Module 5.2 Flashcards
Define the term standard lattice enthalpy
The enthalpy change when one mole of ionic lattice is formed from its gaseous ions under standard conditions
Give an example reaction equation that shows standard lattice enthalpy
Sodium ion(g) + Chloride ion(g) → NaCl(s)
Calcium ion(g) + Oxygen ion (g) → CaO(s)
Define the term standard enthalpy change of formation
The enthalpy change when one mole of compound is formed from its elements in their defined standard states under standard conditions
Give an example reaction equation that shows standard enthalpy change of formation
K(s) + 1/2F2(g) → KF(s)
2C(s) + 3H2(g) + 1/2O2 (g) → C2H5OH
Define the term standard enthalpy change of atomisation
The enthalpy change when one mole of gaseous atoms is from from its elements in their defined standard states under standard conditions
Give an example reaction equation that shows standard enthalpy change of atomisation
K(s) → K(g)
1/2Br2 (s) → Br2(g)
Define the term first ionisation energy
The amount of energy required to remove one mole of electrons from one mole of gaseous atoms.
Give an example reaction equation that shows first ionisation energy
Na → Na^+ + e^-
O → O^+ + e^-
Define the term second ionisation energy
The amount of energy that accompanies the formation of one mole of gaseous 2+ ions from 1 mole of gaseous 1+ iions
Give an example reaction equation that shows second ionisation energy
Na^+ → Na^2+ + e^-
O^+ → O^2+ + e^-
Define the term first electron affinity
The enthalpy change that accompanies the formation of one mole of gaseous 1^- ions from gaseous atoms
Give an example reaction equation that shows first electron affinity
Cl(g) + e^- → Cl^-(g)
1/2F2(g) + e^- → F^-(g)
Define the term second electron affinity
The enthalpy change that accompanies the formation of one mole of gaseous 2^- ions from one mole of gaseous 1^- ions.
Give an example reaction equation that shows first electron affinity
Cl^-(g+ e^- → Cl^2-(g)
F^-(g) + e^- → F^-(g)
What are the standard conditions
100kPa and 298Kelvin
Is Lattice Enthalpy always endothermic or always exothermic?
Always EXOTHERMIC
What factors determine lattice enthalpy?
Ionic size and Ionic charge
How does a decreasing ionic size affect lattice enthalpy?
Smaller ions have a higher charge density. This means that the ions attract to each other more strongly. Therefore, more energy is released when bonds form. Therefore, the smaller the ionic radius, the bigger the lattice enthalpy
How does an increasing ionic size affect lattice enthalpy?
Bigger ions have a smaller charge density. This means that the ions attract to each other more weakly. Therefore, less energy is released when bonds form. Therefore, the bigger the ionic radius, the smaller the lattice enthalpy
How does an increasing ionic chargevaffect lattice enthalpy?
The higher the charge on the ions, the more energy is released when an ionic lattice forms. This is due to the stronger electrostatic forces between the ions. Therefore, the higher the ionic charge, the larger the lattice enthalpy
How does a decreasing ionic charge affect lattice enthalpy?
The smaller the charge on the ions, the less energy is released when an ionic lattice forms. This is due to the weaker electrostatic forces between the ions. Therefore, the smaller the ionic charge, the smaller the lattice enthalpy
Higher lattice enthalpy means a higher or lower negative value?
Higher
What factors affect ionisation energy?
Nuclear charge
Shielding
Atomic radius
Greater nuclear charge = _______ ionisation energy. Why?
Higher. This is because the outermost electrons are more strongly attached to the nucleus. Therefore, more energy is needed to remove one mole of electrons from a gaseous atom.
Greater shielding = _______ ionisation energy. Why?
Lower. This is because the outermost electrons are less strongly attached to the nucleus. Therefore, less energy is needed to remove one mole of electrons from a gaseous atom.
Greater atomic radius = _______ ionisation energy. Why?
Lower. This is because the outermost electrons are further away from the nucleus. Therefore, they are less strongly attached to the nucleus. This means that less energy is needed to remove one mole of electrons from a gaseous atom.
What is a Born-Haber Cycle and what is it used to do?
A Born-Haber cycle is an indirect cycle which allows us to find lattice enthalpy for a reaction.
What does a generic Born-Haber cycle look like?
TOP
First IE
↑ Electron affinity
Atomisation ↓
↑ ↓
Atomisation ↓
↓ ↓
Formation - Formation - Formation - Formation
BOTTOM
What thing must you include in a Born-Haber cycle?
State symbols
Direction of arrows
Diatomic?
Name of steps (e.g. enthalpy change of atomisation)
What do you times by 2 or 3 etc
- Exothermic or endothermic (Watch out for 2nd electron affinity)
- Balancing charges
In the Born-Haber cycle for a group 1 and group 7 element, do we times anything by 2 or 3?
NO
In the Born-Haber cycle for a group 2 and group 6 element, do we times anything by 2 or 3? If yes, what?
NO
In the Born-Haber cycle for a group 3 and group 6 element, do we times anything by 2 or 3? If yes, what?
