogens
52
What orbital does the lone pair on the carbon occupy?
sp
53
How many hydrogens are present on the indicated atom?
1 hydrogen
54
How many hydrogens are present on the indicated atom?
3 hydrogens
55
What is the formal charge of the indicated atom?
+1
56
What is the formal charge of the indicated atom?
+1
57
What is the formal charge of the indicated atom?
0
58
Given the formal charge of the indicated atom, how many lone pairs are present?
Two lone pairs (4 total electrons)
59
Given the formal charge of the indicated atom, how many lone pairs are present?
Three lone pairs (6 total electrons)
60
Given the formal charge of the indicated atom, how many lone pairs are present?
One lone pair (2 total electrons)
61
Given the formal charge of the indicated atom, how many lone pairs are present?
Two lone pairs (4 total electrons)
62
Given the formal charge of the indicated atom, how many lone pairs are present?
One lone pair (2 total electrons)
63
Given the formal charge of the indicated atom, how many lone pairs are present?
Two lone pairs (4 total electrons)