Nitrogen compounds Flashcards
1
Q
R/C CN to amine
A
Lialh4 in dry ether
2
Q
R/C halogeno to amine
A
Excess conc nh3 in ethanol heat in sealed tube
3
Q
R/C amine to amide
A
Acyl chroride
4
Q
R/C protonated nh3+
A
Hcl aq
5
Q
R/C phenylamine to tri sub X
A
X2 aq
6
Q
R/C nitrobenzene to phenylamine
A
Sn in conc hcl heat followed by naoh aq
7
Q
R/C amino acids to form peptide bonds
A
*Only bonds between 2 amino acid can be called peptide bonds
8
Q
R/C hydrolysis of esters / amide
A
Basic hydrolysis: naoh aq
Acidic hydrolysis: hcl aq
9
Q
R/C Reduction of esters and amides
A
Lialh4
Esters: 2 alcohol fn group
Amines amides: lose the c=o to and replace with 2h
