Modelling a gas Flashcards

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1
Q

Mole

A

A quantity of substance with the same number of particles as 12 grams of carbon -12.

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2
Q

Avogadro’s constant

A

6.02 x 1023

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3
Q

Formula for no. of particles

A

n = N / NA
no. of moles= No. of particles/Avogadro’s no.

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4
Q

Formula for mass, molecular mass and moles

A

n = m/μ
no. of moles = mass/ molecular mass

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5
Q

Pressure definition

A

Force acting perpendicularly per unit area

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6
Q

Pressure in solids when force is at an angle

A

P = F cos θ /A

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7
Q

Pressure in liquids

A

P = heg
Pressure = height x density x gravity

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8
Q

Properties of an ideal gas

A
  • Molecules are point particles, each with negligible volume
  • Molecules obey the laws of mechanics
  • No forces between molecules except during collisions
  • Duration of collisions is negligible compared to time between collisions
  • Collisions between molecules and with the walls of the container are perfectly elastic
  • Molecules move randomly with a range of speeds
  • Do not change state
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9
Q

Properties of a real gas that prevent them from being ideal gases

A
  • Forces between molecules
  • Molecules have definite volume
  • They condense before zero
  • Condense at high pressure and low temperature
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10
Q

Pressure-volume (Boyle’s) law

A

For a gas with contsant temperature and mass, pressure is inversely proportional to volume

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11
Q

Pressure-volume law equation

A

p=k/V
p1 V1 = p2 V2

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12
Q

Volume-temperature (Charle’s) law

A

The volume of a fixed mass of gas at constant pressure is directly proportional to its absolute temperature

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13
Q

Volume-temperaure law equation

A

V = kT
V1 / T1 = V2 / T2

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14
Q

What is absolute zero?

A

0 Kelvin. When particles are not moving

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15
Q

Pressure- temperature (Gay-Lussac’s) law

A

Pressure of a fixed mass of gas, at constant volume, is direcly proportional to absolute temperature

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16
Q

Pressure-temperature law equation

A

P = kT
p1 / T1 = p2 / T2

17
Q

Isobar

A

Line joining points at the same pressure

18
Q

Isothermal

A

Line joining points at the same temperature

19
Q

Combined gas law

A

p1 V1 / T1 = p2 V2 / T2

20
Q

Equation of state of an ideal gas

A

pV = nRT

p = pressure (pa)
V= volume (m3)
n = no. of moles
R = 8.31
T = Temperature (K)

21
Q

Value of R (universal gas constant)

A

R = 8.31 J/Kmol

22
Q

Kinetic energy of 1 molecule of gas (2 equations)

A

EK = 1/2 mc2
EK = 3/2 KB T

c = root mean square speed (r.m.s)
c2 = mean square speed
KB = R/NA (Boltzmann’s constant)

23
Q

Pressure of a gas

A

p = 1/3 ec2

e = density (kg/m3)

24
Q

Internal energy(U)

A

U = 3/2 nRT