module 6: acids and bases Flashcards
Properties of Acids
Sour
Produce H+ when dissolved in water
pH below 7
Corrosive
Properties of Bases
Bitter
Produce OH- when dissolved in water
pH above 7
Caustic
Types of Bases
Metal hydroxides
Metal oxides
Metal carbonates/hydrogen carbonates
Strength of an acid/base
Extent of ionisation/dissociation in water
Strong acids
HCl, HBr, HI, H2SO4, HNO3
Strong bases
Group 1 and 2 metal hydroxides
Dissociation of an acid
HA(aq) + H2O(l) ⇌ H3O+(aq) + A-(aq)
Monoprotic
A substance which is capable of donating one proton (H+)
Polyprotic
A substance which is capable of donating multiple protons (H+)
Dissociation of a base
B(aq) + H2O(l) ⇌ BH+(aq) + OH-(aq)
Methyl orange
Low pH = red
High pH = yellow
pH of colour change = 3.1-4.4
Litmus
Low pH = red
High pH = blue
pH of colour change = 4.5-8.3
Bromothymol blue
Low pH = yellow
High pH = blue
pH of colour change = 6.0-7.6
Phenolphthalein
Low pH = colourless
High pH = pink
pH of colour change = 8.2-10.0
Method for Preparing and Testing Cabbage Indicator
- Shred cabbage leaves, place in beaker, covered with distilled water.
- Boil cabbage until all red pigment is removed from the leaves.
- Allow to cool and pour liquid into a clean beaker.
- Prepare samples of various acids, bases, and neutral substances.
- Drop cabbage solution into each sample, recording any colour change
Limitations of Indicators
Can slightly distort the original pH of solutions
Only provides a range of pH
May change colour at different pH levels is temperature exceeds 25C
The way people observe colour is different
Acid-Metal reaction
acid + metal → salt + hydrogen gas
Acid-Carbonate reaction
acid + carbonate → salt + water + carbon dioxide
Acid-Base reaction
acid + base (hydroxide/oxide) → salt + water
Lavoisier’s Theory
(1) An acid is a substance that contains oxygen
(-) Could not explain why metal oxides were not acidic
Davy’s Theory
(2) Acids contain replaceable hydrogen, bases neutralise acids
(-) Could not explain why other hydrogen compounds were not acidic
Arrhenius Acid
A substance that ionises in water to produce hydrogen ions
Arrhenius Base
A substance that dissociates in water to produce hydroxide ions
Advantages of Arrhenius Theory
- Explains how neutralisation occurs between acids and bases with the net ionic equation between hydrogen and hydroxide ions
- Explains the relative strength of acids and bases based on their extent of ionisation or dissociation in water
Limitations of Arrhenius Theory
- Suggests that non OH containing substances are not a base
- Fails to explain the behaviour of acids and bases in solid or gas phases
- Does not explain why reactions between acids and bases do not produce salt solutions that are neutral