Module 1 Flashcards
Central Goal
Recognize distinctive properties of chemical substances that can be used to identify and separate them
homogeneous mixtures
have uniform composition and properties
ie. clean air and drinking water
heterogeneous mixtures
composed of visibly different substances that can be in the same or different phases
ie. minerals on earth
intensive properties
properties that do not depend on the amount of substance; not all of them can be differentiating characteristics but most are
ie. melting point, density, conductivity, temperature, pressure
extensive properties
properties that depend on the amount of substance; these are NOT differentiating characteristics
ie. mass, volume
good differentiating characteristics
- unique values for each substance
- do not vary with size of the sample
- can be selectively measured
boiling point
the temperature at which a substance transforms from liquid to gas at a given pressure; at which a substance transforms into a liquid as it cools down from a gas
normal boiling points
boiling temperatures at atmospheric sea level
Celsius to Kelvin
K = C + 273.15
phase transition / phase change
chemical nature of a substance is preserved; substance goes from one phase to another
Does a substance’s temperature change during a phase transition?
No; at a phase transition, the energy added or removed to a substance will induce a change of state WITHOUT altering the actual temperature of the system.
melting
solid to liquid
boiling
liquid to gas
sublimation
solid to gas
solidification
liquid to solid
condensation
gas to liquid
deposition
gas to solid
physical change
the chemical nature of the substance does not change with a transformation
How does pressure affect phase transitions?
The values of the external pressure around a substance can change the temperatures at which a substance transitions.
phase diagrams
Graphical representations of a substance’s stability & phase change during certain temperatures & pressures.
triple point
The point at which three different phases of a substance can coexist with each other under certain conditions.
critical point
The point at which the characteristics of a substance during gas & liquid phases become identical.
The critical point occurs at a certain temperature & pressure for each substance.
supercritical fluid
When the gas and liquid phase of a substance is indistinguishable. This occurs when temperatures and pressures are higher than the critical point.
vapor pressure
The pressure that a vapor of a substance exerts when it evaporates from a liquid in a sealed container.
When the vapor pressure of a liquid is equal to the external pressure on the liquid, then boiling occurs. This is b/c the gas can freely escape.
vapor pressure curve
The liquid-to-gas transition line in a pressure-temperature phase diagram
filtration
The mechanical separation of solid substances and fluid substances (liquid or gas).
Efficiency largely depends on filter’s thickness and pore size
crystallization
Formation of a solid phase is induced by changing the temperature or concentration of components in a mixture, OR by adding other substances.
distillation
Involves a phase change from liquid to gas and reconversion of the separated substances to the liquid phase.
atm to mmHg
1 atm = 760 mmHg