OChem 1 Nomenclature Flashcards
CH4 name
CH3CH3
CH3CH2CH3
CH3CH2CH2CH3
methane
ethane
propane
butane
C5H12 C6H14 C7H16 C8H18 C9H20 C10H22
Pentane Hexane Heptane Octane Nonane Decane
C11H24
C12H26
Undecane
Dodecane
Which carbon chain is taken as the backbone?
How is it determined which end is C1?
The longest
The direction in which the lowest set of numbers is obtained for the substituents
When naming compounds, how are substituents ordered in the name?
Alphabetically
Are prefixes like di, tri,, etc. alphabetized as substituents?
Are cyclo, iso, and neo alphabetized as substituents?
No
Yes
How do alkenes end in naming?
-ene
When identifying a carbon back bone, how to double bonds factor in?
The longest chain that contains the double bond or the greatest number of double bonds if multiple are present.
What is the common name for ethyne?
Acetylene
What do vinyl and aryl mean?
Vinyl is a bond directly attached to a double bonded C
Aryl is a bond away from that double bonded carbon
What are alkanes with halide substituent groups called?
Haloalkanes
or alkyl halide
What can ethyl chloride also be called? Its a haloalkane
Chloroethane
What is the ending for alcohols?
-ol
Methyl alcohol can also be called
2-propanol can also be called
Methanol
isopropyl alcohol
Molecules with two hydroxyl groups are called
What is there suffix
Diols (or glycols)
Diol
Diols with hydroxyl groups on adjacent carbons are called
Diols with hydroxyl groups on the same are carbon are
Vicinal
Geminal
Geminal diols are also called
Hydrates
What is the structure of ethers?
What is the prefix?
–O–
alkoxy
Where does numbering begin on the ring for cyclic ethers
What are three membered rings called?
It begins on the oxygen and proceeds to provide the lowest number for the substituents
Oxiranes. OR epoxides!
What is the suffix for aldehydes?
-al
What is the suffix for ketones
What its prefix in complex molecules
-one
oxo-
What is the suffix for carboxylic acids?
-oic
For simple compounds, how do you name amines?
What about for complex compounds?
Name the alkane and replace the final e with amine
Use the prefix amino-