OG unit 2.4 Organic chemistry Flashcards
What are the 4 types of formulas?
- Molecular formula
- Structural formula
- Displayed formula
- Skeletal formula
Explain molecular formula
Shows atoms and how many of each
Explain structural formula
Shows atoms, how many of each, and how it’s connected
Explain displayed formula
Shows clearly which atoms present, how they arranged and all bonds
Explain skeletal formula
Uses zig-zag lines representing carbon chain
What code name for 1 carbon?
Meth…
What code name for 2 carbons?
Eth…
What code name for 3 carbons?
Prop…
What code name for 4 carbons?
But…
What code name for 5 carbons?
Pent…
What code name for 7 carbons?
Hept…
What code name for 9 carbons?
Non…
If the functional group has a double bond, what the suffix?
ene…
e.g.
Methene
If the functional group has chlorine, what the prefix?
Chloro
e.g.
1-chloro-butane
If the functional group has bromine, what the prefix?
Bromo
e.g.
1-bromo-butane
If the functional group has fluorine, what the prefix?
Fluoro
e.g.
1-fluoro-butane
If the functional group has iodine, what the prefix?
Iodo
e.g.
1-iodo-butane
If the functional group has amine (NH2), what both prefix & suffix?
P: Amino e.g. 1-amino-butane?
S: amine e.g. but-1-amine
If the functional group has hydroxyl (OH), what prefix & suffix?
P: Hydroxy e.g. i dunno
S: ol e.g. butanol
If the functional group has Carbonyl: Aldehyde/Ketone (C=O, double bond), what’s the suffix?
al/one
e.g.
butanal
propone
If the functional group has carboxyl (O=C-OH, mainly has hydroxyl and double bond with oxygen), what’s the suffix?
oic acid
e.g.
Ethanoic acid
If the functional group has nitrile (R-C≡N, ig the main thing is C≡N), what’s both prefix and suffix?
P: Cyano e.g. Cyano-1-Butane?
S: nitrile e.g. Butanol nitrile?
Tho what’s the structure and prefix for Methyl?
CH3, is just methyl
And structure and prefix for Ethyl?
Ch2CH3, is literally just ethyl
One sentence for alkanes?
Saturated hydrocarbons
One sentence for alkenes?
Functional group C=C
Unsaturated hydrocarbons
One sentence for alcohols?
Functional group -OH
One sentence for halogenoalkanes?
Functional group -F, -Cl, -Br, -I
One sentence for carboxylic acids?
Functional group -COOH
General formula for alkane?
CnH2n+2
e.g.
C20H42
General formula for alkene?
CnH2n
e.g.
C25H50
General formula for alcohol?
CnH2n+1OH
e.g.
C66H133OH
General formula for halogenoalkane?
CnH2n+1X
e.g.
C66H133F/Cl/Br/I
General formula for carboxylic acid?
CnH2n+1COOH
e.g.
C66H133COOH
Definition for isomers?
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Compounds having the same molecular formulae, but different structural formulae - i.e. a different arrangement of atoms in space
What are the 3 different types of isomerism?
- Chain isomerism
- Positional isomerism
- Functional group isomerism
What’s the difference for chain isomerism?
Ya got straight chain
CH3CH2CH2CH3
and ya got branched chain
CH3CH(CH3)CH3
What’s the difference for positional isomerism?
Ya got 1-bromopropane
CH3CH2CH2Br
and ya got 2-bromopropane
CH3CHBrCH3
Which functional group can positional isomerism be applied to?
Alcohols ig
What’s the difference for functional group isomerism?
Ya got propanal
CH3CH2COH
and finally propanone
CH3COCH3
When does geometric (E/Z) isomerism take place?
Atoms joining up in same order but different spatial arrangement
What would the E in E/Z isomerism correlate to?
E- entgegen (opposite side)
What would the Z in E/Z isomerism correlate to?
Z - zussamen (zame side)
When would 1,2-dibromoethene have a Z?
during C=C, both Br’s on top of both C’s (vice-versa for H)
(Z) - 1,2 - dibromoethene
When would 1,2-dibromoethene have an E?
during C=C, both Br’s on opposite positions diagonally on both C’s (vice versa for H)
(E) - 1,2 - dibromoethene
So what about E/Z isomerism for some complicated formula like:
1-bromo-2-chloro-1-fluoro-2-iodoethene?
Uhhhhhhhhh, based on atoms with highest atomic mass, which take priority, honestly look at page 16.
For the 4 main group 7 elements, order them from highest to lowest in terms of atomic mass (highest has more priority)
- Iodine
- Bromine
- Chlorine
- Fluorine
Why does b.p increase for longer chains?
Longer chains =
More VDW forces =
More energy needed to overcome forces =
Higher B.P.
What’s the effect of branching on boiling temperatures?
The more branches a molecule has, the lower it’s boiling temperature ig?
Ye go do past paper, or u can start unit 2.5 if u want
Who knows what he chooses