Module 7: Acid Stimulation Flashcards

1
Q

What is stimulation?

A

the act of either removing the skin damage (matrix acidizing) or bypassing the damage and creating a negative skin (hydraulic fracturing)

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2
Q

When referring to acid stimulation or matric stimulation, are the injection pressure above or below the fracture pressure of the formation?

A

BELOW

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3
Q

Name 6 types of damage that acid stimulation can attempt to remediate?

A
  1. Clay
  2. Paraffin Asphaltenes
  3. Emulsions
  4. Wettability Issues
  5. Scale
  6. Particulate damage
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4
Q

When does the presence of clay become an issue in a reservoir?

A

if it is present in large enough volumes and will react in a a detrimental manner to the fluid flowing through the pore space.

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5
Q

What are the 4 most common clays that account for most the of the formation damage seen in oil and gas wells?

A
  1. Kaolinite
  2. Smectite (montmorillinite)
  3. Illite
  4. Chlorite
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6
Q

What kind of formation damage can be seen from Kaolinite clay?

A

large particle sizes and does not bond well to host grain, making It a migrating and plugging issue

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7
Q

What kind of formation damage can be seen from Smectite Clay?

A

swelling problems, sensitive to water. High micro-porosity that traps migrating particles and binds water to the host grain.

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8
Q

What kind of formation damage can be seen from Illite Clay?

A

same as smectite and also fibres can trap micro size debris and may also break off and migrate.

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9
Q

What kind of formation damage can be seen from Chlorite clay?

A

serves as a collection point for migrating debris and contains high levels of iron which may precipitate as iron hydroxide.

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10
Q

When are paraffins and asphaltenes deposited?

A

during the production of crude oil

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11
Q

How is the precipitation of paraffins triggered?

A

loss of pressure, loss of temperature and/or loss of light end hydrocarbons.

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12
Q

Where is the most common are for the precipitation of paraffins?

A

production tubing. But can also form on the perforations in cases where nearby pressure-depleted reservoirs experience dry gas cycling.

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13
Q

What are the 3 common forms asphaltenes are found in?

A
  1. Hard coal like substance
  2. Blackened sludge or rigid film emulsion
  3. In combination with paraffins
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14
Q

What leads to the precipitation of alphaltenes?

A

anything that takes away the resin or breaks the stability of the micelle.

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15
Q

What is an emulsion and what does it consist of?

A

combination of 2 or more immiscible fluids that will not molecularly disperse into one another. consists of an inside phase and an outside phase (interface).

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16
Q

What are some common solids that stabilize emulsions?

A
Silt
Sand
Clays
Cuttings
Metal flakes
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17
Q

What is wettability?

A

the fluid type and behaviour of that fluid that coats the grain of the formation and acts as its connate saturation component.

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18
Q

Formation’s wettability can be?

A

Water-wet
Oil-wet
Neutral

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19
Q

In order to recover the most hydrocarbons, it is the aim of most treatments to change the formation wettability to and how is this achieved?

A

Water-wet

Achieved by using surfactants

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20
Q

Will change to wettability affect ultimate recovery and relative permeability?

A

YES!!

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21
Q

When does scale usually occur?

A

from the mixing of incompatible waters

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22
Q

What are the 3 most common scales?

A
  1. Calcite
  2. Calcium sulfate
  3. Barium Sulfate
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23
Q

How can the 3 scales be removed?

A

calcite- HCL
Calcium sulfate- not removed by acid
Barium sulfate- mechanical removal is necessary

24
Q

What is particulate damage?

A

fines blocking of pore throats is caused by invasion of drilling mud, cements, kill fluids, and dirty water during drilling, completion, and production of a well.

