Midterm Flashcards

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1
Q

Pasteurization name came from

A

Louis pasteur

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2
Q

Louis studied

A

the
application of heat in controlling fermentations and preserving
the liquid product.

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3
Q

Napolenic wars was in the years

A

1799-1815

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4
Q

Napoleanic war detail

A

Supply lines were stretched and army was hungry so napoelin offered a prize of 12,000 francs for a new method to perserve and the winner was nicholas appert

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5
Q

Nicholas appert

A

Nicholas appert from the year 1749-1841 publishes article on perserving food and found that foods heated in sealed
containers would not spoil as long as the containers remained closed and created product heated in sealed glass bottles He called this appertization and wrapped the bootles in canvas

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6
Q

In 1810 who developed tin cans

A

Peter durand

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7
Q

Can opener made by

A

Yates in 1855

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8
Q

Who disovered before apperts did

A

Lazzaro Spallanzini shows meat extract perserved in sealed glass by boilling for one hour and carl wilhelm scheele used vinegar to perseve in 1782

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9
Q

French wine disaster

A

early 1860’s, the French wine
industry was on the verge of
collapsing due to unknown and
unwanted contaminants. severe impact on export
of wines.Louis Pasteur (1822-1895) was requested by Emperor
Napoleon III to investigate Pasteur identified the source of the
problem as being “microbes” that
could be killed by heating to about
60⁰C.
* Pasteur also applied the process to
beer –but not to milk!
* Process became known as
“Pasteurization”

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10
Q

Pasteurizatin before pasteur

A

William Dewees, - milk be
heated to near boiling and cooled prior to using the milk for
babies. tendency of milk to decompose
in hot weather was diminished
by this treatment

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11
Q

20th Century, many
people felt that pasteurization of milk
was

A

undesirable and unnecessary

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12
Q

In 1908, became the first city in the world to
require pasteurization of milk sold within the city limits.

A

Chicago

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13
Q

Selling raw milk

A

Sales of raw milk flourished just outside city limits.
 In 1909, legislation was passed by City of Chicago that
addressed this problem.

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14
Q

first commercial milk pasteurizer

A

In 1881, the first commercial milk pasteurizer was
introduced in Germany.

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15
Q

Dr. Henry
Koplik.

A

In 1889, the world’s first dispensary of heat-treated milk for
infants was established in New York City

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16
Q

1923, APV developed

A

plate heat exchangers which
enhanced control over the pasteurization process.

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17
Q

n order to determine if milk has been effectively pasteurized,
_ is used as an indicator.

A

alkaline phosphatase

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18
Q

alkaline phosphatase

A

responds to time-temperature exposure in such a
way that it can be used to monitor the degree of pasteurization
that a particular batch of milk has had. f the residual enzyme concentration is above a specified value,
the degree of pasteurization has been insufficient to meet
processing requirements

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19
Q

test for alkaline
phosphatase activity,

A

specific assay is performed,
often involving a color
change that indicates
enzyme activity. If the
enzyme is present, the milk
may require further heat
treatment. A substrate solution (often p-nitrophenyl phosphate) is added
to the milk sample. This substrate is colorless and becomes
yellow when dephosphorylated by alkaline phosphatase.
After incubation, the reaction is halted, often by adding an alkaline
solution. The intensity of the yellow color developed is measured
using a spectrophotometer at a specific wavelength (typically
around 410 nm).

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20
Q

Specific Heat:

A

 This is the amount of heat lost or gained in changing the
temperature of a unit mass of product by one

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21
Q

Sensible Heat

A

When heat is added to or removed from a material and a
temperature change results, this is called “sensible heat”.
* It can be felt or sensed by
touching the material
* The change in temperature
can be measured with a
thermometer.

