Midterm 1 Flashcards
Precursor of carbon fiber
PAN (polyacrylonitrile)
Carbon fiber manufacture steps
Precursor, oxidize, carbonize, graphitize, hot stretch, etch
Oxidization of carbon fiber temperature
200-300 C
Carbonization of carbon fiber temp
1000-2000 C
Carbonization of carbon fiber
Removal of oxygen and nitrogen from polyacrylonitrile precursor to form aromatic carbon
Graphitization of carbon fiber temp
> 2000C
Graphitization of carbon fiber
Converts aromatic carbon structure into graphitic structure with high modulus and low strength
Role of CF hot stretching
Increased strength by aligning graphitic planes
Role of CF etching
Preparation for bonding to resin in composites
Four modulus categories
Ultra-high modulus, high modulus, intermediate modulus, high tensile
UHM
> 450 GPa
HM
350-450 GPa
IM
200-350 GPa
HT
<100 GPa, ST > 3.0 GPa
Weave - UD
Unidirectional (no weave; plastic stitching).
Use of UD weave
Where principal loading predictable
Weave - plain
Checkerboard weave.
Weave - twill
Skipping weave.
Example: 2x2 twill weave
Each fiber passes over 2 fibers and under 2 fibers
Weave - harness satin
Each fiber passes over n and under 1
Example: 4HS weave
Each fiber passes over 4 and under 1 fiber
Tow
Larger strip of carbon fiber consisting of many individual filaments
Tow notation
nk, denoting n thousands of fibers per tow
Significance of tow counts
Low tow counts are difficult to manufacture and more expensive
Significance of bulk factor
Large bulk factors lead to wrinkling
Factors that contribute to bulk factor
Vacuum compaction, curing shrinkage, resin infiltration into fibers
Autoclave vs. OOA, cost
Autoclave is higher
Autoclave vs. OOA, time
Autoclave is shorter
Autoclave vs. OOA, atmospheric pressure
Autoclave 3-8 atm (higher pressure); OOA ambient
Autoclave vs. OOA, atmospheric composition
Autoclave N2, OOA air
Autoclave vs. OOA, bulk factor
Autoclave can have higher bulk factor
Autoclave vs. OOA, void content
Autoclave lower
Autoclave vs. OOA, void reduction mechanisms
Autoclave governed by pressure resulting in air evacuation and resin infiltration; OOA depends on availability of evacuation channels and resin flow.
Autoclave vs. OOA vacuum bag considerations
OOA vacuum bag requires an edge dam
Autoclave vs. OOA, DOI
Autoclave uses DOI ~ 100%; OOA uses lower DOI
Autoclave vs. OOA, strength of resin
Autoclave stronger
Autoclave vs. OOA, viscosity
Autoclave higher viscosity
Autoclave vs. OOA, fiber-matrix ratio
Autoclave higher fiber-matrix ratio
Autoclave vs. OOA, end use
Autoclave for primary structural parts; OOA for secondary
Autoclave vs. OOA, temperature
Autoclave 177 C; OOA 93/121 C.
Resin transfer molding, binder
Binder additive is used to stabilize fibers and maintain a better shape.
Resin transfer molding steps
Binder-stabilized fabric, lay up, preforming, resin injection, curing
Gelation
Beginning of polymer cross-linking and formation of viscoelastic solid
Gelation wrt rate of cure
Does not affect rate of cure.
Relevance of gelation for work life
Gelation point is upper limit of work life (i.e. no more working should be performed on polymer)
Vitrification
Glass transition temperature is increased to cure temperature, causing formation of glassy elastic solid
Vitrification wrt rate of cure
Vitrification does result in a rapid decrease in the rate of cure
Effect of temperature of cure on glass transition temperature
Increased overall temperature of cure raises glass transition temperature
Viscous response to stress wrt time
Linear strain response
Elastic response to stress wrt time
Near instant strain response; returns to initial state after strain removal
Viscoelastic response to stress wrt time
Time-dependent strain
1-2 vs. x-y
1 is fiber, 2 is transverse, x and y are loading directions
theta in 1-2 vs. x-y drawings
Angle between x and 1.
Orthotropic
Orthogonal planes of property symmetry
Example of isotropic material
Glass, plastic (amorphous)
Example of anisotropic material
Diamond, crystals
Example of orthotropic material
CF lamina
Isotropic response to tensile normal stress
Elongation in direction of tensile stress, contraction in other direction
Anisotropic response to tensile normal stress
Extensional-shear coupling; both extensional and shear deformation
Orthotropic response to tensile normal stress
If in principal direction, behaves as isotropic material. Else behaves as anisotropic material.
[0/45/90]
0 followed by 45 followed by 90
Subscript S in layup code
Symmetrical about a midplane
+- sign in layup code
Fabric repeated twice, positive then negative
[0/(+-45)_2]
[0/45/-45/45/-45]
[0/90/0bar]_s
Odd layup with 0 at center: [0/90/0/90/0]