Module 02: Atoms and Elements Flashcards
02.01 Atomic Theory 02.02 Electromagnetic Radiation 02.03 Quantization of Energy 02.04 Quantum Models 02.05 Honors Electrons 02.06 Periodic Table 02.07 Periodic Trends 02.08 Contributions to Chemistry
What did John Dalton contribute to science in 1803?
Devised a way to indirectly observe atomic nature
- temperature
- atmospheric conditions
- wind patterns
What does the word “atom” mean?
Derived from the Greek term meaning “cannot be cut into smaller pieces”.
What is Dalton’s Atomic Theory?
All matter is composed of extremely small particles → atoms
- Atoms of element: identical (size, mass, etc)
- not broken down into smaller pieces
Law of Conservation of Mass
Atoms cannot be subdivided, created, or destroyed
Law of Multiple Proportions
Atoms of different elements can combine > compound (whole-number ratio)
What is the Law of Conservation of Mass?
Atoms cannot be subdivided, created, or destroyed
What is the Law of Multiple Proportions?
Atoms of different elements can combine > compound (whole-number ratio)
How did Dalton’s Theory prove durable?
Dalton’s original theory provides explanation to atomic structure. 200 years additional support for theory
Define subatomic particles?
particles smaller than an atom
- Protons
- Neutrons
- Electrons
Explain how J. J. Thomson discovered electrons (1867-1906)?
Experiment:
- loved cathode rays
- discovered smaller, negative particles in an atom
- called: electrons
Conclusion:
Thomson hypothesized that these corpuscles were scattered within a positively charged atom
Explain Ernest Rutherford’s contribution to the understanding of atoms (especially the nucleus)?
Who: Ernest Rutherford (student J. J. Thomson)
Experiment:
behavior particles as they were radiated onto a piece of gold foil
- some particles not pass strait through
- some scattered
- others bounced back
Conclusion:
Something big, positively charged in the center of the atom → nucleus
composed of protons and neutrons
What contribution did James Chadwick make to the understanding of the nucleus?
Experiment:
- Found neutrons
- bombarded beryllium atoms with alpha particles → unknown radiation produced
- Neutral electrical charge
Conclusion:
determined neutron existed in an atom’s nucleus
mass close to the proton
What conclusion did Crookes create related to cathode tubed?
How did Thomson challenge this idea?
Crookes’s Cathode:
Created cathode tube → allowed electrically charged particles flow between electrodes
Conclusion: something was traveling from the negative to the positive side
Thomson’s Electrons:
J. J. Thomas: used cathode ray tubes
negative attracted to the positive side & repelled by the negative side
calculate a mass-to-charge ration
How did Rutherford’s discovery of the nucleus challenge Thomson’s hypothesis regarding electrons?
Assumed fast-moving alpha particles pass through piece of tin foil
if Thomas’s model was right nothing would scatter the rays
scattered particles indicated a nucleus
Explain what the Bohr’s Quantum Model is:
Hypothesis:
The energy of a atoms not continue → only certain values
Proposal:
- emitting energy: higher to lower energy level
- absorbing energy: lower to higher energy level
Electrons:
- fixed energy
- only move
Energy Shell:
layers around the nucleus
- 2 first
- 8 second
Comparative to Solar System:
given away to the electron cloud model:
- orbitals
- brightness correlated to density
How did Schrodinger and Heisenberg’s Electron Cloud Theory replace Bohr’s Quantum Model?
electrons not move in exact orbitals (like solar system)
Existed in the electron cloud
- region around the nucleus - mostly empty space - electrons orbit
Define Atoms:
smallest unit of an element that retains the properties of that element
How does the nucleus compare to the electron cloud?
NUCLEUS:
center
most of the mass
Protons:
- positively charged
Neutrons:
- neutral
- identifies the element
ELECTRON CLOUD
area around the nucleus
majority of the volume
Electrons:
- negative particles
- revolve around the nucleus
- ability move from one electron to another
Define Ions:
atom/molecule with a positive or negative charge
Define Isotopes:
atoms of the same element with different masses due to varying number of neutrons
What is the overall charge of a atom?
