Natural food pigments Flashcards

1
Q

State the food sources of anthocyanins

A

Fruits, vegetables and microorganisms.

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2
Q

State the food sources of flavonoids

A

Fruits, vegetables and microorganisms.

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3
Q

State the food sources of melanins

A

Shellfish, dried fruits, vegetables and microorganisms.

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4
Q

Give 6 natural food pigments

A
1- anthocyanins
2- flavonoids
3- melanins
4- chlorophyll
5- heme
6- carotenoids
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5
Q

Give three differences between chlorophyll a and b

A

a is :

  • darker
  • as a methyl group on C3 instead of a formyl
  • absorbs at different wavelenghts
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6
Q

complete : under acidic and heat conditions, chlorophyll will lose the ____ and become ___ which is ___ (color)

A

Mg2+
Pheophytin
dull green

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7
Q

What color is pheophytin?

A

dull green

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8
Q

What color is pheophorbide?

A

brown

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9
Q

What color is chlorophyllide?

A

light green

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10
Q

complete : under acidic and heat conditions, chlorophyllide will lose the ____ and become ___ which is ___ (color)

A

Mg2+
pheophorbide
brown

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11
Q

complete : under the action of chlorophylase, chlorophyll will lose the ____ and become ___ which is ___ (color)

A

phytol
chlorophyllide
light green

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12
Q

complete : under the action of chlorophylase, pheophytin will lose the ____ and become ___ which is ___ (color)

A

phytol
pheophorbide
brown

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13
Q

complete : Fe also covalently linked to ____ in a ____ residue in globin (protein);

A

nitrogen

histidine

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14
Q

What are the differences between chlorophyll and heme?

A
  1. globin vs phytol side chain
  2. liposoluble vs hydrosoluble
  3. color red vs green
  4. Fe central atom vs mg
  5. side chain is linked to the fe in heme while it is on one of the pyroll in chlorophyll
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15
Q

What are the similarities between chlorophyll and heme?

A
  1. tetrapyroll ring
  2. metal ion as central atom
  3. massive side chain
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16
Q

why does cooking change the color of heme?

A

because the iron is oxidized (Fe2+ to Fe3+) and the proteins are denatured

17
Q

When heme is red, the Fe is the ___ state and it is linked to ___.

A

reduced (Fe2+) and linked to oxygen.

18
Q

The oxymyoglbin is ___ (color)

A

red

19
Q

What is the name of the pigment formed when nitrite oxide is linked to the iron of the heme

A

nitrosomyoglobin

20
Q

What is the state of the iron in nitrosomyoglobin?

A

reduced (Fe2+)

21
Q

Ferric is when the Fe is in the state __ +

A

3+

22
Q

Ferrous is when the Fe is in the state ___ +

A

2+

23
Q

when Mb is in the presence of oxygen for a short time it will become ____ and the iron state will be ___

A

Mb-O2 (oxymyoglobin)

Fe2+

24
Q

When Mb is in presence of H2O without oxygen is will be ___ (color) and the iron state will be ___

A

purple / blue

reduced (Fe2+)

25
Q

when Mb is in the presence of oxygen for a long time it will become ____ and the iron state will be ___

A

metmyoglobin (Met-Mb)

ferric or oxidized (Fe3+)

26
Q

What is the name of the brown pigment created when you cook cured meats

A

nitrosohemichrome

27
Q

in nitrosomyoglobin the iron is in the state ___

A

Fe2+

28
Q

nitrosohemichrome, the iron is in the state ___

A

Fe3+

29
Q

Using redeucing agents containing ___ can lead to the formation of __

A

Sulfur (cystein)

sulfmyoglobin