Metals Flashcards
metallic bonding
the electrostatic force of attraction between positively charged ions and delocalised electrons (electrons that are free to move)
ore
a naturally occurring solid material from which a metal or valuable mineral can be extracted, and which contains a relatively high proportion of the metal, making extraction profitable and worthwhile
mineral
a solid, naturally occurring inorganic substance
native
metals found pure (uncombined as elements) in their metallic form in nature and which are unreactive elements
reactivity series - group A metals
- mercury, silver, gold
- least reactive metals, found uncombined in the Earth’s crust as an element or ore
- extracted from their ore using heat alone
reactivity series - group B metals
- zinc, iron, tin, lead, copper
- moderately reactive metals
- extracted from their ore by heating with carbon or carbon monoxide
- C / CO oxidised to form CO₂ forcing metal to be reduced
- C / CO must be more reactive than metal being reduced
reactivity series - group B metals - equation
metal oxide + carbon / carbon monoxide ➡️ metal + carbon dioxide
reactivity series - group C metals
- potassium, sodium, calcium, magnesium, aluminium
- very reactive metals
- extracted from their ore using electrolysis
- positive ions gain electrons (are reduced) at the negative electrode
- negative ions lose electrons (are oxidised) at the positive electrode
reactivity series - group C metals - why must a DC supply be used?
so that the same reaction occurs at the same electrode all the time, meaning that the products can be identified
reduction
the removal of oxygen / the gain of electrons
oxidation
the addition of oxygen / the loss of electrons
oil rig 🏗
- oxidation is loss (of electrons)
* reduction is gain (of electrons)
metal + water ➡️
metal hydroxide + hydrogen
metal + oxygen ➡️
metal oxide
metal + acid ➡️
salt + hydrogen
displacement reactions rule
the metal which is higher in the electrochemical series will displace a metal lower in the series from its compounds in solution
half cell
a metal in solution of its own ions
electrolyte
an electrically conducting solution containing ions
ion bridge examples
- folded filter paper soaked in salt water
- glass u-tube containing potassium chloride solution / gel
- string soaked in salt water
- a porous plug in the middle of a u-tube (the solutions for each half cell go in either side of the plug)
electrochemical cell voltage rule
the further apart the metals are in the ECS the greater the voltage produced
electrochemical series
a measure of how easily a metal atom loses electrons to form positive ions in solution
simple cell
made by linking two metals with an electrolyte
electrochemical cell
the arrangement of two metals connected by wires to a meter with a wet filter paper placed between them
ion bridge
completes the circuit because it allows ions to move, carrying the current between the two halves of the cell