Monosaccharides Flashcards
Aldose
monosaccharide with a carbon backbone chain with a aldehyde group
simplest- glyceraldehyde
Ketose
monosaccharide with a carbon backbone and a ketone group
simplest- dihydroxyacetone
Anomeric carbon
Carbon that the aldehyde or ketone group is attached to.
Direction of the OH attached to it determines if its alpha or beta
D isomer
OH on the right of the highest numbered chiral carbon
L isomer
OH on the left of the highest numbered chiral carbon
Alpha anomer
OH down
Beta anomer
OH Up
Sugar acid
The oxidation (loss of H) of aldehyde group in a monosaccharide
Oxidation at C1 - yield adonic acids (“onic” - gluconic acid)
Oxidation at C6- yield uronic acids (“uronic” -glucuronic acid)
Oxidation at C1 & C6- yield aldaric acids (“aric” - glucaric acid)
Sugar alcohols
Are formed by the reduction (gain of H) of a monosaccharide.
Each carbon has a OH group attached
Examples- Sorbitol, mannitol, xylitol
Deoxy-sugars
reduction of other positions in a monosaccharide with one or more hydroxyl group (OH) replaced by hydrogens (H)
Example- Deoxyribose
Amino sugars
one or more hydroxyl groups of a monosaccharide is replaced with a amino group (contains nitrogen)
Example- Chitin (in exoskeletons)
Glycosides
is any molecule in which a sugar group (glycon) is bonded through its anomeric carbon to another group (non-sugar(aglycon) via a glycosidic bond