Neutral
Rutherford’s famous gold foil experiments shot heavy particles at a thin sheet of gold foil. What did he observe, and why did these observations eventually result in the addition of a nucleus to the atomic model? (3 points)
- Some of the heavy particles bounced off the foil, because there are positive particles spread throughout the atom.
- Some of the heavy particles bounced off the foil, because there is a dense, positive area in the atom.
- The heavy particles all passed straight through the foil, because the atoms are mostly empty space.
- The heavy particles all bounced off the foil, because the subatomic particles have mass and volume.
2.
Some of the heavy particles bounced off the foil, because there is a dense, positive area in the atom.
Modern atomic theory states that atoms are neutral. How is this neutrality achieved? (3 points)
- Equal number of neutrons and protons
- Equal number of protons and electrons
- More electrons than protons
- More neutrons than electrons
2. Equal number of protons and electrons
What is true of neutrons? (3 points)
- They have no charge and are located inside the nucleus.
- They have no charge and are located outside the nucleus.
- They are negatively charged and are located inside the nucleus.
- They are negatively charged and are located outside the nucleus.
- They have no charge and are located inside the nucleus.
In the 1800s, one of the statements in John Dalton’s atomic theory was that atoms are indivisible. Later experimental evidence led to the discovery of subatomic particles such as neutrons, electrons, and protons. What happened to the indivisible atom part of Dalton’s atomic theory, and why? (3 points)
- The entire theory was discarded because Dalton’s scientific reputation was ruined once new evidence invalidated part of his theory.
- The indivisible atom part of the theory was discarded because the consensus of data must exist for theories to be valid.
- The theory remained unchanged because Dalton was correct regarding all other statements within the accepted scientific theory.
- The theory remained unchanged because new data is discarded if it doesn’t fit within the accepted theory.
2. The indivisible atom part of the theory was discarded because the consensus of data must exist for theories to be valid.
Which hypothesis of Thomson’s atomic model was later found to be not true by Niels Bohr and why? (5 points)
J. J. Thomson discovered the electron. However, he concluded that the electrons were scattered within the positively charged atom. A few years later, Niels Bohr disproved Thomson’s hypothesis that elections were randomly scattered in the atom. Comparatively, he posed that electrons moved in orbits around the nucleus. Bohr’s hypothesis was built on Rutherford’s discovery of the atom. Rutherford disproved Thomson’s idea that there was an even distribution of particles in the atom; instead, there is a nucleus in the middle (which he found with hid tin foil experiment).
Hence, if there is a positively charged cluster of particles in the middle, there cannot be electron scattered the way Thomson proposed. So Bohr deduced from Rutherford’s theory of the nucleus that the atom had a “solar system” like structure (which was disproven by Schrodinger and Heisenberg later). The electrons, according to the Bohr, were ordered in layers - orbitals - around the nucleus.
How does energy travel in waves?
The disturbance of the particles of a substance resulting in undulating motion
What discovery did Max Planck make in relation to energy?
“Energy has both wavelike and particle-like properties”
No continuous energy but transfer in packets
Define Quanta:
quantity of energy proportional in magnitude to the frequency of the radiation it represents
What did Albert Einstein say about Plank’s theory regarding energy?
Agreed with Planck
Energy transferred discrete packets called quanta
Define Radiation:
Emission of energy in the form of waves
- repetitive
- come various sizes
- carry energy
Define Electromagnetic Wave:
Wave of energy generated by periodic fluctuation of an electromagnetic field
Describe the structure of an electromagnetic wave?
Trough: lowest point
Crest: highest point
Amplitude: vertical distance between the crest/trough
measures height, intensity
What is the speed of light?
3.0 * 108 m/s
Define wavelength:
Distance between corresponding points on adjacent waves
Consistent between the entire wave
Define Frequency:
waves passing by a fixed amount of time (per second)
Hertz (Hz)
What is the relation between wavelength and frequency?
inverse related
wave period → amount of time it takes for one wavelength to pass through a point ( seconds (s): Hz = 1/2)
Define Wave Period:
amount of time it takes for one wavelength to pass through a point ( seconds (s): Hz = 1/2)
Define Electromagnetic Radiation (EMR)?
