Missed questions Flashcards
What can be the definition for the rate of a reaction?
How many moles of the reactant was used up per second
What are ways in which we can measure the rate of a reaction?
- Change in Concentration:
- Titration: Regularly sample the reaction mixture and titrate to determine the concentration of a reactant or product.
- Spectrophotometry: Measure the absorbance of light by a reactant or product at a specific wavelength. The change in absorbance over time correlates with the concentration.
- Change in Mass:
- Mass Loss: Measure the mass of the reaction mixture over time, especially if a gas is produced and escapes, reducing the mass.
- Change in Volume:
- Gas Volume: If the reaction produces a gas, measure the volume of gas evolved over time using a gas syringe or an inverted measuring cylinder over water.
- Change in Pressure:
- Manometry: Monitor the change in pressure in a closed system when a reaction produces or consumes a gas.
- Change in pH:
- pH Meter: Measure the change in pH if the reaction involves the production or consumption of hydrogen ions (H⁺). The rate of pH change indicates the reaction rate.
- Change in Electrical Conductivity:
- Conductometry: Monitor the change in electrical conductivity if the reaction involves ions. As the concentration of ions changes, so does the conductivity.
- Change in Color:
- Colorimetry: Measure the change in color intensity of the solution if the reaction involves colored substances. The intensity is related to the concentration of the colored species.
- Change in Temperature:
- Calorimetry: If the reaction is exothermic or endothermic, measure the temperature change over time. The rate of temperature change can be related to the reaction rate.
- Change in Pressure Drop in a Flow System:
- For reactions occurring in a flowing medium, monitoring the pressure drop across a catalyst bed can give an indication of reaction rate.
- Quenching:
- For fast reactions, samples are taken at different times and then quickly quenched (stopped) by rapid cooling or adding a reagent to stop the reaction. The concentration of reactants/products is then measured.
For a zinc and sulfuric acid reaction. What cannot increase the rate of this reaction?
Increasing the pressure
As temperature increases what also increases?
The collision rate and strength between all particles.
The flame test is used for determining
The identity of a metal
What do open systems do?
Exchange energy and matter with the surroundings
What is a bond energy?
amount of energy required to break 1 mole of a bond into its constituent gase
What is the chemical equasion for an incomplete combustion
Fuel+ oxygen- CO+ water