Molecular geometry Flashcards

1
Q

Electronegativity

A

This is the measure of the amount of attraction that an atom is able to exert upon a shared electron pair within a chemical bond

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2
Q

VSEPR

A

Valence Shell Electron Pair Repulsion - there are numerous forces that exist with the molecule due to electron repulsions that occur as a result of the proximity of the bonding pairs and lone pair electrons within the individual atoms’ orbitals. These are called intramolecular repulsion forces or steric stresses.

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3
Q

Lone pair to lone pair repulsions

A

Strong

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4
Q

Lone pair to bond pair repulsions

A

Intermediate

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5
Q

Bond pair to bond pair repulsions

A

Weak

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6
Q

Angular

A

104,5-degree bond angle. Consists of 2 lone pairs that repel the 2 bond pairs with intermediate strength. Example: H2O (water)

2:2

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7
Q

Pyramidal

A

107,3-degrees bond angle. Consists of 1 lone pair that repels the 3 bond pairs with accumulative strength.
Example: NH3 (ammonia)

3:1

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8
Q

Tetrahedral

A

109-degrees bond angle. Consists of 4 bond pairs with the most steric stress in the molecule even though it has the lowest strength individually. Example: CH4 (methane)

4:0

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9
Q

Linear

A

180-degree bond angle. Consists of 1 or 2 bond pairs. Typical in diatomic molecules. Examples: HF, HCL, HBr and HI.

1 or 2:0

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10
Q

Trigonal planar

A

120-degree bond angle. Consists of 3 bond pairs. They are perfectly symmetrical. Example: BF3

3:0

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