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22
Q

Latent Heat:

A

When heat is added to or removed from a material and
causes a change in state (e.g., from a liquid to a solid, or a
solid to a liquid) without causing a change in temperature,
this is called “latent heat”.
* Since there is no observable temperature change, this
heat is essentially “hidden”

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23
Q

Latent Heat of Fusion:

A

The amount of heat removed or added to a unit mass
of material to change its state from a liquid to a solid or
vice versa with no corresponding temperature change.

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24
Q

Latent Heat of Vaporization

A

The amount of heat required per unit mass of liquid to
change it to a gaseous state with no corresponding
temperature change.
 The units are kJ/kg.
 Note: The reverse of the latent heat of vaporization is
the latent heat of condensation.

25
Q

latent heat of fusion for one kg of apples

A

it follows that
the latent heat of fusion for one kg of apples is 84% of the
latent heat of 1 kg of pure water.
Remember: This is because apples contain 84% water.

26
Q

The following factors will influence microbial growth in heat treated
canned products 5

A

the species of microorganisms in the microbial population
 acidity of the product
 ability of the population to grow in anaerobic environments
 water activity of the product (lower aw’s protect spores)
 thermal resistance of the food itself

27
Q

Process Lethality

A

A typical “sterilization”
process is designed to
provide a suitable time at a
specific temperature for the
coldest particle or volume
element of product in a
package or processing
stream.

28
Q

Slowest heating region or container cold
spot depends on the:

A

Type of product
* Container type and size
* Thermal processing method/system
* Heat transfer mechanism

29
Q

lethal
temperature.

A

The temperature which is being targeted to “kill” the
microorganisms that are present 121°C (or 250°F)

30
Q

unit of lethality”

A

the amount of heat
kill equivalent to one minute at 121°C for a microorganism
with a given z-value.

31
Q

Heat equation

A

Q=mcpT

32
Q

Membrane Filtration

A

using a
semipermeable material as
an interface to separate
solutes.

33
Q

Feed

A

he solution that
enters the system
containing molecules
(of diverse
characteristics) in a
solvent, usually water.

34
Q

Permeate

A

the liquid and the
molecules it contains that
pass through the
membrane.

35
Q

Retentate

A

the liquid and solutes
that do not pass through
the membrane.

36
Q

Flux rate

A

used to
describe the rate at which
permeate goes through the
membrane.
It is expressed in units of
volume per membrane area
per unit of time

37
Q

Tangential flow

A

flow pattern
most often used in membrane
processes where the feed is passed
across the membrane surface rather
than straight down upon it.
In this way, the flow continuously
sweeps across the membrane surface
and carries away much of the material
that might otherwise foul or plug the
membrane and its pores.

38
Q

Dead-end Filtration

A

Fluid flows
perpendicular to the membrane.
It has a simple setup, ideal for low
particle loads (e.g., water purification,
lab filtration).
It is encountered mainly at the lab scale
for analytical purposes.

39
Q

Dead-end Filtration Why Dead End?

A

Particles accumulate on the surface,
forming a filter cake.
*Requires frequent cleaning or
replacement.

40
Q

Pressure-driven
membrane
technologies common basis

A

Particle size difference is
the common basis for
pressure-driven membrane
separation
* Other physicochemical
interactions (e.g.,
electrostatic, H-bond, π-π)
may play an important role,
especially for tight and
dense membrane
separations

41
Q

Pressure-driven
membrane
technologies types

A

Microfiltration, ultrafiltration, nanofiltration and hyperfiltration / reverse osmosis

42
Q

Microfiltration

A

0.1 - 10
μm
MF is commonly used to remove insoluble particles (typically
particles responsible for turbidity) and microorganisms such as
yeasts or bacteria

43
Q

Ultrafiltration

A

0.1 ~ 0.01
μm
It mainly addresses macromolecule separation. The molecular
weight cutoff is defined as the molar mass of the smallest molecule
rejected at 90%. UF (together with the MF) is also efficient for
colloids, a family of particles difficult to remove because of their
small size (1 μm-1 nm) and stability (electrical repulsion).

