Module 5 Flashcards
Define thermal contact
When energy is being exchanged between two objects due to a temperature difference
Define thermal equilibrium
A situation in which two objects would not exchange energy if they were placed in thermal contact
Define the zeroth law of thermodynamics
If object A and B are separately in thermal equilibrium with a third object C, then A and B are in thermal equilibrium with each other.
Define the first law of thermodynamics
Energy is always conserved
Define the second law of thermodynamics
Entropy of any isolated system always increases
Define the third law of thermodynamics
Entropy of a system approaches a constant value as the temperature approaches 0K
Define temperature
The property that determines whether an object is in thermal equilibrium with other objects
Describe how to calibrate the thermometer
Record where the liquid expands to at the freezing point of water, and the boiling point, and create a scale between the two marks
Describe how a constant-volume gas thermometer works
The level of mercury in column A can be set to fixed reference level by raising or lowering mercury reservoir, keeping a constant volume of gas The height of the mercury column indicates the pressure of the gas, and hence the temperature
Define heat
The amount of energy stored in a substance and can be regarded as the sum of the random kinetic and potential energies of all the molecules in that substance, so is dependent of temperature and the amount of substance present.
Describe the spacing, ordering and motion of atoms/molecules in a solid
Made up of particles arranged in a regular 3D structure, with strong forces of attraction between the particles, which can vibrate.
Describe the spacing, ordering and motion of atoms/molecules in a liquid
The particles are free to move around, so flows easily and has no fixed shape, but there are still forces of attraction between the particles.
Describe the spacing, ordering and motion of atoms/molecules in a gas
The particles are far apart and have virtually no forces of attraction and moe at high speed. Because they are further apart, they occupy a much larger volume than a liquid.
Describe the Brownian model
Elastic collisions between different molecules, allowing them move, giving strong proof for the kinetic model
Describe how the Brownian model can be observed
Air molecules will constantly strike smoke particles, so can be observed by watching smoke molecules under a microscope with light shining on it, and, as they have the same kinetic energy, they will move.
Define absolute zero
The lowest limit for temperature, at which a substance has minimum internal energy.
Describe the change in the internal energy of a body as its temperature rises
Whilst changing phase, increases due to increase in potential energy. When temperature increases, increases due to increase in kinetic energy.
Define specific heat capacity
The amount of energy required to raise one kilogram of a substance by one kelvin.
Describe an experiment to work out the specific heat capacity of a solid
Heat an insulated object, and time how long you are heating the object for, and the average current and voltage. E=IVt, and use E=MC∆T
Describe an experiment to work out the specific heat capacity of a liquid
Heat the liquid in a calorimeter and measure the change in temperature against time, with
Define specific latent heat of vaporisation
The amount of energy required to change one kilogram of a substance from a liquid to a gas
Define the specific latent heat of fusion
The amount of energy required to change one kilogram of solid into a liquid
Describe an experiment to work out the specific latent heat of vaporisation of a substance
An electric heater heats up the liquid in a flask, where the gas is then collected and condensed using a condenser and kept separate, so the mass can be measured.
Describe the assumptions when modelling a gas using the idea gas law
Large number of molecules in random, rapid motion Particles (atoms or molecules) occupy negligible volume compared to the volume of gas All collisions are perfectly elastic and the time of the collisions is negligible compared to the time between collisions Negligible forces between particles except during collision
Using the kinetic model, describe how gases cause pressure
The aroma or molecules are always moving, and when they collide with walls of a container, the container exerts a force on them, changing their momentum. A single atom with u ms^-1 will have a change in momentum of -2mu. The atom or molecule makes frequent collisions with the walls. Newton’s second law an be used to work out the force of the wall on the atom, and the third law states that this force will then have the same magnitude as the force exerted on the wall by the gas. As a large number of atoms or molecules will randomly collide with the wall, with a force F, and p = F/A, the pressure can be calculated.
State and describe Boyle’s Law
Pressure*Volume = Constant, so Pressure is indirectly proportional to Volume
Describe an experiment to prove Boyle’s Law
A gas in a sealed tube has the pressure slowly reduced, and its volume increase can be measured, as long as the gas inside the tube remains fixed.
Describe an experiment to work out an approximation for absolute zero
Place a sealed container of dry gas in a water bath, and measure the temperature. Measure the pressure of gas in the sealed container for different temperatures and plot a graph of Temperature against Pressure, and extrapolate the line to where it crosses the X-axis
Describe the equation of state of an ideal gas
pV=nRT, Where: p=Pressure, in kPa/Pa V=Volume, in dm^3/m^3 n=Number of Moles, in mol R=Gas Constant (8.31 mol J^-1 kg^-1) T=Temperature, in K
Define Root Mean Speed
The square root of all the mean square speeds of a gas particle
Describe the general distribution of the Maxwell-Boltzmann distribution
The distribution is an unsymmetrical bell shape, starting at the Origen, and tending towards zero as the speed of the particles increase. As the temperature increases, the distribution becomes more shifted, but the area under the graph remains the same.
Define the Boltzmann constant
k=R/N_a
Describe the internal energy of an ideal gas
Internal energy is the sum of kinetic and potential energy. One assumption of an ideal gas is that the electrostatic forces between particles in the gas are negligible, except during collisions, meaning there is no electrical potential energy in an ideal gas, so all the internal energy is in the form of the kinetic energy of the particle, so are directly proportional.
Give two reasons why the time which can be calculated to heat an object is often an underestimate
Some of the energy will be transferred to heat the surroundings; As the two objects approach thermal equilibrium, the temperature gradient decreases, so the rate of transfer of energy decreases.
Describe the change in internal energy when a mass of water of 100˚C becomes an equal mass of water vapour at 100˚C
Potential energy increases and kinetic energy stays the same, work is done to move the molecules apart.
Define the radian
The angle subtended by a cirular arc with a length equal to the radius of ther circle
Define the period of an object in circular motion
The amount of time it takes the object in circular motion to complete one full revolution
Define the frequency of an object in circular motion
The number of revolutions per second an object in circular motion has.
Define angular velocity
The rate of change of angle for an object moving in a circular path
Describe what causes an object to travel in a circular path
A constant net force perpendicular to the velocity of an object causes it to travel in a circular path
Define centripetal force
A force that keeps a body moving with a constant speed in a ciruclar path
Define centripetal acceleration
The acceleration of any object travelling in a circular path at constant speed, which always acts towards the centre of the circle
Describe an experiment using a whirling bung to investigate circular motion
A bung is swung in a horizontal circle through a glass or plastic tube, with a weight attached at the bottom. A paper clip is attached to help give a reference for a constant radius to the circle. The force the weight provides is equal to the centripetal force, and changing the angular velocity will change whether the centrapetal force is equal to the force the bung is exerting to leave the system
Explain how banked services work to allow objects to travel faster in a circle.
As well as friction contributing to the centripetal force, the horizontal component of the normal contact force will as well, so this will allow the centripetal force to increase, so a higher speed is achieveable
Describe the displacement of an oscillating particle
The distance between the equilibrium position and the particle
Define the amplitude of an oscillating object
The maximum dispacement from the equilibrium position
Define the period of an oscillating object
The time taken to compete one full oscillations
Define the frequency of an oscillating object
The number of complete oscillations per unit time