Option C: Engineering Physics (Thermodynamics) Flashcards
In thermodynamics, what is a system?
A volume of space filled with gas.
What are the two types of system?
- Open
* Closed
What are open systems?
Those that allow gas to flow in, out or through them.
What are closed systems?
Those that don’t allow gas to enter or escape.
What does the first law of thermodynamics describe?
How energy is conserved in a system through heating, cooling and doing work.
State the first law of thermodynamics.
The heat energy supplied to the system either increase the internal energy or enables it to do work.
Give the equation for the first law of thermodynamics.
Q = ΔU + W
Where:
• Q = Heat energy transferred to the system
• ΔU = Change in internal energy
• W = Work some by the gas
In thermodynamics, what is Q?
Heat energy transferred to the system
In thermodynamics, what is ΔU?
Change in internal energy
In thermodynamics, what is W?
The work done by the system (i.e. by the gas)
What is the internal energy of a gas?
The sum of the potential and kinetic energies of all of the particles.
When heat is transferred to the system, what is the sign of Q?
Positive
When heat is transferred away from the system, what is the sign of Q?
Negative
When a gas expands, what is the sign of W?
Positive
When a gas is compressed, what is the sign of W?
Negative
A cylinder is sealed by a moveable piston. The gas in the cylinder is heated with 60J of heat to move the piston. The internal energy of the gas increases by 5J.
a) Calculate the work done by the gas to move the piston.
b) Now the piston does 60J of work on the gas to compress it. No heat is lost. Calculate the change in the internal energy of the gas.
a) W = Q - ΔU = 60 - 5 = 55J
b) ΔU = -W = 60J
What is another name for a closed system?
Non-flow process
What must be assumed when doing calculations about a gas in a closed system?
That the gas is an ideal gas.
What are some of the assumptions when working with an ideal gas?
- Internal energy ONLY depends on the temperature (i.e. potential energy is negligible)
- A change in volume means work is done
- pV = nRT applies
For an ideal gas, what does the internal energy depend on?
- Temperature (and therefore kinetic energy)
* NOT potential energy
Does the potential energy of an ideal gas in a closed system change?
No
What does a change in volume of a gas in a closed system indicate?
That work is being done.
What is the ideal gas law equation?
pV = nRT
Where: • p = Pressure (Pa) • V = Volume (m³) • n = Moles of gas (mol) • R = Gas constant (8.31J/K/mol) • T = Temperature (K)
What is the equation used in working out pressures, volumes and temperatures in a closed system undergoing a change?
p₁V₁ / T₁ = p₂V₂ / T₂
NOTE: Not given in exam
What is an isothermal change?
One that happens at constant temperature.
What quantity defines an isothermal change and why?
- ΔU = 0
* Because the internal energy only depends on the temperature, which is not changing
What can be said in terms of the first law of thermodynamics for an isothermal change?
- ΔU = 0
* So Q = W
Explain an isothermal change in terms of the first law of thermodynamics.
- The work done by a system is equal to the heat energy supplied
- The work done on the system is equal to heat energy loss of the system
What is the equation for the constant in an isothermal change?
- pV = Constant
* So: p₁V₁ = p₂V₂
What is an adiabatic change?
One where no heat is lost or gained by the system.
What quantity defines an adiabatic change and why?
- Q = 0
* Because there is no heat transfer to or away from the gas
What can be said in terms of the first law of thermodynamics for an adiabatic change?
- Q = 0
* So ΔU = -W
Explain an adiabatic change in terms of the first law of thermodynamics.
Any change in the internal energy of the system is caused by work done by/on the system.
Does an adiabatic change result in a temperature change?
Yes, since the internal energy is changing.
What is the equation for the constant in an adiabatic change?
- pV^γ = Constant
- So p₁V₁^γ = p₂V₂^γ
Where:
• γ = Adiabatic constant
What is the adiabatic constant?
- A constant used in adiabatic change calculations.
* Depends on the type of gas.
What is the adiabatic constant (γ) for a monoatomic gas?
