Midterm 1 Flashcards
Alkane
-saturated hydrocarbons - contains only single bonds
-CnH2n+2
Sp^3 hybridization (tetrahedral) 109° ..
alkene
unsaturated hydrocarbons - contains at least one double bond
alkyne
unsaturated hydrocarbons - contains at least one triple bond
aromatics
a special class of ring containing compoudns
Molecular geometry
number of bonds around carbon atom gives us clues to molecular geometry…
Hybridization
used to predict shape
sp^3 - 4 sigma bonds - tetrahedral - 109°
sp^2 - 3 sigma bonds - trigonal planar - 120°
sp - 2 sigma bonds - linear - 180°
Alkanes (naming)
CH4 Methane C2H6 Ethane C3H8 Propane C4H10 - Butane C5H12 - Pentane C6H14 - Hexane C7H16 - Heptane C8H18 - Octane C9H20 - Nonane C10H22 - Decane
Alkanes and forces
-Only Van der Waals forces
Alkanes and hydrogen bonding
-Can’t hydrogen bond
Alkanes and boiling points
-Boiling point increases as size increases
Alkanes and reactivity
- Unreactive and tough to break through because only single bonds
- React with O2, making water and carbon dioxide - release lots of energy upon formation
What are primary/secondary/tertiary carbons/hydrogens?
Primary carbon - attached to one other carbon
secondary carbon - attached to two carbons..
primary hydrogen - a hydrogen attached to a primary carbon
secondary H - attached to a secondary carbon…
Primary carbons are most reactive and lose reactivity as move further away from primary.
isomers
molecules that have the same formula but with differently arranged atoms
Isomers flow chart
http://wpcontent.answcdn.com/wikipedia/commons/thumb/7/7f/Isomerism.png/500px-Isomerism.png