NMR Flashcards
nuclear spin (I)
The nuclei of many atoms have a property called nuclear spin (I)
Nuclear spin is really a purely quantum phenomenum
angular momentum
Any spinning object has angular momentum.
In classical physics a body can have any value of angular momentum.
This isn’t true at the atomic level.
Nuclear spin is quantised
- The spin of subatomic particles (nuclei, electrons…) can only have certain fixed values.
- We can think of this as ‘only particular rotation speeds are possible’.
- We say that the angular momentum is quantised. This is the basis of all of quantum theory used to describe motion at the atomic level.
quantum number, I
The spin is characterised by a quantum number, I
Even mass nuclei composed of even numbers of protons and neutrons have ____ spin
Even mass nuclei composed of even numbers of protons and neutrons have zero spin ( I = 0 ). So 12C, 16O have ZERO spin.
Nuclei with even number of protons and odd number of neutrons have ____ spin
Nuclei with even number of protons and odd number of neutrons have 1/2 integer spin
Nuclei with odd numbers of protons and neutrons have ______ spin values.
Nuclei with odd numbers of protons and neutrons have integer spin values.
Nuclear spin is associated with
a magnetic field.
If I >0 then
the spinning nucleus generates a magnetic field
The resulting spin-magnet of I >0 has a
magnetic moment (μ) proportional to the spin.
If we put a bar magnet in a magnetic field
it will align with the field
If we put a spinning magnet in a magnetic field
will line up at an angle and rotate around the field direction