mod 5 ch 5 Flashcards

1
Q

what is the equation to find the number of stereoisomers a molecule is capable of forming

A

2^n
where n = # of chiral centers

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

define enantiomer

A

their R and S configurations are exactly opposite

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

define diastereomer

A

they have at least one difference in their R and S configurations

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

what are the three requirements to be a meso compound

A
  1. must have two chiral centers
  2. one must be R, one must be S
  3. must have the same three groups off both of the chiral centers
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

meso compounds are

A

achiral due to symmetry

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

what things are optically inactive

A
  • meso compounds
  • racemic mixtures (50% each enantiomer cancels out)
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q
A
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

to determine if a molecule is pro-R or pro-S

A

label the atom they are pointing to priority one and find R or S

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

a positive rotation of light or in the clockwise direction is referred to as

A

dextrorotatory

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

a negative rotation of light or in the counterclockwise direction is referred to as

A

levorotatory

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

when determining re and si…

A

assign priorities
re: clockwise
si counterclockwise

How well did you know this?
1
Not at all
2
3
4
5
Perfectly