Midterm Study Flashcards

1
Q

Complete combustion of a sample of a hydrocarbon in excess oxygen produces equimolar quantities of carbon dioxide and water. Which of the following could be the molecular formula of the compound?

A

c. C4H8

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2
Q

Zn(s) is used to reduce other compounds in chemical reactions. If a chemist needs a substance that is more effective in its reducing ability, which of the following species would be the best choice?

A

a. Na

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3
Q

A kinetics experiment is set up to collect the gas that is generated when sample of chalk, consisting primarily of solid CaCO3, is added to a solution of ethnic acid(acetic acid) CH3COOH. The rate of reaction between CaCO3 and CH3COOH is determined by measuring the volume of gas generated at 25ºC and 1 atm as a function of time. Which of the following experimental conditions is most likely to increase the rate of gas production?

A

d. Decreasing the particle size of the CaCO3 by grinding it into a fine powder

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4
Q

H2(s)+I2(g)2HI(g). At 450ºC, 2.0 moles of H2, I2, and HI are combined in a 1.0 L rigid container. The value of Kc at 450ºC is 50. Which of the following will occur as the system moves toward equilibrium?

A

b. More HI will form

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5
Q

The graph above shows the speed distribution of molecules in a sample of gas at a certain temperature. Which the following graphs shows the speed distribution of the same molecules at a lower temperature (as a dashed curve)?

A

c.

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6
Q

The elements I and Te have similar atomic masses. A sample that was believed to be a mixture of I and Te was run through a mass spectrometer, resulting in the data above. If all of the following statements are true, which one would be the best basis for concluding that the sample was pure Te?

A

c. I only consists of one naturally occurring isotope with 74 neutrons, whereas Te has more than one isotope

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7
Q

All the reactions represented above occur in an aqueous solution of oxalic acid. Which of the following represent a Brønsted Lowry conjugate acid-base pair?

A

b. HC2O4 AND C2O4

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8
Q

Which of the following particulate diagrams shows the formation of water vapor from hydrogen gas and oxygen gas in a rigid container at 125ºC?

A

c.

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9
Q

At point R in the titration, which of the following species has the highest concentration?

A

a. HA

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10
Q

Which of the following is the best particulate representation of the species (other than H2O) that are present in significant concentrations in the solution at point U in the titration?

A

b. 

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11
Q

At which point on the titration curve is A- closest to twice that of HA?

A

c. T

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12
Q

A student carries out the same titration, but uses an indicator instead of a pH meter. If the indicator changed color slightly past the equivalence point, what will the student obtain for the calculated concentrations of the acid?

A

b. slightly more than 0.0800 M

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13
Q

The average kinetic energy of the gas molecules is:

A

d. The same in all three containers

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14
Q

The density of the gas, in g/L, is

A

b. greater in container B

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15
Q

The mass percent of carbon in pure glucose, C6H12O6, is 40.0%. A chemist analyzes an impure sample of glucose and determines that the mass percent of carbon is 38.2%. Which of the following impurities could account for the low mass of carbon in the sample?

A

a. Water (H2O)

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16
Q

Caffeine (C8H10N4O2) is a weak base with a Kb value of 4x10^-4. The pH of a .01 M solution of caffeine is in the range of:

A

d. 11-12

17
Q

Which of the following statements is true?

A

d. The rate law that is consistent with this mechanism is:m rate=k[NO]^2[O2]

18
Q

For which of acid is the value of the acid dissociation constant, Ka, the smallest?

A

a. Acid 1

19
Q

Using the table and information from question #18, which of the four acids listed in the table is hydrochloric acid?

A

b. Acid 2

20
Q

Using the information on the table in question #18 again, of the following species, which has the greatest concentration in a 1.0M solution of acid 1 at equilibrium?

A

c. Acid 1

21
Q

If equal volumes of the four acids at a concentration of 0.50 M are each titrated with a strong base, which will require the greatest volume of base to reach the equivalence point?

A

d. All the acids will require the same volume of base to reach the equivalence point

22
Q

A 25 mL sample of a 1.0 M solution of acid is mixed with 25 mL of .50 M NaOH. Which of the following best explains what happens to the pH of the picture when a few drops of 1.0 M HNO3 are added?

A

c. The pH of the picture stays about the same, because the conjugate base of acid 1 reacts with the added hydronium ions

23
Q

Which of the following correctly describes the reaction?

A

b. the decomposition of N2O5 is a first order reaction

24
Q

A proposed mechanism for destruction of ozone gas in the stratosphere is represented above. Which of the following is evidence that the mechanism is occurring?

A

a. The presence of Cl increases the rate of the overall reaction

25
Q

Which of the following combines to produce a white solid closest to the center of the tube?

A

a. HCl and CH3NH2