Molecular properties of matter Flashcards
Avogadro’s number
number of molecules in a mole of material
Na = 6.022x10^23 molecules/mol
a given material is made up of
identical elementary entities
Gas made of a large number of molecules
motion can be treated statistically
Molecules are in continuous and rapid random motion
they collide elastically with each other and with the walls of the vessel
Pressure originates from
the summation of large numbers of reaction forces as the molecules bounce off the walls.
Molecules occupy
a negligible fraction of the total volume
long-range forces of attraction between the particles are
negligble
pV =
1/3Nm(vrms)^2
1/2m(vrms)^2 =
3/2kT
Equation of state for an ideal gas
pV = nRT
R = 8.3J/mol.K.
Ktr
the total translational KE of the gas molecules
E =
Ktr/N = (3/2nRT)/N = 1/2m
= mean square velocity
KE per molecule
= 3/2 kbT
KE per mole
= 3/2kT