44
Q

Nanofiltration

A

0.01 ~
0.001 μm
A specificity of NF membranes is the presence of superficial charge
(also evidenced in the UF to a lesser extent). Depending on the pH
of the solution, lower or higher than the isoelectric point (pHi) of
the membrane, the membrane surface is either positive or
negative (3, pHi, 5)

45
Q

Hyperfiltration/
Reverse
Osmosis

A

0.001 ~
0.0001 μm
It is mainly based on the difference in solubility and diffusion of
water and solutes in the membrane material, favouring water
transfer compared with solute transfer.

46
Q

Membrane Structures

A

Symmetrical membranes like isotropic microporous and nonporous dense membrane
Anisotropic membranes like loeb-sourirajan anisotropic and thin fim composite anisotropic

47
Q

Electrodialysis

A

membrane
process that separates ions across
ion-selective membranes under an
electric field.

48
Q

Electrodeionization

A

continuous
technique of eliminating ionizable
species from feed water using
electrodialysis and ion exchange resins.

49
Q

What are the properties of the permeate in the ultrafiltration
process?

A

First, we will need to do a mass balance on the feed and
retentate solutions based on the information given.

50
Q

The water in an oil/water mixture is forced in centrifugation

A

outside of
the spinning centrifuge and the less dense oil forms a layer
on top of the water towards the inside of the spinning
centrifuge.
basket centrifuges (batch and continuous)
 perforated bowl centrifuges

51
Q

The benefits of freeze concentration include

A

lack of a
heat treatment step which can vapourize volatile flavour
components and aromatics.
* The heat may also cause other thermal damage to the
product.

52
Q

Freeze conc steps

A

step 1 filling of wash column, 2. compressing ice crystal, 3. washing crystal with water, 4. scarping ice from top

53
Q

Drying is done primarily through

A

Evaporation or sublimation

54
Q

We dry foods to

A

to achieve a desired moisture level
to reduce spoilage
to increase shelf life
to reduce weight (shipping etc.)
to enhance convenience
to alter inherent attributes
to facilitate further processin

55
Q

Mechanism to dry foods includes

A

Liquid Diffusion
* Vapour Diffusion
* Freeze Drying (Sublimation)
* Surface Diffusion
* Hydrostatic Pressure Difference
* Combination of these methods

56
Q

Factors influencing Drying

A

Product composition / structure
Thickness
Particle size
Particle shape (characteristic dimensions)
Porosity
Specific heat
Surface characteristics
Moisture content
Seasonal variation
type of dryer
-temperature of air
-relative humidity of air
volumetric rate of air flow
-linear velocity of air flow
direction of air flow
-retention times

57
Q

Possible negative factors of drying

A

Nutritional degradation:
Many vitamins are unstable and highly susceptible to heat
damage.
Loss of structural integrity:
Stresses in drying may cause cells or structural matrix to
collapse
Reduction in functionality:
* Changes in structure due to heating such as starch gelatinization.
* Protein Denaturation and Loss of Solubility
Flavour changes:
Caramelization due to browning or Maillard Reaction. This may
or may not be desirable.
Case hardening:
Excess surface drying creates impermeable outer “shell” that
prevents or restricts moisture loss.
Often, the product feels dry but it is only dry on the surface.
Leaching of soluble constituents:
Water draws soluble nutrients to the surface of the material as it
diffuses from the interior during drying.
These soluble nutrients can then be lost if the dried material is
placed in water to re-hydrate it.

58
Q

Plate Heat Exchanger ( Flow Diversion Valve)

A

Flow from heat exchanger
2.Flow of finished product
3.Diverted flow (if needed)
4.Piston to valve
5.Assembly to activate valve

59
Q

Thermal Processing Operation

A

Control panel with circular
recording chart.
2.Balance tank
3.Centrifugal pump
4.Plate heat exchanger
5.Frame of modular unit