midterm 1 Flashcards
Strongest bond. Sharing a pair of electrons. energy must be used to break.
Covalent Bonds
a charged group on one molecule attracting an oppositely charged group on another. energy is given by coulombs law (E=kq1q2/Dr). weak but in huge numbers. important for structure.
Electrostatic interactions
E=Kq1q2/Dr
Coulombs law
want is to be large. property of material something is in (ex water=80)
Dialectric constant ( the D in E=kq1q2/Dr)
responsible for base pair interaction in DNA. important for secondary structures. an H atom is partially shared by electrons atoms (ex, N or O). responsible for properties of water. ionic interactions
Hydrogen bond
the group that includes both the atom that the H atom is more tightly linked and the H itself.
hydrogen-bond donor
the atom less tightly linked to a hydrogen atom in a hydrogen bond
hydrogen-bond acceptor
partial + and - charges around atoms. too close=repulsion. very low strength but huge number (like velcro).
Van der waals interactions
water is…
Polar, highly cohesive, hydrogen bonds with itself (really good at hydrogen bonding)
distribution of charge is asymmetrical, has a dipole moment. electronegativity of atom is unequal. hydrophilic!!
Polar
electronegativity of atom is equal. hydrophobic!!
Non-polar
exergonic
negative. favourable. reaction will proceed.
endogonic
positive. unfavourable.