Modern Optics Flashcards
Clock Uncertainty
delta T / T
delta w / w
Definition of a second
9,192,631,770 periods of the radiation of the ground state hyperfine transition in Cs
Broadening Mechanisms
Collisional
Doppler
Natural - spontaneous (collisions increase spontaneous rate)
Transit time
Principle of atomic clock
Atom provides reference freq. +vs Unperturbed atomic transition identical in all atoms of same element, atoms do not wear out.
Steps of atomic clock
Atom provides frequency
Oscillator produces EM wave with freq. w
Detector counts atoms in excited state
Servo adjusts w until detector signal maximised
Count no. of oscillations in time you wnt to measure
Seconds = N oscillations/ 9billion ..
Minimise broadening mechanisms
Min possible delta w
Maximum time to syncronise EM source with resonance - TT
Conduct under ultra high vaccuum conditions - collisional
Spont. emiss, TT - understand atom/EM field interactions
Electrip dipole interaction & moment, magnetic dipole interaction
H’ = -d.E
d = -er
= = -e
H’ = - mu . B
Transition
During transition, the atom is in a superposition of the ground and excited states.
is absorption or emission of a photon
Spontaneous emission
Atom in excited state may spontaneously decay to lower E level - releases photon in random direction with random phase. Induced by vacuum fluctuations.
Rate of decay by spont emission ~ einstein A coeff.
A & Linewidth
A21 = w21^ 3 d^2 g1
3pi hbar epsilon0 c^3 g2
A21 = 1/tau = Gamma - linewidth (total decay rate)
delta w = Gamma (FWHM) - natural linewidth as a result of natural broadening
Can have smaller w or smaller d for smaller A - want to reduce A
Is 2p
No - order 10^-8 - best clocks are 10^-19
Hyperfine & Fine Structure splitting
Hyperfine - F, fine structure J
J = L + S
F = I + J
How do we reduce A
Use magnetic dipole transitions - A different and smaller
Fine structure selection rules
delta l = +-1 delta L = 0, +-1
delta J = 0, +-1
delta S = 0
delta mJ = 0, +-1
Why do energy levels split? MM
Spin - electron and proton have spin and therefore magnetic moments - can be spin up or down. GS thus has degeneracy 4 and this is lifted by the hyperfine interaction. Nuclear spin interacts with B-field produced by electronic spin and orbital motion.