Module 2: Definitions Flashcards

1
Q

Define relative formula mass.

A

The weighted mean mass of the formula unit of a compound compared with one-twelfth of the mass of an atom of carbon-12.

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2
Q

Define relative atomic mass.

A

(Ar)

The weighted mean mass of an atom of an element compared with one-twelfth of the mass of an atom of carbon-12.

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3
Q

Define relative isotopic mass.

A

The mass of an atom of an isotope compared with one-twelfth of the mass of an atom of carbon-12.

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4
Q

Define relative molecular mass.

A

(Mr)

The weighted mean mass of a molecule of a compound compared with one-twelfth of the mass of an atom of carbon-12

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5
Q

What is an ionic bond?

A

Electrostatic force of attraction between cations and anions.

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6
Q

What is a metallic bond?

A

Electrostatic attraction between cations (positive metal ions) and delocalised electrons.

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7
Q

What is a covalent bond?

A

Strong electrostatic attraction between a shared pair of electrons and the nuclei of the bonded atoms.

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8
Q

What are isotopes?

A

Atoms of the same element with different numbers of neutrons and different masses.

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9
Q

What are IMF’s?

A

Intermolecular force.

An attractive force between molecules. Intermolecular forces can be London forces, permanent dipole-dipole interactions or hydrogen bonding.

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10
Q

What is a hydrogen bond?

A

A strong dipole-dipole attraction between an electron-deficient hydrogen atom of -NH, -OH or HF on one molecule and a lone pair of electrons on a highly electronegative atom containing N, O or F on a different molecule.

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11
Q

What is the empirical formula?

A

The formula that shows the simplest whole-number ratio of atoms of each element present in a compound.

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12
Q

What is the molecular formula?

A

A formula that shows the number and type of atoms of each element present in a molecule.

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13
Q

Define stoichiometry.

A

The ratio of the amount, in moles, of each substance in a chemical equation (essentially the ratio of the balancing numbers).

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14
Q

Define anhydrous.

A

Containing no water molecules.

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15
Q

Define hydrated.

A

A crystalline compound containing water molecules.

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16
Q

Define water of crystallisation.

A

Water molecules that are bonded into a crystalline structure of a compound.

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17
Q

Define dative covalent.

A

A shared pair of electrons in which the bonding pair has been provided by one of the bonding atoms only; also called a coordinate bond.

18
Q

What is Avogadro’s constant?

A

(Na)

The number of atoms per mile of the carbon-12 isotope.

6.02x10^23 mol^-1

19
Q

Define molar mass.

A

(M)

The mass per mole of a substance, in units of gmol^-1.

20
Q

What is molar gas volume?

A

(Vm)

The volume per mole of gas molecules at a stated temperature and pressure.

21
Q

What is a mole?

A

The amount of any substance containing as many elementary particles as there are carbon atoms in exactly 12g of the carbon-12 isotope, that is, 6.02x10^23 particles.

22
Q

What is percentage yield?

A

% yield =
actual amount of product (mol)
__________________________________

theoretical amount of product (mol)

X100

23
Q

Define atom economy.

A

Sum of molar masses of desired products

/ divided by

Sum of molar masses of all products

Å ~ 100

24
Q

What is sustainability?

A

Carrying out chemical processes without depleting the Earth’s natural resources or damaging the environment.

25
Q

What is an acid?

A

A species that releases H+ ions in aqueous solution.

26
Q

What is a base?

A

A compound that neutralises an acid to form a salt.

27
Q

What is an alkali?

A

A type of base that dissolves in water to release hydroxide ions, OH- (aq).

28
Q

What is a weak acid?

A

An acid that dissociates only partially in solution.

29
Q

What is a strong acid?

A

An acid that dissociates completely in solution.

30
Q

What is a salt?

A

The product of a reaction in which the H+ ions from the acid are replaced by metal or ammonium ions.

31
Q

Define oxidation.

A

Loss of electrons or an increase in oxidation number.

32
Q

Define reduction.

A

Gain of electrons or decrease in oxidation number.

33
Q

What is a redox reaction?

A

A reaction involving both reduction and oxidation.

34
Q

What is an oxidising agent?

A

A reagent that oxidises (takes electrons from) another species.

35
Q

What is a reducing agent?

A

A reagent that reduces (adds electrons to) another species.

36
Q

What is a shell (electron shell)?

A

A group of atomic orbitals with the same principal quantum number n. Also known as a main energy level.

37
Q

What is a subshell?

A

A group of orbitals of the same type within a shell.

38
Q

What is an orbital?

A

A region of space around the nucleus that can hold up to two electrons as long as their spins are paired (opposite spins).

39
Q

Define electronegativity.

A

A measure of the attraction of a bonded atom for the pair of electrons in a covalent bond.

40
Q

What are polar molecules?

A

A molecule with an overall dipole, having taken into account any dipoles across bonds and the shape of the molecule.