Module 7: Organic Chemistry Flashcards

1
Q

hydrocarbons

A

compounds made of hydrogen and carbon

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2
Q

types of hydrocarbons

A
  1. aromatic hydrocarbons (contain 1 or more benzene rings)
  2. aliphatic compounds (other hydrocarbons where C atoms are bonded to chains or non-aromatic rings)
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3
Q

hydrocarbon chain compounds are further classified into…

A

families based on the individual C-C bonds

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4
Q

alkanes

A

hydrocarbon compound with all C-C single bonds
- saturated compound

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5
Q

alkenes

A

hydrocarbon compounds with at least one C-C double bond
- unsaturated compound

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6
Q

alkynes

A

hydrocarbon compounds with at least one C-C triple bond
- unsaturated compound

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7
Q

cyclic hydrocarbons and types

A

hydrocarbon compounds where C atoms join to form a closed ring structure
- saturated or unsaturated

*C-C single bond = cycloalkanes
*C-C double bond = cycloalkenes
*C-C triple bond = cycloalkynes

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8
Q

saturated compounds

A

compounds with the same bond type

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9
Q

unsaturated compounds

A

compounds with multiple bond types

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10
Q

representing organic molecules

A

*molecular formula
e.g. C3H8, (identifies number of carbon atoms, not arrangement)

*structural formulae
–> expanded formula (shows each atom and its bond with other atoms)
–> condensed formula (shows overall arrangement, condenses alkyl ground e.g. CH3)
–> skeletal structure
(carbon chain arrangement, not atoms)

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11
Q

homologous series. provide example and formula

A

a group of compounds with the same general formula e.g. Cn H2n+2 (alkanes, alkenes, alkynes)

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12
Q

straight-chain alkalines

A

the first 10 alkanes are called straight chain alkanes because the C atoms are joined in a continuous chain

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13
Q

who names hydrocarbons.

A

IUPAC (International Union of Pure and Applied Chemistry)

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14
Q

why is it important to have universally understood names for chemical compounds?

A

Creates a single scientifically accepted name for an organic compound. Ensures consistency despite language differences.

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15
Q

substituents

A

Other atoms or groups of atoms attached to the main (parent) chain

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16
Q

if a substituent is a carbon group, what is it called?

A

alkyl group

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17
Q

naming conventions

A

Prefix (no. of C):
Meth = 1
Eth = 2
Prop = 3
But = 4
Pent = 5
Hex = 6
Hept = 7
Oct = 8

Suffix (nature of bonds):
Single bonds = ane
Double bonds = ene
Triple bonds = yne
alcohol = anol
aldehydes = anal
ketones = one
carboxylic acid = noic acid
amine = amine
amide = amide

Carbon atoms in branched chain (substituents):
Methyl = 1 C
Ethyl = 2 C…

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18
Q

functional groups

A

specific group of atoms within a molecule that undergoes change in a reaction, it gives the molecules their characteristic properties

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19
Q

organic chemistry

A

chemistry of carbon and its compounds

20
Q

general molecular formulas of functional groups

A

alkane - C(n) H(2n+2)
alkene - C(n) H(2n)
alkyne - C(n) H(2n-2)
hydroxyl (alcohol) - C(n) H(2n+1)

21
Q

what is the functional group of alcohol

A

hydroxyl (alcohol) - R-OH

22
Q

distinguish between primary, secondary and tertiary alcohol

A

P - OH –> 1C –> 1C
S - OH –> 1C –> 2C
T - OH –> 1C –> 3C

23
Q

uses of alcohol

A

fuels, alcoholic drinks, solvents, disinfectant

24
Q

positional vs chain isomers

A

P - position of -OH
C - rearrangement of carbon chain (e.g. 1 less carbon on chain so 1 substituent added)

(same molecular structure)

25
carbonyl compounds and examples
compounds containing a C atoms double bonded to oxygen atom e.g. aldehydes and ketones
26
aldehydes (alkanal)
hydrocarbons which contain a carbon-oxygen double bond at a terminal carbon on the carbon chain
27
types of carbon chains
chain, branched, cyclic, aromatic
28
what can you say about substances with the same functional group?
you can expect them to undergo similar types of reactions as the functional group is the most reactive part of the molecule
29
functional group of aldehydes and ketones
carbonyl C=O
30
ketones
hydrocarbons which contain a carbon-oxygen double bond at a non-terminal carbon on the carbon chain
31
what types of compounds are aldehydes and ketones
carbonyl compounds
32
types of alcohols
primary, secondary, tertiary
33
primary alcohol
-OH → 1C → 1C
34
secondary alcohol
-OH → 1C → 2C
35
teritary alcohol
-OH → 1C → 3C
36
functional groups of carboxylic acids
COOH (oxygen double bonded to carbon with an additional hydroxl group off the same carbon)
37
homologous series have the same...
general formula and functional group
38
Amine
Amine functional group (NH2) attached to one or more C atoms → Found as amino acids, the building blocks of proteins
39
Amide
NH2 attached to a C atom double bonded to an oxygen → Formed when an amine reacts with a carboxylic acid
40
Halogenated organic compounds
→ hydrocarbons containing halogen atoms →H atom replaced with a halogen atom → F, Cl, Br, I are commonly used
41
isomer
A series of compounds that have the **same molecular formula** but **different structural formulae**
42
isomer types
* chain * positon * function
43
chain isomers
Same molecular formula but different arrangement of C skeleton | * Different C chain length * Include 1+ side branches
44
position isomers
Same molecular formula and carbon skeleton but different location of functional group | * Change location of bond or functional group
45
Functional group isomers
Same molecular formula and carbon skeleton but structural differences of functional group that changes the series it belongs to | * Differing position of atoms gives different series
46
do isomers have the same physcial properties?
no, because the structure affects the strength of intramolecular and intermolecular bonding thus affecting physical properties e.g. the attractive force of neighbouring molecules in 1-butanol is stronger than that of 2-butanol
47