Molecular geometry Flashcards
Electronegativity
This is the measure of the amount of attraction that an atom is able to exert upon a shared electron pair within a chemical bond
VSEPR
Valence Shell Electron Pair Repulsion - there are numerous forces that exist with the molecule due to electron repulsions that occur as a result of the proximity of the bonding pairs and lone pair electrons within the individual atoms’ orbitals. These are called intramolecular repulsion forces or steric stresses.
Lone pair to lone pair repulsions
Strong
Lone pair to bond pair repulsions
Intermediate
Bond pair to bond pair repulsions
Weak
Angular
104,5-degree bond angle. Consists of 2 lone pairs that repel the 2 bond pairs with intermediate strength. Example: H2O (water)
2:2
Pyramidal
107,3-degrees bond angle. Consists of 1 lone pair that repels the 3 bond pairs with accumulative strength.
Example: NH3 (ammonia)
3:1
Tetrahedral
109-degrees bond angle. Consists of 4 bond pairs with the most steric stress in the molecule even though it has the lowest strength individually. Example: CH4 (methane)
4:0
Linear
180-degree bond angle. Consists of 1 or 2 bond pairs. Typical in diatomic molecules. Examples: HF, HCL, HBr and HI.
1 or 2:0
Trigonal planar
120-degree bond angle. Consists of 3 bond pairs. They are perfectly symmetrical. Example: BF3
3:0