naming aromatic compounds Flashcards

1
Q

which groups are shown as prefixes to benzene?

A
  • alkyl groups < 7 carbons
  • halogens
  • nitro groups

eg ethylbenzene, chlorobenzene, nitrobenzene

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2
Q

how are compounds with one substituent group named?

A
  • benzene considered parent
  • eg chlorobenzene, ethylbenzene
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3
Q

what is meant by benzene ‘substituent’?

A

when benzene is attached to an alkyl chain with a functional group or an alkyl chain with 7+ carbons
- prefix phenyl is used

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4
Q

give examples of molecules where the prefix phenyl is used

A
  • phenylthanone
  • phenyloctane
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5
Q

how are groups counted if all groups are the same?

A
  • pick any group as 1
  • take shortest path around ring
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6
Q

what is the benzene called when attached to another compound?

A

phenyl
- this is the prefix!!
- eg phenylethene

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7
Q

what is a phenol?

A

benzene with OH group

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8
Q

what does benzoic acid look like?

A
  • benzene ring
  • COOH group
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9
Q

what does 2 hydroxybenzoic acid look like?

A
  • benzene ring
  • COOH group on C1
  • OH group on C2
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10
Q

which has priority: COOH or OH?

A

OH

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11
Q

how are prefixes added to benzene for short alklyl chains, halogens, nitro groups?

A
  • alphabetical
  • di tri tetra
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12
Q

what does phenylamine look like?

A
  • benzene ring
  • NH2
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13
Q

what does benzaldehyde look like?

A
  • benzene ring
  • CHO
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14
Q

when is the prefix amino used for NH2?

A

when CHO or COOH take priority or there is more than one

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15
Q

when is the prefix hydroxy used for OH?

A

when CHO or COOH take priority or there is more than one

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16
Q

draw 3 chlorobenzoic acid

A
  • benzene
  • COOH on C1
  • Cl on C3
17
Q

draw 1,4 diaminobenzene

A
  • benzene
  • NH2 on C1 and C4
18
Q

draw 2,4,6 trinitrophenol

A
  • benzene
  • OH on C1
  • NO2 on C2, C4 and C6
19
Q

draw phenylethene

A
  • benzene
  • ethene on C1
20
Q

draw phenylpropanone

A
  • benzene
  • propanone (ketone with 3Cs)
21
Q

draw 1,2,4 tribromobenzene

A
  • benzene
  • Br on C1, C2 and C4
22
Q

draw 2,4,6 trichloromethylbenzene

A
  • benzene
  • Cl and CH3 on alternating carbons
23
Q

draw 2,3 dichlorobenzanoic acid

A
  • benzene
  • COOH on C1
  • Cl on C2 and C3