module 6: acids and bases Flashcards

1
Q

Properties of Acids

A

Sour
Produce H+ when dissolved in water
pH below 7
Corrosive

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2
Q

Properties of Bases

A

Bitter
Produce OH- when dissolved in water
pH above 7
Caustic

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3
Q

Types of Bases

A

Metal hydroxides
Metal oxides
Metal carbonates/hydrogen carbonates

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4
Q

Strength of an acid/base

A

Extent of ionisation/dissociation in water

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5
Q

Strong acids

A

HCl, HBr, HI, H2SO4, HNO3

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6
Q

Strong bases

A

Group 1 and 2 metal hydroxides

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7
Q

Dissociation of an acid

A

HA(aq) + H2O(l) ⇌ H3O+(aq) + A-(aq)

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8
Q

Monoprotic

A

A substance which is capable of donating one proton (H+)

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9
Q

Polyprotic

A

A substance which is capable of donating multiple protons (H+)

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10
Q

Dissociation of a base

A

B(aq) + H2O(l) ⇌ BH+(aq) + OH-(aq)

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11
Q

Methyl orange

A

Low pH = red
High pH = yellow
pH of colour change = 3.1-4.4

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12
Q

Litmus

A

Low pH = red
High pH = blue
pH of colour change = 4.5-8.3

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13
Q

Bromothymol blue

A

Low pH = yellow
High pH = blue
pH of colour change = 6.0-7.6

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14
Q

Phenolphthalein

A

Low pH = colourless
High pH = pink
pH of colour change = 8.2-10.0

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15
Q

Method for Preparing and Testing Cabbage Indicator

A
  1. Shred cabbage leaves, place in beaker, covered with distilled water.
  2. Boil cabbage until all red pigment is removed from the leaves.
  3. Allow to cool and pour liquid into a clean beaker.
  4. Prepare samples of various acids, bases, and neutral substances.
  5. Drop cabbage solution into each sample, recording any colour change
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16
Q

Limitations of Indicators

A

Can slightly distort the original pH of solutions
Only provides a range of pH
May change colour at different pH levels is temperature exceeds 25C
The way people observe colour is different

17
Q

Acid-Metal reaction

A

acid + metal → salt + hydrogen gas

18
Q

Acid-Carbonate reaction

A

acid + carbonate → salt + water + carbon dioxide

19
Q

Acid-Base reaction

A

acid + base (hydroxide/oxide) → salt + water

20
Q

Lavoisier’s Theory

A

(1) An acid is a substance that contains oxygen
(-) Could not explain why metal oxides were not acidic

21
Q

Davy’s Theory

A

(2) Acids contain replaceable hydrogen, bases neutralise acids
(-) Could not explain why other hydrogen compounds were not acidic

22
Q

Arrhenius Acid

A

A substance that ionises in water to produce hydrogen ions

23
Q

Arrhenius Base

A

A substance that dissociates in water to produce hydroxide ions

24
Q

Advantages of Arrhenius Theory

A
  • Explains how neutralisation occurs between acids and bases with the net ionic equation between hydrogen and hydroxide ions
  • Explains the relative strength of acids and bases based on their extent of ionisation or dissociation in water
25
Q

Limitations of Arrhenius Theory

A
  • Suggests that non OH containing substances are not a base
  • Fails to explain the behaviour of acids and bases in solid or gas phases
  • Does not explain why reactions between acids and bases do not produce salt solutions that are neutral