Module 5: Transition metals Flashcards
What is a transition element?
A d-block element that has an incomplete d-sub-shell as a stable ion.
What catalysts are used in: 1. Haber process 2. Contact Process 3. Hydrogenation of alkenes. 4. Decomposition of hydrogen peroxide. 5. Hydrogen production Give the equations for the reactions.
- Iron metal N2 + 3H2 —> 2NH3
- Vanadium oxide (V2O5) 2SO2 + O2 —> 2SO3
- Nickel metal C2H4 + H2 —> C2H6
- Manganese (IV) oxide MnO2 2H2O –> 2H2O + O2
- Copper (II) sulphate Zn + H2SO4 —> ZnSO4 + H2
What colour are Cu2+ ions in solution.
what happens upon the addition of NaOH?
Solution = blue NaOH = light blue ppt
What colour are Co2+ ions in solution.
what happens upon the addition of NaOH?
Solution = pink NaOH = dark blue ppt
What colour are Fe3+ ions in solution.
what happens upon the addition of NaOH?
Solution = Rust NaOH = rust coloured ppt
What colour are Fe2+ ions in solution.
what happens upon the addition of NaOH?
Solution = Grey/green NaOH = Grey/green ppt
What colour are Ni2+ ions in solution.
what happens upon the addition of NaOH?
Solution = Green NaOH = Light green ppt
What colour are Zn2+ ions in solution.
what happens upon the addition of NaOH?
Solution = Colourless NaOH = White ppt
How do you form precipitates?
Precipitates are formed when an insoluble solid forms from 2 solutions.
Define a complex ion.
Transition metal bonded to one or more ligands by coordinate bonds.
Define ligands.
Molecule or ion that can donate a pair of electrons to the transition metal ion to form a coordinate bond.