Moles Flashcards

1
Q

Mole

A

The amount of substance containing as many particles as there are C atoms in exactly 12g of C – 12

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2
Q

Avogadros constant

A

The number of particles per mole of a substance (6.02 x 10 23)

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3
Q

Molar mass

A

The mass per mole of a substance (gmol-1)

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4
Q

(Molecules/atoms/ions…interchangeable)
Particles =

A

Moles x Na (avogadro)

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5
Q

Moles (solid)

A

Mass/Mr

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6
Q

Moles (gas)

A

V/24
dm3

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7
Q

Cm3 -> dm3

A

/1000

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8
Q

Moles (solution)

A

c x v
(Dm3)

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9
Q

Molar gas volume (rule)

A

One mole of any gas occupies a volume of 24 dm3 at RTP and has a molar gas volume of 24.0dm3mol-1

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10
Q

Solution

A

Substances dissolved in a specific volume of water (solute in solvent )

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11
Q

Stoichiometry

A

Reacting molar ratios
(Numbers in balanced equation)

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12
Q

Atom Economy

A

Measure of the proportion of reactant atoms that become part of the desired product in the balanced chemical equation

Mr desired product/Total product Mr. (x100)

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13
Q

Addition reaction atom economy

A

Always 100% (add to 1 compound)

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14
Q

Benefits of high atom economy

A

-low waste - expensive to separate + dispose + environment effects
-reactants expensive
-limited raw materials - sustainability
-some catalysts developed to increase AE.

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15
Q

% yield

A

% To indicate how much product is made in reaction compared to how much could have been made
Actual/theoretical (x100)

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16
Q

Water of crystallisation

A

Water molecules that are bonded into the
crystalline structure of a hydrated compound, giving the compound a crystalline appearance

17
Q

Hydrated

A

When water of crystallisation is present in a crystal compound
(H2O joined to ionic compound so (CuSO4.xH2O)

18
Q

Opposite of hydrated

A

Anhydrous

19
Q

Empirical formula

A

The simplest whole number ratio of atoms of each element present the compound

20
Q

Empirical formula method

A

1) divide % or mass by Mr
2) divide by smallest number (ratio)
3) x to make whole numbers
4) formula

21
Q

Molecular formula

A

The actual number of atoms of each element in a molecule

22
Q

Molecular formula method

A

1) empirical formula
2) find Mr of each using empirical (empirical mass)
3) molar mass/ empirical mass
4) multiply empirical by answers

23
Q

How is Mr found

A

Mass spectroscopy machine
(= to molecular ion peak furthest to the right)

24
Q

% of water crystallisation

A

Mr atoms of element/Mr compound (x100)

25
Q

Formula from water of crystallisation

A

1) %/mass
2/ find moles
3) molar ratio
4) formula

26
Q

Experimental determination of water moles

A

1) measure mass of hydrated salt
2) heat - evapourate h20 attached
3) measure new mass = anhydrous salt
4) mass lost = water mass
5) find moles of each
6) ratio -> formula of hydrated salt

27
Q

Balancing combustion equation

A

1) balance c
2) h
3) o

28
Q

Reheating to constant mass

A

1)Mass of empty Crucible
2) mass of salt plus Crucible
3) add loose lid (prevent loss of solid, allow water vapour loss)
4) cool + reweigh
5) reheat + re weigh
6) repeat to constant mass
All water has been removed
Mass= anhydrous salt

29
Q

Conservation of mass

A

Mass equal before and after reaction
So can be used to find unknown elements, use Mr of known, find moles, find Mr unknown

30
Q

rule when scaling moles

A

moles decrease by same proportion as volume

31
Q

scaling concentration

A
  1. find moles from original solution
  2. n/v (new diluted volume) to find c of dilute solution
32
Q

steps to find the concentration of a given ion in a mixture using moles

A
  1. find the total moles of each solution, n
  2. for each compound: n x the number of [x] ion present in the compound
  3. add the moles of the ion found above
  4. use total volume of mixture + total moles of [x] ion in c=n/v
33
Q

how to identify the limiting reactant from volumes

A

test quantities of each reacted using using molar ratios

34
Q

if asked to find total gas volume after a given reaction where not all reactant gas is used up, remember to consider…?

A

any product gases - add to final vol