midterm 1 Flashcards
caracteristics of sustainable material
durable
local or regional production
contain recycled materials
manufactured with minimal pollution
do not themselves pollute
min energy to produce
reusable
renewable rapidly
can be used in a way that lessen environmental, social and economic impact
what is sustainable development
sustainable développement is a global concept that looks at every aspect of a cdertain industry over an infinite timeline, material are chosen on their total energy consumption from start to finish
whats the life cycle of products and processes
material extraction-> material processing -> product manufacture -> construction process -> building -> demolition -> landfill
wich are the two life cycle process that are the same step for concrete
product manufacture and construction process
whats the embodied energy of steel(mini and conventional mill), concrete and wood?
mini mill steel 15Mj/kg
conventional mill 46Mj/kg
concrete 0.75Mj/kg
wood 5.8 Mj/kg
whats the concrete usage vs population growth factor from 1970-2004
3.5x (cement) steel more than doubled
what are the3 issues of concern for the concrete/cement industry and explain
-profitability: profit margin for cement small so can’t change things
-compliance to standards: verry regulated so not much innovation/trials
-sustainability: cant change concrete for greener alternative, can only make concrete greener
how much concrete do we consume as humans?
concrete is the second most consumed thing behind water annually
what are the negative impacts of concrte and steel production ?
enormity of ressources used
generation of large amount of CO2 (concrete single biggest polluting industry outside of power generation)
how much CO2 is liberated per tonne of cement?
almost 1 tonne
what are the CO2 emission sources in the concrete industry?
-material manufacturing
-concrete manufacturing
- construction
-repair and rehabilitation throughout service life
-demolition and recycling
-transportation at each stage
what are the 3 key words for sustainability in order of importance and a quick def and how to effctively do it
Reduce: eliminate unecessary space in buildings, cconsume less mats when building and finally improve durability
reuse: renovate instead of rebuild, use mats in the construction phase that can be reused ex bolted connections instead of welds in steel, homogeneous mat instead of composite
recycle: less efficient than last two, but can be used for most mats concrete,wood,steel
how can concrete become more sustainable?
-manufacture portland cement more efficiently
-using waste mats as fuel(burn rubber tires)
-replacing portland cement with SCM and or fillers
-make it more durable
-use recycled concrete as aggregates
-capture, store or utilize CO2 emission
-improve structural design and building code make them sustainable
-effective maintenance and repair Strats(not like Mtl)
what are the four time scales over wich we need to examine industry environement interactions?
1)Past: remediate measure for dealing with innapropriaye waste disposal
2) present: prevent mistakes from the past by emphasizing waste minimazition, avoid toxic mats, control co2 emission
3)future: industry-environement interactions dictated by industrial products of today
4) far futur(50+years): industry environement interactions dictated by industrial process dev for futur use
why is it more expensive to build a road of concrete instead of cement if asphalte is more expensive than conrecte
concrete doesnt flex like asphalte so need more concrete (thicker)
what are engineering mats
defined as the inanimater matter that are useful to the engineering profession, consitute backbone of modern civilaztion
what are mats science
refers to knowledge of physical science as general truth and Principe in particular physic and chem
what are the four groups of eng mat
1: matal and alloys
2 ceramic and glass
3 organic polymers
4 composite
descibe metal and alloys
metals: capable of changing shape permenantly, good thermal and electrical conductivity and reflective of light
alloys: combination of more than one metal (steel) all metals used in eng are alloyed with something(iron,steel,alluminum,copper)
describe ceramic and glasses
-made from a combination of element from both the metaks and non metals of periodic table
-non metalic innorganic substances
-brittle
-good thermal and insulating prop
ex:bricks,tiles,silica
describe organic polymers
-composed of large num of molecules joined like a chain
-majority of eng polys are hydrocarbons
-eng polymers are syntethic and natural(wood,rubber)
-relatively inert and light
-high plasticity
-good compatibility with human tissue
-resist atmospheric and other corrosion
-resiste elec current
ex PVC,PVA, epoxy,cotton
descibe composites
- combination of other mats
ex concrete, fibre reinforced polymers
three area of implementation of mats and what types do they all have in common
structural: objects without moving parts(bridge, dams)
machines: involves major parts(jet engines, elec motors)
devices:eng innovations (lasers, transistors)
metak and alloys, ceramic and glasses and polymers are all that can be in all 3
mats caracteristics and properties wjat are they
-physicial (shape, size, finish, color, specific gravity, density, porosity, structure)
-Mechanical: strength, stiffness, elasticity, plasticity, ductility, creep, brittleness, hardness, toughness, resilience, impact resistance, fatigue behaviour)
-Thermal: specific heat, heat of transformation, thermal capacity, thermal expansion, heat transfer and thermal conductivity, thermal stresses, thermal fatigue, thermal shock capacity, latent heat of fusion)
-Electrical: resistivity, conductivity, relative capacity or dielectric constant, dielectric strength, semi-conductivity, superconductivity, corrosion resistance*
-Chemical: corrosion resistance*, atomic weight, valency, molecular weight, acidity, alkalinity, atomic number
-Magnetic: hysteresis, reductivity, retentivity, susceptibility, residual inductance, saturation value
-Optical: color, lustre, diffraction, fluorescence, reflectivity,
luminescence
-Technological: hardness, weldability, machinability, formability, castability
why is corrosion resistance in electrical and chemical properties?