1.67
What is the adiabatic constant (γ) for a diatomic gas?
1.40
What is the adiabatic constant (γ) for a polyatomic gas?
1.33
What is the equation for the work done to expand a gas?
W = p x ΔV
Where:
• W = Work done by the system (J)
• p = Pressure (Pa)
• ΔV = Change in volume of system (m³)
Derive W = pΔW.
- W = F x d
- F = p x A
- W = p x A x d
- W = p x ΔV
Is work done by or on a gas when it expands?
By the gas
Is work done by or on a gas when it is compressed?
On the gas.
For an isobaric change, what equation can be stated?
V₁/T₁ = V₂/T₂
This comes from pV = nRT
What is the work done when there is no change in the volume of a gas?
0
What quantity defines an isovolumetric change and why?
- W = 0
* Since no work is done if the volume is unchanging.
What can be said in terms of the first law of thermodynamics for an isovolumetric change?
- W = 0
* So Q = ΔU
Explain an isovolumetric change in terms of the first law of thermodynamics.
The internal energy of the gas increases by the heat energy transferred to it, since none is lost/gained by doing work.
What graph can be used to represent non-flow processes?
p-V diagram
When looking at the lines on a p-V diagram, what is it important to remember?
Look at the arrows to see the direction in which the change is happening.
How is the work done represented on a p-V diagram?
It is the area under the line.
Describe the p-V graph for an isothermal process.
Smooth curve between the top left and bottom right (where p₁V₁ = p₂V₂)
On a p-V diagram, which way does the arrow point on the line for an isothermal compression?
To the top left
On a p-V diagram, which way does the arrow point on the line for an isothermal expansion?
To the bottom right
What are p-V curves for isothermal processes called?
Isotherms
How does the position of an isotherm depend on the temperature?
The further the curve is from the origin, the hotter it is.
On a p-V diagram, which direction does the line have to point in order for work to be done by the gas and on the gas?
- By the gas -> To the right
* On the gas -> To the left
Describe the p-V graph for an adiabatic process.
Steep, smooth curve between the top left and bottom right
On a p-V diagram, what is the difference between the line for an adiabatic and isothermal process?
The adiabatic change is steeper.
Is more work done when compressing a gas isothermally or adiabatically? Why?
Adiabatically, because the curve is steeper, so the area under the p-V graph is larger.
Is more work done when a gas expands isothermally or adiabatically? Why?
Isothermally, because the curve is less steep, so the area under the graph is larger.
Remember to practise drawing out the p-V diagrams for an adiabatic and isothermal expansion ad compression.
See diagram pg 230 of revision guide
Describe the p-V graph for an isovolumetric process.
Straight vertical line
How can you tell from a p-V graph that an isovolumetric process involves no work being done?
- It is a straight vertical line
* So there is no area under the line, meaning no work is done
If a system is kept at a constant volume but heated between temperatures T₁ and T₂, what change will be observed?
The pressure will increase.
For an isovolumetric change on a p-V graph, what is the relative temperature at the bottom and top of the line?
- Bottom: Lower temperature
* Top: Higher temperature
No work is done in an isovolumetric change. What causes the change in pressure?
Heating or cooling
Describe the p-V graph for an isobaric process.
Straight horizontal line
On the p-V graph for an isobaric change, what is the work done?
The area under the straight horizontal line.
When is W = pΔV true?
For an isobaric change.
How is W = pΔV shown on a p-V graph?
- The work done in an isobaric change is equal to the area under the straight horizontal line.
- The height of this area is p, while the length is ΔV.
How are cyclic processes shown on a p-V graph?
They form a loop.
On a p-V diagram, how can the net work done per cycle by a cyclic process be calculated?
It is the area of the loop.
What must you remember about the work done on a p-V diagram for a cyclic process?
The area is the work done PER CYCLE.
Remember to practise labelling the p-V cycle on pg 231.
Do it.
For a cyclic process on a p-V diagram that goes clockwise, is the net work done on or by the system?
By the system.