Midterm - Composite Flashcards
Polymerization/Curing
setting and hardening, doubles bonds to single bonds
Degree of Conversion
measure of the extent of polymerization, the % of C=C bonds into single bonds
Activation
initiating curing
Autocure
a chemical reaction started by mixing two components
Photocure
light activated (a single component) - UV, visible light cure
Dual Cure
starts with photo cure, completes with chemical autocure
Without Silane Coupling Agent
lack of bonding between filler/matrix, easy separation, leakage, decreases fracture, fatigue, wear resistance
Silane Chemistry
reacts to filler via alkyoxysilane groups (Si-O-Si)
reacts with itself to form siloxane
reacts with methacrylate groups in resin
Light Activation Peak
peak intensity between 450-490nm
Risks of Inadequately Cured Resins
allergen leaching
increased marginal breakdown
increased secondary decay
Dual Cure: One Component Systems
one paste, initial cures by photo cure, finishes with autocure
no mixing
Dual Cure: Two Component Systems
two pastes, base paste can be light cured only, activator allows for chemical curing
bulk filling, remote areas inaccessible to light cure
Total Retentive Force
retention power, depends on the cavity surfaces in bonding, the greater the number of bonded surface and fewer unbounded surfaces, greater will the retention power be
C-factor
Filler Distribution
different sizes in a filler allow for greater total amount in a given volume
- large = strength
- smaller = higher polish/finishability
Recommended Use: Packable
class I, II, VI