Option B2 Flashcards

Thermodynamics

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1
Q

State

The first law of thermodynamics

A
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2
Q

Define Internal energy

A

Internal energy is defined as the energy associated with the random, disordered motion of molecules.

should be equal to

Total Potential energy + Random kinetic energy of moleucles

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3
Q

State

The second law of thermodynamics

in Clausius form

A

It is impossible for thermal energy to flow from a cold to a hot object without performing any work.

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4
Q

State

The second law of thermodynamics

in Kelvin form

A

It is impossible, in a cyclic process, to completely convert heat into mechanical work.

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5
Q

State

The second law of thermodynamics as a

consequence of Entropy

A

The total entropy of a system either increase or remain constant, it never decreases.

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6
Q

Formula

of calculating

Change in Internal Energy

A
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7
Q
A
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8
Q

Explain

the sign convention of

quantum energy/heat transfer

between a system and its surrounding (Q)

A

Q > 0 if heat is supplied to the system

Q < 0 if heat is released by the system

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9
Q

What is the formula of

calculating Workdone (W)

in first law of thermodynamic

A
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10
Q

Explain the sign convention

of Workdone (W) in

the first law of thermodynamic

A
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11
Q

Describing the first law of thermodynamics as a statement of conservation of energy

A
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12
Q

What is

Entropy?

A

Entropy is

A measure of disorder

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13
Q

Describle

how a system will become

more disorder (i.e. entropy increase)?

A

A system will be more disorder if it is more difficult to determine the position of molecules, e.g.

  1. Temperature increase
  2. Volume increase
  3. No of molecules increase
  4. Change of stage from Solid to Liquid to Gas
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14
Q

What is the formula

of calculating

Change in Entropy?

A
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15
Q

What is the entropy change for

Reversible and Inreversible Process

according to the second law of thermodynamic?

A

·

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16
Q

Under what condition that

A process will have decrease in entropy?

A

A process with have decrease in entropy

only if energy is supplied

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17
Q

In what way do the entropy

of a universe (or a closed system)

change?

A

The entropy of a universe (or a closed system) is constantly increasing, never decreasing

18
Q

When will two systems

are said to be in same state?

A

Two systems are said to be in same state if they have the same pressure, same volume and same temperature and hence they have the same internal energy.

19
Q

What is

the Ideal Gas Law?

A
20
Q

What is the work done

of the cyclic process AB

In a PV graph?

A

work done = area within the loop

21
Q

What does the direction of

a cyclic process indicate?

A
22
Q

Characteristics of a

Isochoric or isovolumetric process

A
23
Q

Characteristics of a

Isobaric process

A
24
Q

Characteristics of

an Isothermal process

A
25
Q

Characteristics of

an Adiabatic Process

A
26
Q

How to

distinguish between

adiabatic and isothermal curve?

A
27
Q

What is the

difference between

Adiabatic Compression

and

Isothermal Compression?

A
28
Q

What is a

Carnot cycle ?

A

The Carnot cycle represents the cycle of processes for a theoretical heat engine with the maximum possible efficiency. Such an idealized engine is called a Carnot engine.

29
Q

What are the processes

in a Carnot Cycle ?

A
30
Q

What is

the Thermal efficiency

for a Carnot engine?

A
31
Q

What is

the Thermal efficiency

for a heat engine?

A
32
Q

Explain, in terms of the energy of its molecules, why the temperature of a pure substance does not change during melting.

A

Energy supplied during melting is used to break bond between water molecules, the energy supplied increase potential energy of molecules, and no increase in kinetic energy, so there is no change in temperature.

33
Q

State what is meant by an isothermal process

A

An isothermal process is a process in which temperature remains constant

34
Q

State what is meant by a

Isochoric or isovolumetric process?

A

Process in which the volume of the system does not change

35
Q

State what is meant by

an Isobaric process?

A

Process in which the pressure of the system is constant.

36
Q

State what is meant by

an Adiabatic Process?

A

Process in which there is no exchange of thermal energy between a system and it surroundings.

37
Q

Explain why it is not possible for an engine, operating in a cycle, to be 100% efficient

A

For an engine to be operating in a cycle, the system must return to original conditions (P, V, and T), to do that, some of the thermal energy absorbed by gas must be given off to the surroundings; hence not all thermal energy absorbed by gas can be converted to work; it is the second law of thermodynamics;

38
Q

Describe how the ideal gas constant R is defined.

A
39
Q

With respect to a gas, explain the meaning of the terms thermal energy and internal energy

A

Thermal energy (Q) is the energy transferred between two objects when are at different temperatures.

Internal energy (U) is the energy associated with the random, disordered motion of molecules, which comprises of the total potential energy and random kinetic energy of the molecules of the gas.

40
Q

Outline why an efficiency calculation is important for an engineer designing a heat engine.

A

So as to reduce energy loss; increase engine performance; effective use of fuel; etc.

41
Q

There are various equivalent versions of the second law of thermodynamics. Outline the benefit gained by having alternative forms of a law.

A

There are different modellings, allow testing in different ways and the laws can be applied in different situations.

42
Q

Define Thermal Energy

A

Energy transferred between two objects which are at different temperature