Molecular polarity Flashcards

1
Q

What makes a structure asymmetricla

A

Center is exposed OR there are atoms of different electonegativies bonding around the central atom

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2
Q

What types of intermolecular forces are there between neutral molecules

A
  • London Dispersion (LDF)
  • Dipole-Dipole forces (DD)
  • Hydrogen bonding
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3
Q

How many electrons does boron take

A

6

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4
Q
# of atoms boded to central atom: 3
# of unshared electron pairs on central atom: 1
A

Trigonal pyramidal

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5
Q
# of atoms boded to central atom: 2
# of unshared electron pairs on central atom: 0
A

Linear

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6
Q

London dispersion forces (LDF)

A
  • Atrraction caused by a temporary, uneqeual distribution of electrons, which cause a momentary positive/negative area on a molecule
  • Made stronger by more electrons in the molecule
  • Found in all atoms and molecules ( even noble gases)
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7
Q

What makes molecules stick together

A

Forces that exist between molecules called intermolecular forces

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8
Q
# of atoms boded to central atom: 1
# of unshared electron pairs on central atom: 1
A

Linear

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9
Q
# of atoms boded to central atom: 1
# of unshared electron pairs on central atom: 2
A

Linear

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10
Q

What makes a molecule polar

A
  1. It has polar bonds

2. It is asymmetrical (center is exposed or atoms of dif electronegativities bonded to center)

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11
Q

How do you mix substances

A

You need two substances with the same type/strength of IMF
EX: Only things with LDF dissolve/mix in things with only only LDF
-DD forces interact well with other DD forces (Hyrdogen bonding is a stong DD force)

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12
Q

What makes the central exposed

A

It has unshared electrons

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13
Q

How to tell difference in strength for DD

A

-HB the strongest. Otherwise whichever has greater electronegativity difference

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14
Q
# of atoms boded to central atom: 3
# of unshared electron pairs on central atom: 0
A

Trigonal planar

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15
Q

Exeptions to the 8 electron rule

A

B only takes 6 valence electrons

H only take 2 valence electrons (1 Bond)

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16
Q
# of atoms boded to central atom: 4
# of unshared electron pairs on central atom: 0
A

Tetraheda

17
Q

Dipole-Dipole forces (DD)

A
  • Attraction caused by permanently establish dipoles on molecules (the partial positive and partial negative charge)
  • Found in polar molecules
  • Stronger with a greater electronegativity difference
18
Q

Hydrogen bonding

A

-Extremely stong dipole
-Found when hydrogen is bonded to N, O, or F directly
and it has unshared electrons

19
Q
# of atoms boded to central atom: 2
# of unshared electron pairs on central atom: 2
A

Bent

20
Q

What does strong IMF mean

A
  • Higher boiling point
  • Higher melting point
  • Lower vapor pressure (less evaporation)
21
Q

How many electrons does Barrilium take

A

4

22
Q
# of atoms boded to central atom: 2
# of unshared electron pairs on central atom: 1
A

Bent

23
Q

The stronger the IMF….

A

The more the molecules want to stick together

24
Q

What is the substance mixing rule

A

-Like dissolves like

Polar dissolves polar, nonpolar dissolves nonpolar

25
Q
# of atoms boded to central atom: 1
# of unshared electron pairs on central atom: 3
A

Linear

26
Q

How to tell difference in strength for LDL things

A

-The one with more total electrons is stronger

27
Q

What makes bond polar

A

If electronegativity is different

28
Q

How many electrons does hydrogen take

A

2-> one line