Moles Flashcards

1
Q

Mole

A

The amount of substance containing as many particles as there are C atoms in exactly 12g of C – 12

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2
Q

Avogadros constant

A

The number of particles per mole of a substance (6.02 x 10 23)

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3
Q

Molar mass

A

The mass per mole of a substance (gmol-1)

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4
Q

(Molecules/atoms/ions…interchangeable)
Particles =

A

Moles x Na (avogadro)

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5
Q

Moles (solid)

A

Mass/Mr

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6
Q

Moles (gas)

A

V/24
dm3

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7
Q

Cm3 -> dm3

A

/1000

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8
Q

Moles (solution)

A

c x v
(Dm3)

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9
Q

Molar gas volume (rule)

A

One mole of any gas occupies a volume of 24 dm3 at RTP and has a molar gas volume of 24.0dm3mol-1

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10
Q

Solution

A

Substances dissolved in a specific volume of water (solute in solvent )

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11
Q

Stoichiometry

A

Reacting molar ratios
(Numbers in balanced equation)

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12
Q

Atom Economy

A

Measure of the proportion of reactant atoms that become part of the desired product in the balanced chemical equation

Mr desired product/Total product Mr. (x100)

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13
Q

Addition reaction atom economy

A

Always 100% (add to 1 compound)

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14
Q

Benefits of high atom economy

A

-low waste - expensive to separate + dispose + environment effects
-reactants expensive
-limited raw materials - sustainability
-some catalysts developed to increase AE.

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15
Q

% yield

A

% To indicate how much product is made in reaction compared to how much could have been made
Actual/theoretical (x100)

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16
Q

Water of crystallisation

A

Water molecules that are bonded into the
crystalline structure of a hydrated compound, giving the compound a crystalline appearance

17
Q

Hydrated

A

When water of crystallisation is present in a crystal compound
(H2O joined to ionic compound so (CuSO4.xH2O)

18
Q

Opposite of hydrated

19
Q

Empirical formula

A

The simplest whole number ratio of atoms of each element present the compound

20
Q

Empirical formula method

A

1) divide % or mass by Mr
2) divide by smallest number (ratio)
3) x to make whole numbers
4) formula

21
Q

Molecular formula

A

The actual number of atoms of each element in a molecule

22
Q

Molecular formula method

A

1) empirical formula
2) find Mr of each using empirical (empirical mass)
3) molar mass/ empirical mass
4) multiply empirical by answers

23
Q

How is Mr found

A

Mass spectroscopy machine
(= to molecular ion peak furthest to the right)

24
Q

% of water crystallisation

A

Mr atoms of element/Mr compound (x100)

25
Formula from water of crystallisation
1) %/mass 2/ find moles 3) molar ratio 4) formula
26
Experimental determination of water moles
1) measure mass of hydrated salt 2) heat - evapourate h20 attached 3) measure new mass = anhydrous salt 4) mass lost = water mass 5) find moles of each 6) ratio -> formula of hydrated salt
27
Balancing combustion equation
1) balance c 2) h 3) o
28
Reheating to constant mass
1)Mass of empty Crucible 2) mass of salt plus Crucible 3) add loose lid (prevent loss of solid, allow water vapour loss) 4) cool + reweigh 5) reheat + re weigh 6) repeat to constant mass All water has been removed Mass= anhydrous salt
29
Conservation of mass
Mass equal before and after reaction So can be used to find unknown elements, use Mr of known, find moles, find Mr unknown
30
rule when scaling moles
moles decrease by same proportion as volume
31
scaling concentration
1. find moles from original solution 2. n/v (new diluted volume) to find c of dilute solution
32
steps to find the concentration of a given ion in a mixture using moles
1. find the total moles of each solution, n 2. for each compound: n x the number of [x] ion present in the compound 3. add the moles of the ion found above 4. use total volume of mixture + total moles of [x] ion in c=n/v
33
how to identify the limiting reactant from volumes
test quantities of each reacted using using molar ratios
34
if asked to find total gas volume after a given reaction where not all reactant gas is used up, remember to consider...?
any product gases - add to final vol