nomenclature tidbits Flashcards

1
Q

rule to check aromatic

A

2,6,10,14… pi electrons + conjugation

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2
Q

rule to check anti aromatic

A

4,8,12,…. pi electrons + conjugation

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3
Q

how to count lone pairs in furan

A

ignore 1 count 1 pair

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4
Q

how to count lone pairs in thiophene

A

ignore 1 count 1 pair

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5
Q

how to count lone pairs in pyrrole

A

ignore the pair

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6
Q

how to count lone pairs in pyridine

A

ignore the pair

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7
Q

stability order of a, aa, na

A

a>na>aa

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8
Q

test of unsaturation

A

add reddish brown bromine

if it turns colourless that indicates the presence of either a double or triple carbon bond

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9
Q

x degree carbon has _____ hydrogens

A

4-x

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10
Q

vinylic carbon

A

the carbon in a double bond itself

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11
Q

allylic carbon

A

the carbon attached to a vinylic carbon

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12
Q

priority of double vs triple bond

A

if position same double > triple

if the position of triple lesser then triple> double

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13
Q

priority of alkyl groups

A

propyl>ethyl>methyl

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14
Q

how to count in bicyclo

A

bridgehead to bigger ring to smaller ring

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15
Q

how to count in spiro

A

bridgehead to smaller to bigger

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