Mod 6 Flashcards
The 5 strong acids
HCl HBr H2SO4 HNO3 HI
What is its spontaneity at different temeratures
The 3 indicators to remember
Lavoisier 1776
Acids must contain oxygen
Limitation: some acids (e.g hydrochloric acid) don’t contain oxygen
Davy 1810
Hydrogen is the acid identifier
Limitation: some compounds containing hydrogen (e.g methane CH4) aren’t acids
Arrhenius 1884
Arrhenius acid: substances that ionise with water to produce H+ ions
Arrhenius base: substances that ionise with water to produce OH- ions
Limitations:
- doesn’t explain why substances that don’t contain OH- ions like ammonia can produce OH- ions
- Doesn’t explain why some acids and bases produce non-neutral solutions
Bronstead-Lowry Theory 1923
Bronstead-Lowry acid - Proton doner
Bronstead-Lowry base - Proton acceptor
Limitation: cant explain why substances like CO2 have no H+ ions but can still accept them
Enthalpy of strong acid and strong base neutralisation (with ideal conditions)
-57.6 KJ/mol
Most effective buffer capacity equation (probs not needed)
Buffers in blood
H2CO3/HCO3-
H2PO4-/HPO42- (also important in cells)
- Strong acid + strong base
- Weak acid + strong base
- Strong acid + weak base
- Weak acid + weak base
Strong bases
Group 1 and 2 metal hydroxides