No1 Welding guy in the universe Flashcards
What are polymer?
MAcromolecules made by joining together thousands of small molecular units know as monomers
What is the degree of polymerisation?
number of units of polymers in a chain
Advantage of Synthetic polymers?
They have good flexibility, strength, resistivity, chemical internees, and properties. Due to its fine quality of high strength and elasticity, it is used in making ropes for climbing, nets, parachutes, fishing nets, etc.
What do reinforcing fibres do?
Increase tensile strength
Increase flexural modulus
What do conductive fillers do?
improves electrical and thermal conductivity
Advantage of thermoplastics over thermosets?
-if you raise the temperature of a thermoplastic over the melting point you can form them and if they solidify you can process them without degrading the material.
doesn’t apply to thermosets –> can’t be reprocessed.
/What are the 2 divisions in thermoplastics
Crystalline (ordered) and Amorphous (random) structure.
What are some important considerations for thermoplastic polymers?
- solid materials at room temperature but viscous liquids when heated
-they can be easily and economically shaped into products.
-the can be subjected to heating and cooling cycles without significant degradation.
What advantage of branched structure over linear?
-increases entanglement among molecules which makes them stronger in solid state and more viscous at a given temperature.
what does crystallinity refer to?
the degree of structural order of a solid.
what is glass transition temperature?
the temperature at which an amorphous solid become soft when you heat them up and become brittle when you cool it down
Why is glass transition temperature?
-because not all thermoplastic materials have a melting temperature, they only have (Tg). They will only become less viscous which will allow you to shape them.
What do bending polymers do?
the brittle behaviour of amorphous polymer will be reduced.
What are some characteristics of amorphous polymers?
-usually transparent
-low shrinkage
-low chemical resistance
-poor fatigue and wear
What are some important characteristics of crystalline polymers?
-sharp melting point
-usually opaque
-high shrinkage
-good fatigue and wear resistance
What are thermoset polymers?
-they are made from polymeric resins that are capable of forming chemical cross-links.
-thermosets are shaped and then chemically cross-linked. This is called curing
Differences between Thermoplastic and thermoset?
Thermoplastics
-a weak, straight chain that can be broken and hence reprocessed.
-they dissolve organic solvents
-on heating, they will soften and then melt
-the melting point is lower than the degradation point
-in solid state, their structure consists of hard crystalline regions together with elastic amorphous regions.
Thermoset
-strong chemical bonds which do not separate on heating
-Do not dissolve in organic solvents
-on heating they will char and not melt
-degradation point is lower than their melting point
-when solid their structure consists of thermosetting resin interspersed with reinforcing fibre.
How does the curing process work?
-provide energy, initiate chemically cross-linking. energy increase
What events occur during curing/cross-linking?
Gelation - liquids-to-rubber transition (increase in viscosity)
vitrification- liquid or rubber-to-glass transition.(still not 100% cured)
Advantage of polymer over metals/ceramics?
-easy processing and no post-processing required
-cost competitive
-less processing energy
-transparency
-low-density materials with good mechanical, chemical and electrical properties.
Why is injection moulding used?
it can use a wide range of thermoplastics and thermosets at a low scale.
plus good flexibility and good resolution.
High manufacturing rate
What are the 3 units of injection melding equipment?
Unit 1 - injection unit consists of the injection cylinder allows us to melt and inject the material into the mould cavity.
Unit 2 - 2 halfs of the mould
Unit 3 - clamping unit
What does the injection unit do?
-it heats the thermoplastic material to its appropriate viscosity and then forcefully injects it into the mould.