Form of energy moves in a wavelike motion as it travels
fluctuating electric and magnetic energy field → oscillate at right angles to each other
Ex:
- visible light
- radio waves
- X-rays
- ultraviolet (UV) light
- gamma rays
What is Radio Waves?
Used for radio, TV antennas, cell phones
What are Micro-Waves?
Used in radar and to heat food (microwave)
What are Infrared radiation?
HEAT → emitted by all objects (use special cameras to detect)
What is Visible radiation?
All the radiation humans can see (light, sun, fire)
What is Ultraviolet light?
Radiated by the sun (uses burns)
Define X-rays:
Used in medical fields to look at bones on the inside
Define Gamma Rays:
Radiation given off by radioactive substances
Electrons have been shown to have both wavelike and particle-like properties. (4 points)
- True
- False
True
Which type of electromagnetic radiation has a lower frequency than infrared radiation? (4 points)
- Gamma rays
- Microwaves
- Visible light
- X‒rays
2. Microwaves
Compared to infrared radiation, an electromagnetic wave that has a lower frequency will also have a ________. (4 points)
- longer wavelength and lower speed
- longer wavelength and equal speed
- shorter wavelength and lower speed
- shorter wavelength and equal speed
2. longer wavelength and equal speed
What is the frequency of a wave with a wavelength of 6.40 x 104 meters? (4 points)
- 1.87 x 10−6 Hz
- 2.13 x 10−4 Hz
- 4.69 x 103 Hz
- 1.92 x 1013 Hz
3. 4.69 x 103 Hz
Formula to determine wavelength:
Wavelength = Speed of Light / Frequency
What happens to electrons of elements when heat/energy is added?
- absorb energy
- transition into a higher energy level
How do electrons move between the excited and ground state?
Excited: particles has higher energy than lowest possible state
Ground: lowest energy state of atom
What is an emission spectrum?
The transition between Excited <> Ground
- emits light (different colors)
- Emission spectrum: spectrum of electromagnetic radiation emitted by source
How do heat, electricity, and light relate to an increase/decrease in energy?
Heat and Electricity → increases energy
Light → decrease in energy
Define a “photon?”
Basic particle representing a quantum of energy
What is a photon of light?
Emitted by an atom when electron transitions into lower energy level
Define a photon of energy?
Amitted by an atom when electron transitions into lower energy level
What is the formula for a energy of a photon?
E = hf
Directly proportional to the frequency of photon’s emission or absorption
- Joules
- h: Planck’s constant → 6.626 * 10-34 (J *s)
- f: frequency of light
- Amount of energy → dependent on frequency of energy source
Define a “scientific model:”
Visual representation of a scientific idea or process and make it easier to learn a new concept
What are the different types of scientific models? (6)
Diagrams, Sketches, or drawings:
- Illustrations of processes
- Labels and icons
2D or 3D:
- Replicas of objects or processes
- ex: Model of a molecule
Simulations:
- Imitates a process to make it as realistic as possible
Infographics:
Explanatory pictures that improve understanding
Maps:
- Model landmarks, land elevations, weather, and more
- direction
- scale calculate distance
- legend to describe symbols and colors
Graphs
- Shows relationships
What is the estimated effective nuclear charge (zeff) felt by the outer shell electrons in calcium (Ca)?
The outer shell electrons feel an estimated effective nuclear charge of about +2. This is because the total nuclear charge (+20) is shielded by the 18 core electrons in the energy levels closer to the nucleus. The equation +20 − 18 = +2 gives the estimated effective nuclear charge felt by each of sulfur’s outer shell electrons.
Oxygen has a negative electron affinity. Does it absorb or release energy when it gains an electron?
When energy is released, the electron affinity value is represented as a negative value.
A scientist needs to determine the reactivity of two elements. One element is a metal, and the other element is a nonmetal. What periodic trend determines the reactivity of both elements?
For metals, as you go down a column, the chemical reactivity increases. As you go right across a row, the chemical reactivity decreases.
For nonmetals, as you go down a column, the chemical reactivity decreases. As you go right across a row, the chemical reactivity increases.
