nomenclature tidbits Flashcards
rule to check aromatic
2,6,10,14… pi electrons + conjugation
rule to check anti aromatic
4,8,12,…. pi electrons + conjugation
how to count lone pairs in furan
ignore 1 count 1 pair
how to count lone pairs in thiophene
ignore 1 count 1 pair
how to count lone pairs in pyrrole
ignore the pair
how to count lone pairs in pyridine
ignore the pair
stability order of a, aa, na
a>na>aa
test of unsaturation
add reddish brown bromine
if it turns colourless that indicates the presence of either a double or triple carbon bond
x degree carbon has _____ hydrogens
4-x
vinylic carbon
the carbon in a double bond itself
allylic carbon
the carbon attached to a vinylic carbon
priority of double vs triple bond
if position same double > triple
if the position of triple lesser then triple> double
priority of alkyl groups
propyl>ethyl>methyl
how to count in bicyclo
bridgehead to bigger ring to smaller ring
how to count in spiro
bridgehead to smaller to bigger