Midterm Practice Questions Flashcards

1
Q

Identify the one which is the perfect example for Isolated double bond?

A

1,4 pentadiene

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

Conjugated diene reacts with which among the following to form a cyclohexene?

A

Dienophile

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

Identify the statement which is related to Diels-Alder reaction?

A

Cyclic dienes react very slow than the linear chain dienes

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

A molecule in which more than one single bond separates two double bonds are
called as ____________

A

Isolated double bond

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

Which of the following functional groups is indicated by a strong and broad infrared absorption
around 3300 cm–1?

A

Alcohol

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

Which class of compound is an example of a carbonyl compound?

A

carboxylic acid

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

Why is sodium borohydride an important reagent in reducing a ketone?

A

It is a good source of the hydride ion (H-)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

The reactant shown below can follow which type of reaction mechanism

A

Diels Elder Reaction

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

Dienes with  bonds separated by exactly one σ bond are classified as ______.

A

conjugated

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

Identify the conjugated diene from the following options

A

4-methyl-1,3-heptadiene

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

What is the correct classification of the following pericyclic reaction?

A

cycloaddition

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

What would be the optimal conditions to achieve the following synthesis?

A

dilute aqueous H2SO4

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

The mechanism of hydroboration-oxidation must explain the observed _____ addition of the H and OH to the alkene as well as the _____ regiochemistry.

A

syn; anti-Markovnikov

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

The regioselectivity and stereospecificity in the hydroboration-oxidation of an alkene is best described as

A

Anti-Markovnikov orientation with syn-addition.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

What reagent(s) would accomplish the following synthesis?

A
  1. BH3*THF; 2. NaOH, H2O2, H2O
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

Identify the mechanism for the Williamson ether synthesis.

A

SN2 mechanism

17
Q
A