Nomenclature Flashcards
What are some inorganic carbon-containing compounds?
CO, CO2
Compounds containing ions CO3(2-), HCO3(-), CN(-), CNO(-)
Element carbon in form of graphite or diamond (giant covalent structures) is also inorganic
Saturated bonds
Each Carbon atom is bonded to four other atoms by single bonds. Alkanes are saturated hydrocarbons
Unsaturated bonds
Each carbon atom is bonded to other atoms by double or triple bonds. Alkenes are unsaturated hydrocarbons
Open chain/Aliphatic organic compounds
Contains chains of interlinked carbon atoms (eg butane)
Define homologous series
A group of compounds with
1) a general formula,
2) similar chemical properties and
3) showing a graduation in physical properties as a result of increase in size and mass of molecules
General method of preparation can be applied to all members of the series
Define functional group
An atom or group of atoms which gives a molecule its characteristic properties
Alkanes
No functional group
Structure: Saturated single carbon bonds
General formula: CnH2n+2
Suffix: -ane
Alkenes
Functional group: Carbon-carbon double bonds
Structure: carbon carbon double bond
General formula: CnH2n (NO n=1)
Suffix: -ene
Alcohols
Functional group: hydroxyl group
Structure: -OH group
General formula: CnH(2n+1)OH
Suffix: -ol
Carboxylic acids
Functional group: carboxyl group
Structure: O=C–OH or -COOH
General formula: CnH2nO2
Suffix: -noic acid
Numerical prefixes (1-10)
1) meth- 2) eth- 3)prop- 4)but- 5)pent- 6)hex- 7)hept- 8)oct- 9)non- 10)dec-
Define isomerism
Isomerism is the phenomenon in which 2 or more compounds possessing the same molecular formula exist in different forms due to different arrangement of atoms in their molecules. Compounds with same molecular formula but different structural formula are known as isomers.
Chain isomers
Isomers have different carbon chains/ skeletons but possess the same functional group and belong to the same homologous series.
Positional isomerism
Isomers have a substituent group in different positions in the same carbon skeleton. These isomers are chemically similar because they possess the same functional group.
Priority of functional groups in IUPAC naming
1) Carboxylic acid
2) alcohols
3) Alkenes
4) Alkanes