Times by 2 : First IE, 2nd IE and 3rd IE (as there are 2 moles of Group 3 element)
Times by 3: First Electron Affinity and Second electron affinity (as there are 3 moles of Group 4 element)
In the Born-Haber cycle for a group 2 and group 7 element, do we times anything by 2 or 3? If yes, what?
Times by 2: Atomisation of the halogen and the first electron affinity (as there are 2 moles of group 7 element by 1 mole group 2 element)
Give the formula for Lattice Enthalpy
LE =
- Electron affinity - First IE - Enthalpy change of atomisation of element X - Enthalpy change of atomisation of element Y + Enthalpy change of formation
Define enthalpy change of solution
The enthalpy change when one mole of a solute dissolves in water under standard conditions
Give 3 example reactions equations that show the enthalpy change of solution
NaCl(s) → Na^+(g) + Cl^-(g)
MgF2l(s) → Mg^2+(g) + F^-(g)
MgCO3(s) → Mg^2+(g) + CO3^2-(g)
What formula can we use to find the enthalpy change of solution?
Enthalpy change of solution =
Enthalpy change of hydration of X + Enthalpy change of hydration of Y - Standard lattice enthalpy
*Be careful with signs, take time. This is easy marks.
Define enthalpy change of hydration
The enthalpy change when one mole of gaseous ions is dissolved in water under standard conditions
Give 3 example reactions equations that show the enthalpy change of hydration
Na^+(g) → Na^+(aq)
K^+(g) → K^+(aq)
O^2-(g) → O^2-(aq)
Is enthalpy change of hydration, exothermic or endothermic?
Exothermic because bonds are being made with water
Is enthalpy change of solution, exothermic or endothermic?
It can be either
What happens when an ionic solid dissolves in water?
When an ionic solid dissolves in water, the bonds between the ions BREAK to give gaseous ions. This is ENDOTHERMIC. Furthermore, bonds between the gaseous ions and the WATER are made (forms aqueous ions). This is EXOTHERMIC.
Give the Born- Haber cycle for a hydration/solution containing cycle
TOP
Gaseous atoms - Gaseous atoms - Gaseous atoms
↓ ↓
↓ ↓ Enthalpy change of hydration for X
↓ ↓
↓ ↓ Enthalpy change of hydration for Y
↓ ↓
↓ ↓ Enthalpy change of solution
↓ ↓
Ionic solid - Ionic solid - Ionic solid - Ionic solid
BOTTOM
How can you calculate lattice enthalpy from a Born-Haber cycle that consists of enthalpy change of hydration and enthalpy change of formation
LE + Solution = Hydration of X + Hydration of Y
Therefore LE = Hydration of X + Hydration of Y - Solution
If in the Born-Haber cycle that consists of enthalpy change of hydration and enthalpy change of solution, there are 2 moles of something, what do you do to its enthalpy change of hydration?
Times that by 2
What factors affect the enthalpy change of hydration?
Ionic size and Ionic charge
How does a decreasing ionic size affect affect enthalpy change of hydration?
Smaller ions have a higher charge density than bigger ions. They ATTRACT the water molecules BETTER and have a more exothermic enthalpy change of hydration. Therefore, the smaller the ion, the larger its enthalpy change of hydration (due to having a higher charge density and better water attraction
How does an increasing ionic size affect affect enthalpy change of hydration?
Bigger ions have a smaller charge density than smaller ions. They ATTRACT the water molecules WEAKER and have a less exothermic enthalpy change of hydration. Therefore, the bigger the ion, the smaller its enthalpy change of hydration (due to having a smaller charge density and weaker water attraction
How does an increasing ionic charge affect affect enthalpy change of hydration?
Ions with a higher ionic charge are better at ATTRACTING water molecules than those with lower charges. This means that the electrostatic attraction between the ion and the water molecule is STRONGER. This means that more energy is released when bonds are made, giving them a more EXOTHERMIC enthalpy change of hydration. Therefore, the higher the ionic charge, the higher the enthalpy change of hydration
How does a decreasing ionic charge affect affect enthalpy change of hydration?
Ions with a lower ionic charge are bad at ATTRACTING water molecules than those with higher charges. This means that the electrostatic attraction between the ion and the water molecule is WEAKER . This means that less energy is released when bonds are made, giving them a less EXOTHERMIC enthalpy change of hydration. Therefore, the lower the ionic charge, the lower the enthalpy change of hydration
Define the term entropy
A measure of dispersal in a system, which is greater, the more disordered the system
Higher entropy means?
More disorder (likely to be a gas)
Lower entropy means?
Less disorder (likely to be a solid)
How do we look at entropy?
In terms of the number of ways that energy can be shared and the number of ways that particles can be arranged.
More particles mean?
More entropy. This is because, the more particles we have, the more ways they and their energy can be arranged.
High entropy =
More disordered = Positive value = Likely to be a gas
Low entropy =
Less disordered = Negative value = Likely to be a solid
How is entropy affected by temperature?
An increase in temperature means the particles have more kinetic energy and so move more. This means that they become more disordered so entropy increases with temperature (Directly proportional relationship)
How does entropy change in terms of physical states?
As a substance changes from SOLID to LIQUID to GAS, it’s entropy will INCREASE each time. This is because particles are becoming more spread out, therefore more disordered.