mod 5 ch 5 Flashcards
what is the equation to find the number of stereoisomers a molecule is capable of forming
2^n
where n = # of chiral centers
define enantiomer
their R and S configurations are exactly opposite
define diastereomer
they have at least one difference in their R and S configurations
what are the three requirements to be a meso compound
- must have two chiral centers
- one must be R, one must be S
- must have the same three groups off both of the chiral centers
meso compounds are
achiral due to symmetry
what things are optically inactive
- meso compounds
- racemic mixtures (50% each enantiomer cancels out)
to determine if a molecule is pro-R or pro-S
label the atom they are pointing to priority one and find R or S
a positive rotation of light or in the clockwise direction is referred to as
dextrorotatory
a negative rotation of light or in the counterclockwise direction is referred to as
levorotatory
when determining re and si…
assign priorities
re: clockwise
si counterclockwise