Molecular Geometry Flashcards

1
Q

steric # = 2

0 lone pairs

A

linear

180

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2
Q

steric # = 3

0 lone pairs

A

trigonal planar

120

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3
Q

steric # = 3

1 lone pair

A

bent (trigonal planar)

less than 120

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4
Q

steric # = 4

0 lone pairs

A

tetrahedral

109.5

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5
Q

steric # = 4

1 lone pair

A

trigonal pyramidal

less than 109.5

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6
Q

steric # = 4

2 lone pairs

A

bent (angular; tetrahedral)

less than 109.5

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7
Q

steric # = 5

0 lone pairs

A

trigonal bipyramidal

90 or 120

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8
Q

steric # = 5

1 lone pair

A

seesaw

less than 90 or less than 120

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9
Q

steric # = 5

2 lone pairs

A

T-shaped

less than 90

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10
Q

steric # = 5

3 lone pairs

A

linear

180

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11
Q

steric # = 6

0 lone pairs

A

octahedral

90

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12
Q

steric # = 6

1 lone pairs

A

square pyramidal

less than 90

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13
Q

steric # = 6

2 lone pairs

A

square planar

90

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14
Q

how to find steric number

A

SN = (# bound to central atom) + (# of lone pairs on central atom)

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15
Q

e- pair number vs molecular geometry

A

e- pair number represents the standard geometry of steric #

molecular geometry incorporates lone pair when needed

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16
Q

how to tell if a bond is polar

A

electronegativity greater than 0.6

but less than 2.0

17
Q

how to tell if a molecule is polar

A

if the molecule is either asymmetric by having lone pairs on a central atom or by having atoms w/ different electronegativities

typically must have polar bonds to be a polar molecule (?)

18
Q

paramagnetic

A

unpaired e-

attraction to magnetic field

19
Q

diamagnetic

A

paired e-

no attraction to magnetic field

20
Q

bonding orbital

A

high electron density between atoms

21
Q

antibonding orbital

A

high electron density not located between atoms

22
Q

bond order formula

A

1/2 [(# of bonding e-) - (# of antibonding e-)]

23
Q

when does MO mixing occur

A

when there are less than 11 ve-, sigma 2p is before pi 2p

Li2, Be2, B2, C2, N2