because its an electrochemical reaction, electricity is created by movement
on what properties does bonding have a strong influence on?
strength and stiffeness
what are the five types of bonds atomic bonds? and an example for each
1)ionic(sodium chloride)
2)covalent(diamond)
3)metallic(sodium metal)
4)van der Waals(solid argon)
5) hydrogen
explain ionic bonds
forme when a cation(+) transfer an e- to an anion (-). generaly crystalline and higly soluble in water because of strong electrostatic binding force, rigid and high melting and boiling pts. generaly non conductors of heat and elec
explain covalent bonding
shares an e- between two atoms, formed by overlapping e- orbitals results in lower e- energy. localized and directional in nature so form definite angle between bonds. generaly soft, volatile, insolube, good insulators.
explain metalic bonding
e- are shared but not bound to individual or to pairs of atoms as covalent. instead free e- are free to move throughout metal, making good conductor. these bonds are delocalized ans non directional in nature
explain Van der Waals bonds
weak secondary bonds, can be found between covalent bonded chains of polys also formed when molecules undergo polarization
explain hydrogen bonds
special case of van der waals bonding from electrostatic interations between H atoms and O F or N atoms in molecules containing higly olar C-O, H-F or H-N bonds
what are the typical material for each bond types
ionic(ceramic, gypsum )
covalent(diamond glasses)
metalic metals
hydrogen water
van der waals thermoplastic polys
define a space lattice
infinite array of pts in 3D in wich every pts has the same surrounding identical to every other pts of the array
define a unit cell
smallest unit wich when replaced in space indefinetly will generate space lattice. so the smallest Volume that describe the structure of a mat
True of false metals are crystalline
true
true of fals glass is crystalline
False 0 crystal structure
why is glass not crystalline?
glass made of melted sand so crystal dissapear
unit cell diagram go see pp4
slide 2
how many space lattice are there
14
what are the thre basic configuration of space lattice?
simple cubic (SC) 1atom per unit cell
Body centered cubic (BCC) 2 a/uc
face centered cubic (FCC) 4 a/uc
go see crystal diagram pp4
yesssssssir
how can imperfectiton be classified on the basis of their geometry
point imperfection
line imperfection
surface imperfection
volume imperfection
describe point imperfection
imperfctions foudnin a point like region of the crystal. range from 1 to 2 atomic diameter in size and 3 forms:
1 vacancy
2 substitutional impurity
3 interstitial impurity
descibre the 3 forms of point imperfections
vacancy: atoms missing, gonna fail where bonds are weaker aka hole
substitutional: a different atom (intruder)
interstitial: extra small atom
describe line imperfection or dislocations
cause latice distortion around a line. created during solidification or during plastic defo of crystal structure. one dimensional and have 2 types
edge disloation
screw dislocation
describe edge dislocation
created when an extra half plane of atoms are inserted in crystal structure. represented by T up if incomplete start at top or T down if starts at bottom known as (+,-) edge dislo. store E in distorted region around the disco
describe screw dislo
formed when upward od downward shear stress is aplied to a crystal thats been separated by cutting plane. induces a spiral like distortion. here concentration of shear strain created and E is stored
describe surface imperfection
region of distortion that lie about the surface, thickness of a few atomic diameter. ex external surface of crystal itself and grain boundaries of crystal
descibre grain boundary
narrow region of atomic mismatch between two grains. shape determined by restriction imposed by neighbouring grain
define a phase
physically distinct chemically homogeneous and mechanically separable region of a system
define the components of a system
chemical species that comprise the system. can be elements, ion or compounds
what is the phase rule
aka gibbs eq F=C-P+2
degree of freedom in an eq
what are the two boundaries in a binary phase diagram
liquidus(between liquid and two phase region)
solidus (between solid and two phased region)
what is a eutetic phase diagram
when solid solubility is limited and melting pts of components are similar
how do you call the phase boundary where the solid solubility is limited?