Do elements with a low effective nuclear charge also have low electronegativity? Explain your answer.
Outer shell electrons of elements with low effective nuclear charge usually have low electronegativity values because their nuclei exert a weak attractive force on electrons. However, this isn’t always true. There are exceptions on the periodic table.
Define Quantum Model:
Mathematical model based on quantum theory that represents the probable state of electrons within an atom
What was Niel Bohr’s proposal regarding electrons?
Niels Bohr Proposal: partials that circle the nucleus in shells
- lowest: n = 1
- Next: n = 2
- Number of electrons is equal to neutrons
What is Heisenberg Uncertainty Principle?
Cannot know both the position and the velocity of particle at the same time
What is the Principal Quantum Number?
Any whole number from 1-7
Energy levels around the nucleus
energy shells
- n =1 → inner most, least energetic
- energy increase and n increases
What is the Angular Momentum Quantum Number (I)?
4 types of numbers
- S orbital → round
- P Orbital → shaped like a bumble
- D orbital
- F orbital
Define subshells:
group of orbitals with the same potential energy
Describe the ”s” orbitals from the Angular Momentum Quantum Number:
[1] S → one orbital
- spherical shape
- Electrons arrows
- up: clockwise spin
- down: counterclockwise
Describe the “P” orbitals from the Angular Momentum Quantum Number:
[2] P → three orbitals
- dumbbell-shaped
- Max: 6 electrons
Describe the “d” orbitals from the Angular Momentum Quantum Number:
[3] d → five orbitals
- nondescript shape
- max: 10 electrons
Describe the “f” orbitals from the Angular Momentum Quantum Number:
[4] f → seven orbitals
- nondescript in shape
- Max: 14 electrons
Define electron configuration:
: Arrangement of electrons in energy levels (shells) around nucleus
Define the different parts of electron configuration: 1s22s22p6
- Number of electrons
- Oribtals
- Energy Shells
- Number of electrons: 1s22s22p6
- subshell has limit to the number of electron the orbit can hold
- Adding together = number of electron for element
- Orbitals: 1s22s22p6
- Energy Shells: 1s22s22p6
Define each subshell’s corresponding amount of orbitals and electrons: (s, p, d, f)
See attachment:
What are the [4] levels of configuration?
- Electrons
- Example
- type of subshell
Level 01:
- 2 electrons in s subshell
- Configuration: 1s2
Level 02:
- 8 electrons in p subshell
- Configuration: 1s22s22p6
Level 03:
- 18 electrons
- 2 electrons in s subshell
- 6 in p subshell
- 10 in d subshell
- 4s subshell is filled before 3d
- Configuration: 1s22s22p63s23p64s23d10
Level 04:
- 8 electrons
- 2 in 4s
- 6 in 4p
- Configuration: 1s22s22p63s23p64s23d104p6
Define Ground-State Electron Configuration:
Arrangement that places electrons closest to nucleus
What is the Aufbau Principle?
Quantum model of atom mathematically maps out an atom’s orbitals beyond ground state
“Electrons occupies that lowest energy orbital”
- Based on the potential energy of each position
- n = 1 first → lowest energy
- then: 2s, 2p, 3s
What is the total number of electrons that can occupy the p sublevel? (3 points)
- 2 electrons
- 6 electrons
- 8 electrons
- 10 electrons
- 6 electrons
Select the words that correctly fill in the blanks for this statement:
The p sublevel has ________ orbitals that are ________-shaped. (3 points)
- three, dumbbell
- three, spherical
- five, dumbbell
- five, spherical
- three, dumbbell
Which of the following is not a possible sublevel? (3 points)
- 1s
- 2p
- 3f
- 4d
- 3f
Magnesium (Mg) has an atomic number of 12. What is the ground-state electron configuration of magnesium? (3 points)
- 1s21p62s22p2
- 1s21p61d4
- 1s22s22p63s2
- 1s22s22p62d2
3. 1s22s22p63s2
Which of the following is a reasonable ground-state electron configuration? (3 points)
- 1s22s22p63s2
- 1s22s22p63s23d4
- 1s22s22d102p3
- 1s22s22p32d6
- 1s22s22p63s2