Mod 6: Acid/Base Reactions Flashcards
Arrhenius theory
Acids produce H+ and bases produce OH- in aqueous solution
Arrhenius improvements
Accounts for the relative strength between different acids
Arrhenius limitations
Acid base reactions do not always occur in solution e.g. HCl(g) + NH3(g) -> NH4Cl(s)
Bronsted-Lowry theory
Acid is a proton donor, a base is a proton acceptor
Bronsted-Lowry improvements
Accounts for acids and bases in gasesous state
Bronsted-Lowry limitations
Cannot explain reactions between acidic and basic oxides e.g. CaO(s) + SO3(g) -> CaSO4(s)
Indicator for strong acid and strong base (include pH)
Bromothymol blue (6-7.6)
Indicator for strong acid and weak base (include pH)
Methyl orange (3.1-4.4)
Indicator for weak acid and strong base (include pH)
Phenolphthalein (8.3-10)`
Properties of a good solute for a primary standard
Highly pure, stable (not hydroscopic - reacting with water in air), highly soluble in water, large molecular weight (reduce error in weighing)
Equivalence point
When in stoichiometric ratio
Endpoint
When indicator changes colour
Aliquot
Accurately known volume of solution delivered by pipette
Titrant
Solution of known concentration
Titre
Total volume of solution delivered by the burette