solvus
what type of diagram is formed when the melting pts of the components are vastly different
peritetic phase diagram
definition of macrostructure
structure as examined by the naked eye or under low magnification
def of microstructure
structure as observed using optical microscopy
substructure definition
structure obtained by using a microscope with a much higher magnification and resolution than the optical microscope
what re the 4 level of structure
Crystal structure
electronic structure
nuclear structure
molecular structure
define crystal structure
atoms situated in an orderly repetitive arrangement wich occupies space. Provides the detail of atomic arraingement within a cell. suffiecent to describe arrangement of few atoms in the unit cell
metals are crystal and steel is made of microscopy crystal
define electronic structure
electrons in the outermost orbitals of individual atoms of the solid. spectroscopic tech are useful in determining elec structure
define nuclear structure
studied by nuclear spectroscopic tech such as nuclear magnetic resonnance
(can look inside concrete without damaging it)
define molecular structure
spatial arrangement of small groups of atoms wich are strongly joined togetehr within the group or molecule
what structure exerts a major influence on the mechanical and physical properties of the mat
electronic structure
what structure exerts a strong influence on mat behaviour
molecular and crystal
the deformation of a mat is strongly affected by what structure?
molecular and crystal
how can failure occure give ex
mat defect, variation in properties, inadequate design, inadequately controlled processing, poor workmanship, insufficient maintenance, abuse, negligence, etc…
failure analysis graph explain
(Econ,safety,function and appearance) -> design -> mats selection -> fabrication -> machining -> assembly -> service -> failure analysis -> back to design
the tests to determine the properties of different mats can be what ?
destructive or non destructive
define size effect
the larger the specimen, the more likely it is to have flaws of greater severity. so more likely to have a lower fracture strength
why do we take size effect into account
because when testing brittle mats like concrete and woods , the effect on strenght can be significant. a small wood specimen is stronger thsn a concrete specimen
define the tensile test
one of the most useful, a sample is elongated at cst rate and load necessary to produce a certain elongation is measured as dependant variable
True or false we test concrete in tension
false, since concrete as low tensile force
engineering stress formula
sigma = P/Ao
engineering strain formula
epsilon = (l-lo)/lo
Hookes law formula
sigma = E x epsilon
whats the young modulus?
elastic modulus (E)
with what does the young modulus help?
helps limit deflection
linear elastic stress strain curve go see
pp.7 s 5
why are brittle mats not stromg in tension?
because they have micro cracks that propagate under tension but they close in compression thus may have high compressive strength(gray cast iron and concrete)
wheter a mat is brittle or ductile depends on what?
atomic or molecular structure and service conduction
what are the 3 srvice condition affecting the behaviour of the mat
temperature
strain rate
degree of triaxility
see graphs on failure mode pp 07
s8-9-10
what is necking
during plastic deformation, volume doesnt change even though there is elongation, the cross sectional area diminishes so the V stays cst
Aolo = Aili = cst
where do ductile material tend to fail in tension?
in shearing at an angle of 45 deg
how do brittle mats fail under tension
fail due to crack propagation perpendicular to axis of loading, show little to no necking
see pp07 slide 13-14-15 mid term q
oh yeah
what is the flaw of the splitting tension test
since the load is applied in the middle if the major flaw isnt there then its not gonna fail at its weakest pts and calculate the minimizing stress
whats th ration of tensil strength to compressive strenght for concrete
arond 10%
does necking arrise in the compression test?
no since the cross section of the specimen increases
how does concrete fail in the compression test
in tension/shear…
see pp 7 slide 21
yer
difference between three pts bending and 4 pts bending
in three pts bending, we only test the center but in the four pts bending 1/3 of it is tested so its more accurate go check pp 7 slide 23
what are the effects of shear stress
increased deflection
what are the shear formulas
go see pp 7 slide 25
what are the potential problems in bending test
high localised stresses at loading pts(when building you want supports to be round not circular so stress less concentrated, corners induce cracking)
frictional force
torsional loading(make sure cross section is square)
is hardeness a fundamental property of a mat
no purely empirical
how does the hardeness scale work?
