Metals, alloys and casting Flashcards

1
Q

All metals are crystalline. What does crystallinity mean?

A

Metals have regularity, a repeating pattern

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

How many different space lattices can a metal form and which is the most common?

A

14 space lattices

Simple cubic is most common

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

Properties of metals

A
  • Strong bonds (high MP +BP)
  • Good stiffness (modulus of elasticity)
  • Ductile (Can be pulled into wires)
  • Malleable (can be beaten into sheets)
  • Conduct heat and electricity
  • Opaque (non-aesthetic)
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

What is an alloy?

A

An alloy is two or more metals that are mutually soluble in each other in a molten state. Formation of alloys results in enhanced properties.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

What do alloys of a fine grain structure have?

A

The least permanent deformation during service e.g. higher yield stress values

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

Properties of alloys that are important

A
  • Colour: aesthetics
  • Grain size: size of crystals of alloy influenced by cooling rate heat and determines properties like tensile strength
  • Phase structure: level of mixing
  • Corrosion
  • Biocompatibility
  • Thermal properties: melting range, thermal expansion
  • Strength
  • Economic - cost
  • Porcelain bonding
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

Precious metal

A

Containing metals of high economic value such as gold, platinum, palladium, silver
How expensive they are

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

Noble metal

A

A precious metal that is resistant to tarnish. This excludes “silver” by definition
Chemical property

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

Low gold alloys

A

Alloys containing <75% gold (less than 50 a/o gold) which means that gold atoms represent less than every other atom

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

Gold-substitute alloys

A

Precious alloys that do not contain gold

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

Base-metal alloys

A

Alloys not containing precious metals to impart their corrosion

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

How are classes of alloys classified according to ADA 2003?

A
  • High noble alloys (40% wt Gold, 60% wt noble)
  • Titanium and titanium alloys (85% wt Ti) for implants
  • Noble alloys (25% wt e.g. pallidium)
  • Base metal alloys (<25% wt noble e.g. nickel, chromium)
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

How are high noble alloys (Gold-Au) classified?

A

Types 1-4 from soft to extra hard. The less gold, the stronger the alloy will be. From type 1-4 the ductility, elongation at break and corrosion will decrease whilst hardness, tensile strength, proportional limit and modulus of elasticity will increase.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

How can gold be measured?

A
Carat value (24 is maximum carat gold)
Fineness value (value goes up to 1000 and is more valuable than carat to work out % of gold)
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

Uses of type 1-4 of high noble alloys

A
Type 1 (non-heat hardenable): inlay, single surface
Type 2 (non-heat hardenable): inlay, onlay (no thin sections)
Type 3 (heat hardenable): onlay, crown (potential for fracture)
Type 4 (heat hardenable): crown, bridge
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

Use of gold in alloy

A

Corrosion resistance

17
Q

Use of copper in alloy

A

Hardness

18
Q

Use of silver in alloy

A

Counteract reddish colour of copper

19
Q

Use of pallidium in alloy

A

Increase MP and hardness

20
Q

Use of platinum in alloy

A

Increase MP (harder than Pd)

21
Q

Use of zinc in alloy

A

Prevents oxidation during melting (O2 getter)

22
Q

What are the 2 types o f corrosion?

A

Chemical corrosion = reaction of metal with oxygen
Electrochemical corrosion: need anode, cathode, circuit and electrolyte. Different electrochemical corrosion categories: galvanic corrosion, local galvanic corrosion, concentration cell corrosion and stress concentration

23
Q

How are noble alloys different from high noble alloys?

A

Noble alloys have higher hardness and yield strength compared to high noble but lower melting range.
Pd-Cu-Ag very strong - used for cast and are 25% stiffer than any high noble alloy.

24
Q

Base metal alloys

A

Consist of Ni-Cr and Co-Cr alloys

80% of RPD are from Co-Cr alloys

25
Q

Composition of base metal alloys

A

Cobalt 35-65%,
Chromium 11-26%
Nickel 0-30%
Molybdenum little amount

26
Q

What are the properties of each components of base metal alloys?

A

Co and Ni are simialr and result in hard alloys.
Ni slightly enhances ductility [percent elongation]
Mo provides strength and hardness to Co-Cr alloys
Cr gives corrosion resistance but it fails in high concentration of Cl-

27
Q

Advantages of base metal alloys

A

+ High modulus of elasticity (they can be used in thin section)
+ Hardness
+ strength
+ low density

28
Q

How are base metal alloys classified for fixed restorations?

A

Type 1: low strength applications e.g. inlays
Type 2: medium strength e.g. large inlays, onlays, crowns
Type 3: high strength e.g bridge pontics
Type 4: extra high strength for very high stress applications e.g. long span bridges and implant superstructures

29
Q

What is biocompatibility?

A

Ability of a material to perform with an appropriate host response in a specific situation

30
Q

Titanium alloy composition

A

Ti6Al4V
Ti 6%
Aluminium and 4% vanadium with coating hydroxyapatite
Al is a stabiliser and V is B stabiliser

31
Q

Why titanium?

A

Lightweight, biocompatible, corrosion resistant (dynamic inert oxide layer), strong and low priced

32
Q

Titanium grades

A

Grades 1-4 from yeild strength 25,000 –> 70,000

33
Q

Why is implant dentistry becoming more common?

A
  • Demographics and increasing wealth: ageing population with increasing wealth
  • Growing pt awareness of benefits of implants over conventional solutions, increasing importance of estehtics
  • Increasing acceptance of implants: long term clinical success of implant treatment
  • Rising number of trained dentists
34
Q

Different types of implant materials

A

Titanium
Zirconia (aesthetics, no allergies, more holistic, biofilm no plaque accumulation, periimplantitis, chipping of crown)
TiZr (stronger than pure titanium and has excellent osteointegration properties)

35
Q

Lost wax casting technique

A

A wax pattern is heated, vaporised and subsequently replaced by a metal.

  1. impression
  2. Die production (positive replica)
  3. Waxing on die (Wax restoration)
  4. Wax investment (sprue)
  5. Investing
  6. Wax burnout
  7. casting
36
Q

Porcelain-Fused to metal: metal important requirements

A

Metal must have the potential to bond to the dental porcelain, need oxide forming elements; possess coefficient thermal contraction compatible with dental porcelains; sufficiently high solidus temp to permit application of low-fusing porcelains

37
Q

How does porcelain bond to metal?

A
  • Physical bonding nil
  • Mechanical bonding: extensive - surface roughness from sandblasting determines degree of mechanical inter-digitation
  • Chemical bonding: occurs by oxide mixing
38
Q

What are the mechanical failures for porcelain-to-metal fracture and porcelain fractures?

A

Porcelain-to-metal fracture

  1. Fractures originating at the metal surface: surface metal contamination, incomplete degassing, under fired opaque porcelain, improper metal thickness, incorrect metal conditioner, reused metal alloy.
  2. Fracture at the opaque and entering the bulk porcelain: porosity at the opaque layer, cracks at the opaque layer, incomplete opaque bonding from firing at too low temp.

Porcelain fractures

  1. Design or procedural errors: too little bulk of metal, sharp edges of porcelain, improper margin design
  2. Malocclusion or impact stresses
  3. Thermal contraction incompatibility: built in stresses generate cracks at pores, thermal fatigue propagates cracks
39
Q

Repair systems for porcelain to metal fractures

A
  1. Silane and acrylic e.g. fusion, George Taub products
  2. silane + composite e.g. PULPDENT porcelain repair kit
  3. Silane and composite e.g. MIRAGE PFM Repair