Monosaccharides Flashcards

1
Q

Aldose

A

monosaccharide with a carbon backbone chain with a aldehyde group
simplest- glyceraldehyde

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2
Q

Ketose

A

monosaccharide with a carbon backbone and a ketone group

simplest- dihydroxyacetone

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3
Q

Anomeric carbon

A

Carbon that the aldehyde or ketone group is attached to.

Direction of the OH attached to it determines if its alpha or beta

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4
Q

D isomer

A

OH on the right of the highest numbered chiral carbon

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5
Q

L isomer

A

OH on the left of the highest numbered chiral carbon

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6
Q

Alpha anomer

A

OH down

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7
Q

Beta anomer

A

OH Up

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8
Q

Sugar acid

A

The oxidation (loss of H) of aldehyde group in a monosaccharide

Oxidation at C1 - yield adonic acids (“onic” - gluconic acid)
Oxidation at C6- yield uronic acids (“uronic” -glucuronic acid)
Oxidation at C1 & C6- yield aldaric acids (“aric” - glucaric acid)

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9
Q

Sugar alcohols

A

Are formed by the reduction (gain of H) of a monosaccharide.
Each carbon has a OH group attached

Examples- Sorbitol, mannitol, xylitol

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10
Q

Deoxy-sugars

A

reduction of other positions in a monosaccharide with one or more hydroxyl group (OH) replaced by hydrogens (H)

Example- Deoxyribose

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11
Q

Amino sugars

A

one or more hydroxyl groups of a monosaccharide is replaced with a amino group (contains nitrogen)

Example- Chitin (in exoskeletons)

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12
Q

Glycosides

A

is any molecule in which a sugar group (glycon) is bonded through its anomeric carbon to another group (non-sugar(aglycon) via a glycosidic bond

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