the higher number can scartch the lower number. and even if 2 mat have the ssame number doesnt mean they are alike they just performed the same for that test
whats the hardeness test
it measures the resisitance of a mat to an indenter or cutting tool. indenter usually hardened steel, sintered tungsten carbide or diamond and shape is ball pyramid or cone. a load is applied by pressing the indenter at a right angler for a given period of time on the surface of the sample .
what is an impact test
it measures a mat resistance of damage during an impact event. this is not a fundamental property since they are random in nature nd they are empirical in design. most of these test measre the energy required to fracture a standard specimen under specific conditions.
what is the charpy test
its an impact test that gives a relative indication on the notch toughness of a material under shock loading. it was specifically designed to evaluate the effects of temperature on steel behaviour.
true or false most metals are know to absorbe more energy when they fail in a ductile manner than in a brittle manner
true
what are th 4 loading conditions in construction mech
monotonically increasing (static)
high strain rate (impact)
repeated (fatigue)
sustained (creep)
define fatigue
happens under repeated stress, internal damage lead to a sudden fasilure with no significant prior deformation. it is more common in parts subjected to high cyclic loadig ( axles, drive shafts, propeller shafts/blade crank shaft) but can also occur in structural element (plane wings and fuselage, bridges, brains, etc)/
what are the two basic stages in fatigue failur
crack initiation
crack propagation
where do crack start?
they initiate at a free surface pts, a pts of high stress concentration ( preexisting flaw, discontinuity). they can start at any flaw or discontinuity (concrete, paste/aggregate interface)
what is a slip step
slippage between grain boundaries
what causes fatigue damage?
tensile and shear
see pp 8 slide 3 for crack propagation figure
yu
see slides 4-5 of pp8 fatigue curves
yeah
whats the goal of the fatigue test
it is to determine the number of cycles that a smaple material can safely endure for a given stress (S-N diagram)
what are the two basic types of machines for fatigue test
Constant load (load cycle remians constant, strain gradually increases as specimen sustains damage)
Constant displacement (displacement cycle remains cut , stress change as specimen sustains damage
at what speed are fatigue test usually run at
25-500 cycles per seconds
what is the triple point
point where there is 0 degress of freedom. all 3 states can be present at once at a specified pressure and temperature on a phase diagram
what are the drawbacks of a cst moment rotating bending machine
-not suitable for nonzero mean stress
-Specimen must be circular in cross section
how are specimen tested for fatigue testing
they are trsted to failure using different loads and num of cycles before failure is recorded for each load ans is then plotted on a S-N diagram .
true or false ferrous aloys ca be cycled for an indefinite num of times at stresses below fatugue lim or endurance lim
true
reciprocating bending machine caracteristics
flat specimen
zero or non zero mean stress
direct stress machine caracteristics
zero or non zero mean stress
direct tension or compression
what are the variability in fatigue results
- real mats have imperfections so no two samples are truly identical
- pretty much impossible to have the same test conditions over large num of tests
palmer miner hypothesis
used to calculate prelim estimates of fatigue life go see pp8 slide 13
what are the shortcoming of the palmgren miner hypothesis
assumes the damage accumulating in each cycle of loading is independant of stress history
assumes theres no effect due to the order in wich different stress levels are applied
what causes stress concetration to increase
increasing flaw size
decreasing radius of curvature of flaw tip
material properties effect on fatigue
grain size (finer grain improves fatigue res)
surface finish(smooth surface less susceptible to crack initiation),(grinding, eating, milling, etc all affect crack initiation potential)
residual stress in surface (tensil reduce fatigue life, compressive improves fatigue life)
environement effect on fatigue
increase in temp -> decreased fatigue life
fatigue lim may dissapear at high temp
thermal cycling can induce stress that lead to thermal fatigue failure if mat is restrained from expand or contracting (see formula pp8 slide 20)
what is the effect of corrosion on fatigue
surface pitting provides crack initiation pts, fatigue lim disappears in corrosive environement
define creep
known as the plastic deformation of a mat which occurs when it is subject to a cst stress or load
whats the creep test?
commonly thought of as the high temp test because at temps below 40% of absolute melting pts creep is negligibvle in most metals.
does temperature affect the creep in concrete?
no, concrete undergoes creep at virtually any temps unles fully frozen
whats a creep curve
plot elongation of tensile specimen vs time at a given temo under a cst load or true stress. 4 stage of elongation (instantaneous elongation then primary or transient creep then secondary or steady state creep finaly tertiary creep)
see pp 8 slide23 for creep curve
youpi
true or false increasing stress or temperature resutls in a decreased creep rate?
false, it is increased
True or false concrete hardens as it dries
false, once it dries it stops the reaction and doesnt get stronger