nmr Flashcards

1
Q

how many H NMR environments are there GRAMINE

A

7 + NH

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2
Q

what are the H NMR shifts in descending order FOR GRAMINE

A

B>E>D>C>A>F>G

Rusul:

C>F>E>D>B>G>H

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3
Q

WHAT ARE THE GRAMINE C NMR SHIFTS IN DESCENDING ORDER

A

8>3>1>5>4>6>7>2>9>10

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4
Q

HOW MANY ENVIRONMENTS IN GRAMINE CNMR

A

10

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5
Q

how many c NMR environments are in anisole?

A

5

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6
Q

what are the anisole of the c NMR environments in descending order?

A

directly attached to O > ortho to O > para to O > Metha to O > the CH3 on the O.

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7
Q

how many environments in h nmr of anisole

A

4

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8
Q

state the H NMR environments in descending order?

A

H ortho to O > H para to O > H Metha to O > H3 on OCH3

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9
Q

WHAT IS THE C NMR FOR ETHANOL IN DESCENDING ORDER

A

C CLOSEST TO O > THE OTHER C

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10
Q

HOW MANY POSSIBLE H NMR SHIFTS IS IN ETHANOL

A

3

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11
Q

STATE THE ORDER FOR H NMR OF ETHANOL.

A

CH2 > CH3

OH IS BETWEEN 3 AND 2

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12
Q

WHAT IS THE STRECH FOR C-N

A

1000 - 1250 STRONG

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13
Q

WHAT IS THE STRECH FOR C-H

A

2850 - 3000 STRONG

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14
Q

WHAT IS THE STRECH FOR C-H AROMATIC

A

> 3000 WEAK AND POINTY

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15
Q

C=C ON AROMATICS IR?

A

1475 -1600

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16
Q

WHAT ARE MANNIC REACTIONS?

A

The Mannich reaction is a three-component organic reaction that involves the amino alkylation of an acidic proton next to a carbonyl functional group by formaldehyde and a primary or secondary amine or ammonia.

17
Q

WHAT REACTION IS A MANNIC REACTION?

A

The Mannich reaction is an example of nucleophilic addition of an amine to a carbonyl group followed by dehydration to the Schiff base.

18
Q

WHAT IS THE SCHIFF BASE?

A

The Schiff base is an electrophile which reacts in the second step in an electrophilic addition with a compound containing an acidic proton (which is, or had become an enol).