new learning - phases mostly Flashcards

1
Q

average kin energy of an ideal gas

A

KE= 3/2 nRT

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2
Q

average speed of an ideal gas

A

urms =√3RT/M (in kg/mol)

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3
Q

density from ideal gas law

A

p = PM/RT

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4
Q

daltons law

A

Pa= Pt Xa

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5
Q

vapor pressure

A

pressure exerted y evaporated particles above the surface of the liquid

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6
Q

solubility will _______ if partial pressure of gas increases

A

increase

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7
Q

how to relate 2 gases speed with their M

A

r1/r2 = √M2/M1

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8
Q

% difference

A

change in value / original value x 100

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9
Q

to correct deviations from ideal gas law

A

correction values

PV= nRT

(P + n^2a/V^2) (V-nb) = nRT

so if a is large, P would need to decrease to compensate
if b is large, V need to increase to compensate

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10
Q

is condensation rate affected by solutes in solvents?

A

NO, only the evaporation rate is affected

  • vapor pressure depression when solutes are in solvent
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11
Q

Raoult’s law

A

vapour pressure depression caused by solutes in solvent

VPa = Xa VP’a

new VP is mole fraction x pure solvent VP

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12
Q

does pure solvent evaporate faster than solute solution

A

yes, this goes hand in hand with BP elevation - if VP is depressed, than more heat isrequired to get VP to reach atmospheric pressure

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13
Q

boiling point elevation

A

change in T = imKb

  • m is molality (mol/kg)
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14
Q

osmotic pressure

A

ii= i M(mol/L)RT

osmotic pressure is the “sucking” pressure

opposes hydrostatic pressure

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15
Q

dilution

A

M1V1=M2V2

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16
Q

when is enthalpy equivalent to heat

A

usually on MCAT, when pressure is constant (isobaric)

17
Q

heat capacity

A

just cxm (bigger objects have more heat capacity)

18
Q

STP

A

0 C —> 273 K and 1atm

19
Q

non-associative learning

A

sensitivation and habituation

20
Q

operant conditioning vs classical conditioning

A

operant–> associating behaviour with consequences, clasical –> associating unconditioned stim to unconditioned response ( involuntary droooling to bell)

21
Q

ratio vs interval

A

of responses, interval = time

22
Q

fovea vs macula

A

fovea is IN the macula and is the highest vision resoltuion

23
Q

HH equation

A

pH= pKa + log [A-]/[HA]

24
Q

ka, kb and kw

A

kw= ka kb

25
Q

pka pkb and 14

A

pka + pkb = 14

26
Q

weak acids

A

ka = less than 1 –> they dont fully dissociate

27
Q

what’s the trick to solving “calculate the pH of a 1.00M solution of acetic acid”

A

identify that is not a strong acid so it will not fully dissociate

ICE table

and then assume that x «&laquo_space;1

ka= X^2/1.00 –> solve for x

28
Q

why if an acid is really strong is its conjugate base weak?

A

bc kb x ka = kw

so if ka if large than kb must be small indicating a weak base

29
Q

strong strong

A

neutralize + water

30
Q

self-serving bias

A

i failed test bc not enough sleep, was late bc traffic

but I got a good grade bc I studied hard, and im on time bc thats who I am

31
Q

cognitive bias

A

systemic error in thinking - affects decisions and judgments ( you believe something)

32
Q

groupthink

A

Groupthink occurs in groups when individual thinking or individual creativity is lost or subverted to stay within the comfort zone of the consensus view.

group members modify their opinions to match what they believe is the group consensus

33
Q

group polarization

A

move to a more extreme point of view

34
Q

zeff

A

how much attraction the outermost electron feels to the positive nucleus