Ni Flashcards

1
Q

3 states of matter

A

Solids liquids gases

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2
Q

Gases have no what (2)

A

Fixed volume or shape and move around freely

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3
Q

Solids and liquids particles are

A

Tightly packed together

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4
Q

What condense and freeze at sufficiently low temperatures

A

Molecular element

Compounds

Monatomic elements

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5
Q

For freeze and condense what must occur

A

Forces of attraction between discrete atoms or molecules

=VDWF

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6
Q

What are LDF

A

Forces of attraction that can operate between all atoms & molecules

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7
Q

Are they weak or strong LDF

A

Much weaker than all other types of bonding

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8
Q

Strength of LDF depends upon what

A

•No of e
More e the stronger intermolecular forces

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9
Q

Why are LDF formed?

A

As a results of electrostatic attraction between TD and induced dipoles & induced dipoles causes by movement of E in atoms or molecules

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10
Q

Dipoles occur when

A

A dipole in a molecule occurs when opposite ends of atoms, molecules or compounds have different e charged

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11
Q

What affect can dipoles have on their neighbouring atoms

A

Attract atoms e to other end so another dipole is made

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12
Q

The uneven distribution of electrons are only

A

Temporary

Temporary due to small and temporary they are very weak

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13
Q

The negative end of an atom will what (dipole)

A

The repel -E on adjacent atoms causing T.D called induced dipoles

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14
Q

So what’s the positive end like of a dipole

A

It’s attracted to the - end of the dipole on a nearby atom

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15
Q

Non polar covalent bonds

A

•occur between non metals with same E.N
•The more e, the stronger LDF, the more energy to break
•LDF are their intermolecular forces

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16
Q

Covalent bond occurs

A

Between non metal atoms with slightly different electronegative values

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17
Q

In a polar covalent bond what isn’t shared equally

A

•Electrons aren’t shared equally due to EN values

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18
Q

Where do the electrons sit closer to

A

The atom with the higher electronegative values as it has a stronger attraction for shairrd pair of e

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19
Q

What does difference in electronegative values cause

A

Atoms to be slightly charged

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20
Q

The - dipole in molecules is electrostaticlly

A

Attracted to the + Dipole

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21
Q

Covalent bond definition

A

Electrostatic force of attraction of positively charged non-metal nuclei for a shaired pair of electrons

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22
Q

In polar dipoles what are present (bonding)

23
Q

What is a permanent dipole?

A

A PD is a Permanent persistent uneven distribution of electrons due to their diffuclut in e.n between atoms in a molecule, resulting in asymmetrical charged dipoles

24
Q

1 atom attracts what in a PD

A

Attracts e more than the other becoming more -

25
The more E.N the more?
More polar
26
Types of VDWF
HB PDPDI LDF
27
Hydrogen bond is a form of what
PDPDI
28
What are hydrogen bonds
Electrostatic forces of attraction between molecules that contain these highly polar bonds
29
Hydrogen bonds are when we see
O-H N-H F-H
30
Bonds consisting of hydrogen atom bonded to an atom of
Strongly electro negative elements As mentioned n,O,F
31
A hydrogen bond is the strongest buy weaker compared to an
Covalent bond
32
Anomalous boiling points of ammonia eg water and fluoride are a result of
HB
33
Metallic bonding contains what’s
Metals
34
Is metal bonding strong or weak
Strong
35
Structure of metallic binding
Electrostatic attraction between the positive ions & the sea of delocalised electrons
36
Why are metallic boiling points high
Due to large amount of energy needed to break the string metallic bonds Except mercury
37
Across a period metallic bonding
The nuclear charge increases causing the electrons become strongly attracted to the nucleus. This means more energy is required to break the attractions hence the higher melting and boiling points.
38
Metallic Bonding down period
Down a group the number of electron shells increases meaning the outer electrons are further away from the nucleus therefore less strongly attracted This week attractions require less energy to be broken, hence the decrease in melting and boiling points
39
Why are monotonic single atoms?
Due to them having full outer electron shells making them stable
40
What is a covalent networks structure
A covalent network structure contains a giant lattice of non-metals atoms bonded by strong covalent bonds
41
3 elemental covalent structuresb
Silicon = 4 atoms = spider Boron = 3 atoms = hexagon Carbon= Diamond & graphite
42
Why do elements covalent bonds have a very high melting and boiling point
Due to large need to break strong covalent bonds that require large amounts of energy to breaks
43
Why is graphite different in structure
Because: •carbon atoms form layers of hexagonal rings • these rings are held together by LDF, as the forces between them are weaker then covalent bonds it allows layers to slide across each other.
44
What are molecules And what are covalent molecular substances made out of
•Group of atoms helps together by covalent bonds Covalent molecular substances are made up of LDF between molecules that are weak •
45
Ionic bond structure
•formed between at least 1 metal and non metal ion
46
What is ionic bonding
It’s the e.s attraction between a positively charged metal ion and a negatively charged non metal ion
47
Difference in electronegativity ruling for polar
Polar bond formed if difference in e.n is between 0.1-0.8
48
Ionic bonding fomed when EN
Difference greater then 1.8 These are ballpark figutes
49
Viscosity
Measure of how thick a liquid is or how slow it moves
50
Slower IMF viscosity results in
Slows liquid, greater viscosity This mean substances with HB will be most viscous LDF= less viscosity V= no of e depending
51
Solubility meaning
Ability of a substance to dissolve in a substance
52
Aquesos and non aquesos is what
Polar Non-polar
53
“Like to dissolve like”
Polar substances dissolve in polar solvents
54
What are polar compounds attracted to each other
Due to PD.