25
Name 4 methods of diagnosing damage?
DST Inflow Performance Analysis Fluid Analysis Reservoir Logging methods
26
What 3 things should you ensure you eliminate as possible well performance failure prior to considering an acid stimulation?
1. Artificial lift method correct 2. if the well is a water injector, is it possible that hydrocarbons could have been injected causing emulsion or phase blocking 3. is there fill covering the producing interval
27
What are the 2 kinds of acid stimulation?
Matrix acidizing | Hydraulic fracture stimulation
28
Matric acidizing will succeed in doing what to the skin S=?
S=0, will only return the skin to neutral state and will not aid in yielding stimulation
29
What happens when skin damage is present in a well?
it causes additional pressure drop in the system which would not appear if the well was undamaged.
30
The radius over which the skin occurs is usually small, how small?
up to 10cm
31
What is the typical skin factors range?
50(very badly damaged) to -5 (stimulated well). It is impossible for a skin factor to be less than -8.
32
What 2 ways can wellbore radius be increased?
underreaming or fracturing
33
Why is acid stimulation without fracturing favourable?
increases permeability of the reservoir near the wellbore by removing any part of the grain cemetation that is acid soluble.
34
In general, what 4 things are acid stimulation suitable for?
1. High permeability rocks that incurred damage during drilling, completion or production 2. Very soft, unproppable formations 3. Very thick acid soluble zones 4. Supplementing a hydraulic fracture treatment.
35
What are the 4 acids used in oilfield applications?
``` Hydrochloric acid (HCL) Hydrofluoric-hydrochloric acid blends (HF-HCL), known as MUD ACID. Acetic Acid (CHCOOH) Formic Acid (HCOOH) ```
36
What is the most common acid and what kind of formations does it react with?
HCL, reacts with limestone and dolomite
37
What formation is mud acid commonly used in?
sand reservoirs
38
Why is HF-HCL acid blend known as mud acid?
because it works well at eliminating damages caused by mud filtrate invasion during drilling.
39
Formic and acetic acids are known as what and are used why?
organic acids and are used because of their slow reaction times and ease of inhibition. Commonly used with HCL.
40
The design of acid additive systems depend on what 5 things?
1. Temp 2. Formation 3. Rock type 4. hydrocarbon trap 5. damage mechanism
41
Name 6 acid additives
1. Corrosion inhibitor 2. Surfactants 3. Mutual solvents 4. Alcohols 5. Anti-sludge additives 6. iron control/clay control
42
corrosion increased as acid strength increases? T or F?
TRUE
43
Corrosion inhibitors work to form a barrier on tubular surfaces which interferes with what?
electrochemical reactions
44
Why are surfactants used?
to change or maintain wettability by controlling surface and interfacial tension
45
What are the 3 types of surfactants, explain
1. Anionic- used as a non emulsifying, retarding and cleaning agent 2, Cationic- used as non-emulsifiers, corrosion inhibitors and bacteriacides 3. Nonionic- used as a non emulsifiers and foaming agent
46
Why are alcohols considered a cost effective alternative to surfactants?
have surfactant type qualities, can reduce the amount of water in a formation
47
What do anti-sludge properties prevent?
negative reaction between acid and crude oil that cause heavy end precipitate which can be permanent.
48
Does iron accelerate or retard sludge formation?
accelerate and stabilizes emulsions
49
What are some specialty acids used for carbonate stimulation and why are they used?
Foamed acid- used for fluid diversion or for acid fracturing Emulsified Acid- used to increase viscosity for fracturing Surfactant Gelled Acid- Used for acid fracturing
50
What 4 things to design acid treatments include?
1. Tubing Pickling 2. Acid washes 3. Matrix acid jobs 4. Acid diversion
51
Why is tubing pickling used?
to remove iron, pipe dope, scale, etc from tubing prior to injecting acid into the zone
52
Can Pickle acid come in contact with the formation?
NOOOO
53
Why are acid washed used?
to was acid soluble residue or scale from pumps or tubulars. to wash perforations to clean up damage from perforating
54
Why are matrix acid jobs used?
removes near wellbore damage, treat zone that cannot be perforated
55
In a matrix acid job, acid is injected in to the zone above or below fracturing pressure?
BELOW
56
Why are acid diversions used?
to deliver live acid to a larger area of the formation and to provide deeper penetration into the formation
57
Name 3 typical diversion agents?
``` ball sealers (temporarily plug the perfs) chemical diverters (benzoic acid, naphthalene and rock salt) foam fills ```