MIT Lecture 1 Flashcards

1
Q

Thermodynamics is the science of _

A

The flow of heat

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2
Q

Thermodynamics was developed primarily in _

A

The 1800s during the industrial revolution

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3
Q

What prescient calculation did Arrhenius make in the 1800s?

A

The impact of CO2 on the environment. He predicted that we would have problems in about 2000 years

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4
Q

What does the zeroth law define?

A

Temperature (T)

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5
Q

What does the first law define?

A

Energy (U) and its conservation

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6
Q

What does the second law define?

A

Entropy (S)

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7
Q

What does the third law provide?

A

A numerical value to entropy

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8
Q

Under what condition could you attain perfect efficiency?

A

0K

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9
Q

What is the closes that anyone has ever come to 0K?

A

150 nanokelvin

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10
Q

What is the system?

A

The delineated part of the universe that we are looking at

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11
Q

What are the surroundings?

A

Everything that exists outside of the system

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12
Q

What is the boundary?

A

The surface that exists between the system and its surroundings

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13
Q

What is an open system?

A

One in which energy and mass can flow between through the boundary

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14
Q

What is an isolated system?

A

One in which neither energy nor mass can flow through the boundary

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15
Q

What is a closed system?

A

One in which energy but not mass can flow through the boundary

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16
Q

What information do you need to describe an equilibrium state?

A

Number of moles + 2 state variables

17
Q

What is a homogeneous system?

A

One in which all of the molecules are in the same phase

18
Q

What is a heterogeneous system?

A

One in which the molecules are present in different phases within the system

19
Q

How many components are in the system of an ice cube in a glass of water?

A

Just one. There are only water molecules present

20
Q

how many components are in the system of a late coffee?

A

Many since there are many different kinds of molecules in the milk, water, impurities etc

21
Q

Thermodynamics describes systems that are _

A

Equilibrium states

22
Q

Thermodynamics describes the transition between _

A

One equilibrium state to another

23
Q

What are extensive properties? Give examples

A

Properties that scale with the scaling of the system - volume, mass

24
Q

What are intensive properties? Give examples

A

Properties that do not scale with the scaling of the system - temperature

25
Q

How would you convert an extensive variable in to an intensive one?

A

Divide it by the number of moles

26
Q

Why is thermodynamics so powerful?

A

With only a small amount of data you can describe a system in detail, which gives a large amount of predictive power

27
Q

The number of paths you can take between two systems is _

A

Infinite

28
Q

What can define the direction of time?

A

The direction of an irreversible path

29
Q

Define an adiabatic path

A

One in which no heat is transferred to the surroundings