Mixture thermodynamics Flashcards
Define mixture
System in which all components have similar mole fractions
Define solution
One of components is in large excess => component in excess is the solvent, remaining components are solutes
Describe the mixing process
Two pure components are mixed at same temp and pressure so final pressure is the same
Describe the phase equilibrium of binary mixtures
Two phases at the same pressure and temperature are in equilibrium when the chemical potential of each species is the same in both phases.
Describe an ideal mixture
No change in total volume on mixing => total volume equal to sum of components
=> molecular size and interactions of each component of the mixture are the same
What does internal energy depend on?
Only temperature