NMR spectroscopy Flashcards

1
Q

what is nmr based on?

A

bsaed on the magnetic properties of particular types of nuceli when placed into an external magnetic field

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2
Q

what are the 2 different types on nmr

A

magnetic resonance imaging - MRI, and NMR spectroscopy

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3
Q

which uses higher frequency? mri or nmr spectroscopy??

A

nmr spectroscopy

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4
Q

what is mri used for?

A

for diagnostic imaging of soft tissues (water detection)

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5
Q

do all atomic nuclei have nuclear spin and magnetic moment?

A

no

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6
Q

do some nuclei have magnetic properties?

A

yes, each spinning nucleus is like a mini magnet because of its magnetic moment the nucleus can interact with an externa;l magnetic field.. the nucleus can realign itself with the field or against the field, depends how they spin.

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7
Q

what do magnetic momentum on the nucleus depend on

A

depends on quantam properties of the atom

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8
Q

how do you know if your nucleus is magnetically active?

A

any atom with an odd number of neutrons or protons or both

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9
Q

what does spin number 0 mean in terms of magnetic properties?

A

the nuclei has an even mass number and an even atomic number, and therefore the nuclei is not magnetically active and can NEVER exhibit an NMR effect

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10
Q

what does the atomic mass number tell you?

A

the number of protons plus neutrons in its nucleus

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11
Q

what does the atomic number tells you?

A

the number of protons in the nucleus

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12
Q

what spin number do nuclei with even mass numbers but an odd atomic number have?

A

1, 2, 3

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13
Q

what is the spin number for nucleus with odd atomic numbers?

A

1/2, 3/2 etc

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14
Q

when is a nucleus magnetically silent?

A

when spin number is 0 aka when atomic number and atomic mass number are even

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15
Q

is carbon 12 magnetically active? and why

A

no bc has even atomic number and atomic mass

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16
Q

what is sensitivity usually measured against?

A

proton which has sensitivity of 1

17
Q

why do different nuclei have different resonance frequencies in the spectrum

A

bc they have different quantum properties

18
Q

what occuipies higher energy level - spins aligned with the field or spins aligned against the field?

A

spins aligned against the field

19
Q

what occuipies lower energy level - spins aligned with the field or spins aligned against the field?

A

spins aligned with the field